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Diss Factsheets

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
explosive properties of explosives
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
UN Manual of Tests and Criteria: Part I: Classification procedures, test methods and criteria relating to explosives of Class 1
GLP compliance:
yes
Specific details on test material used for the study:
Source: ExxonMobil Research and Engineering (Paulsborro, NJ)
Lot: 17-064163-4
- Expiration date of the lot/batch: 20 March 2019
-Purity test date: 25 September 2017
Appearance: Light grey powder
Storage conditions: Room temperature, keep container tightly closed
Key result
Parameter:
other: Energy (J/g)
Remarks:
Thermal Stability by Differential Scanning Calorimetry
Value:
-110

Table1: Results of the DSC-measurements

No.

Sample weight / mg

Onset / °C

Energy / J/g

PN14432

8.90

170
230
410

+70 (endothermic)
+310 (endothermic)
-90 (exothermic)

PN14433

9.64

170
230
400

+30(endothermic)
+290(endothermic)
-120(exothermic)

A first exothermal signal appears in the temperature range at 400 to 450 °C with an average decomposition energy of -110 J/g.

Interpretation of results:
GHS criteria not met
Conclusions:
In the DSC-measurement the energy of the exothermic decomposition of the test item Lithium salicylate was < 500 J/g. Therefore, further tests for explosive properties had not to be performed.
Executive summary:

In the DSC-measurement the energy of the exothermic decomposition of the test item Lithium salicylate was < 500 J/g. Therefore, the test item does not have to be classified as explosive substance in class 1 according to the UN Transport Regulation or as explosive substance according to GHS or CLP Regulation EC 1272/2008 Annex 1: 2.1, respectively.

Description of key information

In the DSC-measurement the energy of the exothermic decomposition of the test itemLithiumsalicylatewas < 500 J/g. Therefore, further tests for explosive properties had not to be performed.

Key value for chemical safety assessment

Explosiveness:
non explosive

Additional information

Justification for classification or non-classification

In the DSC screening measurement the energy of the exothermic decomposition of the test item Lithium salicylate was < 500 J/g. Therefore, the test item does not have to be classified as explosive substance in class 1 according to the UN Transport Regulation or as explosive substance according to GHS or CLP Regulation EC 1272/2008 Annex 1: 2.1, respectively.