Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
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EC number: 232-152-0 | CAS number: 7789-24-4
Guidance on Safe Use
Administrative data
First-aid measures
Description of First Aid Measures
EYES: Flush with water for at least 15 minutes. If irritation occurs and persists, contact a medical doctor.
SKIN: Wash with plenty of soap and water. Get medical attention if irritation occurs and persists.
INGESTION: Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. If any discomfort persists, obtain medical attention.
INHALATION: Remove to fresh air. If breathing difficulty or discomfort occurs and persists, contact a medical doctor.
Most Important Symptoms and effects, both acute and delayed
Skin and eye irritation.
Indication of any immediate medical attention and special treatment needed
Notes to medical doctor:
This product has low oral, dermal and inhalation toxicity, and is an irritant. Treatment is controlled removal of exposure followed by symptomatic and supportive care.
Fire-fighting measures
Extinguishing media: Dry chemical, CO2, water spray or regular foam.
Special hazards arising from the substance or mixture
Hazardous combustion products: Under fire conditions, may produce toxic fluorides.
General Hazard: No known physical hazard, non-combustible.
Properties contributing to:
Flammability: None
Flashpoint: Not applicable
Flammable limits in air: Upper: Not available; Lower: Not available.
Auto ignition temperature: Not applicable
Sensitivity to static discharge: Not applicable
Sensitivity to static impact: Not applicable
Advice for fire-fighters
Wear full protective clothing and self-contained breathing apparatus (SCBA) approved for fire fighting. This is necessary to protect against the hazards of heat, products of combustion and oxygen deficiency. Do not breathe smoke, gases or vapors generated.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Before cleanup measures begin, review the entire SDS with particular attention to Section 2, Hazards Identification; and Section 8, Exposure Controls/Personal Protection.
Environmental precautions
Do not wash into drains. Dispose of at qualified waste disposal facility.
Methods and material for containment and cleaning up
Sweep up and place in suitable container. Dispose of waste according to local and Federal laws and regulations.
Handling and storage
Precautions for safe handling
Avoid contact with eyes, skin or clothing. Use with adequate ventilation. Wear safety glasses or goggles and rubber gloves. Wash thoroughly after handling.
Conditions for safe storage, including any incompatibilities
Keep away from strong acids. Keep container closed.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- None.
Shipping information
- Proper shipping name and description:
- None.
- Chemical name:
- lithium fluoride
- Language:
- English
Special provisions / remarks
- Special provisions:
- None.
- Remarks:
- Based on available data, the classification criteria are not met.
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- None.
Shipping information
- Proper shipping name and description:
- None.
- Chemical name:
- lithium fluoride
- Language:
- English
Special provisions / remarks
- Remarks:
- Based on available data, the classification criteria are not met.
Marine transport (UN RTDG/IMDG)
- UN number:
- None.
Shipping information
- Proper shipping name and description:
- None.
- Chemical name:
- lithium fluoride
Special provisions / remarks
- Remarks:
- Based on available data, the classification criteria are not met.
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- None.
Shipping information
- Proper shipping name and description:
- None.
- Chemical name:
- lithium fluoride
Special provisions / remarks
- Remarks:
- Based on available data, the classification criteria are not met.
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Exposure controls / personal protection
Exposure controls
Engineering controls: Use local exhaust ventilation to keep airborne concentrations below exposure limits.
Personal protective equipment
Eyes and Face: Safety glasses or goggles
Respiratory: When engineering controls are not adequate, wear a respirator approved for protection against inorganic dusts. (US: NIOSH or MSHA approved; Europe: CEN Class P type)
Protective Clothing: Gloves: Nitrile/Neoprene/PVC/Natural Rubber (permeation breakthrough not detected during 6 hr test)
These glove recommendations should not be used as the absolute basis for glove selection. Actual in-use conditions may vary glove performance from the controlled conditions of laboratory tests. Factors such as concentration and temperature, glove thickness and glove reuse, may affect performance. Other glove requirements, such as length, dexterity, cut, abrasion, puncture and snag resistance, or glove grip need to be considered in making your final selection.
Work Hygienic Practices: Quick-drench eyewash and safety shower.
Stability and reactivity
Reactivity: Reacts with acids to form hydrogen fluoride.
Chemical stability: Stable
Possibility of hazardous reaction: Hazardous polymerization will not occur.
Conditions to avoid: Contact with acids
Incompatible materials: Acids
Hazardous decomposition products: None
Disposal considerations
Use a qualified industrial waste disposal facility. Dispose of waste according to local and Federal laws and regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
