Registration Dossier
Registration Dossier
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EC number: 282-544-0 | CAS number: 84254-97-7
Guidance on Safe Use
Administrative data
First-aid measures
If inhaled: If breathed in, move person into fresh air. Artificial respiration and/or oxygen may be necessary. Call a physician immediately.
In case of skin contact: Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water. Call a physician immediately. Wash contaminated clothing before reuse.
In case of eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 5 minutes. Remove contact lenses. If eye irritation persists, consult a specialist.
If swallowed: If swallowed, rinse mouth with water (only if the person is conscious). Call a physician immediately
Most important symptoms and effects, both acute and delayed
Symptoms: Dilatation of the pupil, Tremors, Sensitisation
Indication of any immediate medical attention and special treatment needed
Treatment: Treat symptomatically.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: Water mist Dry powder Foam Carbon dioxide (CO2) Sand Aqueous film forming foam (AFFF). Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media: Water spray jet
Special hazards arising from the substance or mixture
Specific hazards during firefighting: Risk of dust explosion.
Hazardous combustion products: Carbon oxides, Nitrogen oxides (NOx)
Advice for firefighters
Special protective equipment for firefighters: In the event of fire, wear self-contained breathing apparatus.
Further information: Avoid dust formation. In the event of fire, cool tanks with water spray.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Personal precautions: Avoid dust formation. Avoid breathing dust. Evacuate personnel to safe areas. Keep away from open flames, hot surfaces and sources of ignition.
Environmental precautions: Should not be released into the environment. Do not flush into surface water or sanitary sewer system.
Methods and material for containment and cleaning up
Methods for cleaning up:
Large spills: Sweep up or vacuum with HEPA filter or via wet cleaning into suitable containers for disposal. Pick up and arrange without creating dust. Keep in properly labelled containers.
Small spills: Moisten a towel, cover the spill, pick up the spill or use HEPA vacuum.
Large spills and Small spills: Keep in suitable, closed containers for disposal. Treat recovered material as described in the section "Disposal considerations".
Handling and storage
Precautions for safe handling
Advice on safe handling : Ensure all equipment is electrically grounded before beginning transfer operations. To avoid thermal decomposition, do not overheat. Use personal protective equipment as required. Keep away from heat and sources of ignition. Avoid formation of dust and aerosols. Avoid inhalation, ingestion and contact with skin and eyes.
Advice on protection against fire and explosion : Avoid dust formation.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. When using do not eat, drink or smoke.
Dust explosion class: St3
Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers : To maintain product quality, do not store in heat or direct sunlight. Store in original container. Keep containers tightly closed in a cool, well-ventilated place. Store at room temperature.
Recommended storage temperature: 15 - 25 °C
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN2811
Shipping information
- Proper shipping name and description:
- TOXIC SOLID, ORGANIC, N.O.S.
(1'-(phenylmethyl)-[1,4'-bipiperidine]-4'-carbonitrile) - Chemical name:
- 1'-(phenylmethyl)-[1,4'-bipiperidine]-4'-carbonitrile)
- Labels:
- 6.1
Special provisions / remarks
- Remarks:
- Tunnel restriction code : (E)
Remarks:
This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 2811
Shipping information
- Proper shipping name and description:
- TOXIC SOLID, ORGANIC, N.O.S.
(1'-(phenylmethyl)-[1,4'-bipiperidine]-4'-carbonitrile) - Chemical name:
- 1'-(phenylmethyl)-[1,4'-bipiperidine]-4'-carbonitrile
- Labels:
- 6.1
Special provisions / remarks
- Remarks:
- This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 2811
Shipping information
- Proper shipping name and description:
- TOXIC SOLID, ORGANIC, N.O.S.
(1'-(phenylmethyl)-[1,4'-bipiperidine]-4'-carbonitrile) - Chemical name:
- 1'-(phenylmethyl)-[1,4'-bipiperidine]-4'-carbonitrile
- Labels:
- 6.1
- Marine pollutant
Special provisions / remarks
- Remarks:
- This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 2811
Shipping information
- Proper shipping name and description:
- TOXIC SOLID, ORGANIC, N.O.S
(1'-(phenylmethyl)-[1,4'-bipiperidine]-4'-carbonitrile) - Chemical name:
- (1'-(phenylmethyl)-[1,4'-bipiperidine]-4'-carbonitrile)
- Labels:
- 6.1
Special provisions / remarks
- Remarks:
- IATA (Cargo)
Packing instruction (cargo aircraft): 677
Packing instruction (LQ): Y645
Packing instruction (EQ): E1
IATA (Passenger)
Packing instruction (passenger aircraft): 670
Packing instruction (LQ): Y645
This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of IATA DGR §2.6.10 are met.
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Exposure controls / personal protection
Engineering measures
Engineering controls should be used as the primary means to control possible exposures. Use process enclosures, local exhaust ventilation or other engineering controls to keep exposure levels below recommended exposure limits. All personal protective equipment should be based on a risk assessment. Consult a Environment Health Safety expert if necessary.
Personal protective equipment
Eye protection: Tightly fitting safety goggles
Hand protection: Material: Nitrile rubber
Remarks: Impervious gloves Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
Skin and body protection: closed work clothing disposable one-piece overall
Respiratory protection : Engineering controls should always be the primary method of controlling exposures. If respiratory protective equipment is needed for certain activities, the type as well as the corresponding protection factor will depend upon the risk assessment and air concentrations, hazards, physical and warning properties of substances present. Use only respiratory protection that conforms to international/ national standards. Suitable mask with particle filter P3
Protective measures : The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Stability and reactivity
Reactivity: None reasonably foreseeable.
Chemical stability: Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions Hazardous reactions : Risk of dust explosion.
Conditions to avoid: Heat, flames and sparks. To avoid thermal decomposition, do not overheat.
Materials to avoid: Oxidizing and spontaneously flammable products
Hazardous decomposition products: Nitrogen oxides (NOx), Carbon oxides
Disposal considerations
Waste treatment methods
Product: Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. In accordance with National, Federal, State and Local regulations.
Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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