Registration Dossier
Registration Dossier
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EC number: 221-309-9 | CAS number: 3063-94-3
Auto flammability
Administrative data
- Endpoint:
- auto-ignition temperature (liquids)
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 15 Jan 2018 - 25 March 2018
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 018
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
Test material
- Reference substance name:
- 2,2,2-trifluoro-1-(trifluoromethyl)ethyl methacrylate
- EC Number:
- 221-309-9
- EC Name:
- 2,2,2-trifluoro-1-(trifluoromethyl)ethyl methacrylate
- Cas Number:
- 3063-94-3
- Molecular formula:
- C7H6F6O2
- IUPAC Name:
- 2,2,2-trifluoro-1-(trifluoromethyl)ethyl methacrylate
- Test material form:
- liquid
Constituent 1
- Specific details on test material used for the study:
- SOURCE OF TEST MATERIAL
- Source and lot/batch No.of test material: 449935-248
- Expiration date of the lot/batch: 30 March 2018
- Purity test date: Not specified
STABILITY AND STORAGE CONDITIONS OF TEST MATERIAL
- Storage condition of test material: In refrigerator (2-8°C)
- Stability under test conditions: Stable
Results and discussion
Auto-ignition temperature (liquids / gases)open allclose all
- Auto-ignition temperature:
- 440 °C
- Atm. press.:
- 1 012 hPa
- Remarks on result:
- preliminary test
- Key result
- Auto-ignition temperature:
- 425 °C
- Atm. press.:
- 1 012 hPa
Any other information on results incl. tables
The results of the main study on the determination of the auto-ignition temperature of the test item are given in.
Ignition of the test item within 5 minutes after introduction was observed with each sample volume and with each test a minimum auto-ignition temperature was obtained. The maximum deviation between the three values was < 10°C. According to the guidelines, no further testing was required.
The lowest temperature at which ignition of the test item occurred was 426°C. This temperature was rounded down to the nearest multiple of 5°C giving an auto-ignition temperature of the test item of 425°C.
Auto-ignition Temperature of the Test Item
Test |
Volume |
Auto-ignition |
Ignition delay
|
Colour of the flame |
Minimum auto-ignition |
1 |
70 |
438 |
25 |
orange |
431 |
|
150 |
431 |
17 |
orange/blue |
|
|
250 |
441 |
13 |
orange/blue |
|
2 |
60 |
442 |
26 |
orange/blue |
427 |
|
100 |
427 |
32 |
orange/blue |
|
|
170 |
432 |
16 |
orange/blue |
|
3 |
80 |
435 |
27 |
orange/blue |
426 |
|
120 |
426 |
26 |
orange/blue |
|
|
200 |
431 |
16 |
orange/blue |
|
Applicant's summary and conclusion
- Conclusions:
- Commercially available auto-ignition temperature apparatus was used for the determination of the degree of auto-ignitability of 2,2-trifluoro-1-(trifluoromethyl)ethyl methacrylate.
The test item is auto-ignitable with an auto-ignition temperature of 425°C.
The atmospheric pressure was 1012 hPa.
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