Registration Dossier

Administrative data

First-aid measures

Description of first aid measures:
In case of symptoms or doubt, seek medical advice. No administration though mouth in cases of unconsciousness.
In case of inhalation:
Move affected person into fresh air, keep warm and allow to rest.
In case of irregular breathing / no breathing: artificial respiration.
If unconscious place in recovery position and seek medical advice.

In case of skin (or hair) contact:
Remove contaminated, saturated clothing immediately. Wash immediately with water and soap, rinse off. Consult a physican if problems persist.

In case of eye contact:
Protect uninjured eye. Remove contact lenses.
Flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist if problems persist.

In case of ingestion:
Rinse mouth immediately and drink plenty of water.
Do NOT induce vomiting.
Keep the vomiting person in the recovery position.

If there is a risk of loss of consciousness, place and transport affected person in the recovery position.

Fire-fighting measures

Suitable extinguishing media: Foam, Carbon dioxide (CO2), Dry extinguishing powder, Water spray jet
Unsuitable extinguishing media: Full water jet.

Special hazards arising from the substance:
In case of fire may be liberated: toxic gases (Carbon oxides, Hydrogen chloride gas).

Advice for fire-fighters:
Wear a self-contained breathing apparatus and chemical protective clothing.
Do not inhale vapours and fumes.
Keep containers cool by spaying with water if exposed to fire.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:
for non-emergency personnel:
Provide adequate ventilation.
Stay upwind/keep distance from source.
Avoid contact with skin, eyes and clothing. Do not inhale vapours.
Vapours can accumulate in low areas.
Wear protective gloves/protective clothing/eye protection/face protection.
Remove all sources of ignition, avoid heat and sparks.

for emergency responders:
In case of large amounts wear a self-contained breathing apparatus and chemical protective clothing. No further precautions.

Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Methods and material for containment and cleaning up:
For large amount: dike spillage. Pump off product.
For residues: Pick up with suitable absorbent material (e.g. cloth, fleece).
Gases / vapours / mist knock down with water spray.

Collect it for disposal according to local regulations in the containers provided. Fill and discard into labelled sealable containers. Ventilate and clean affected area after complete removal of the material thoroughly.

Handling and storage

Precautions for safe handling:
Only use the material in places where open light, fire and other sources of ignition have been excluded.
Preparation may charge electrostatically: use only grounded cables when transferring.
Equip the workplace with eye washing bottle and person showers.
Avoid contact with skin and eyes. Do not inhale vapours.
When using do not eat, drink or smoke.

Conditions for safe storage, including any incompatibilities:
Keep only in the original container.
Store in a closed container in a cool, dry, well ventilated place.
To maintain product quality, do not store in heat or direct sunlight.
Advice on joint storage:
No special restrictions for joint storage with other products.

Transport information

Land transport (ADR/RID)

UN number:
UN 1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (1-Chloro-3-methylbut-2-ene)
Chemical name:
1-Chloro-3-methylbut-2-ene
Language:
English
Class:
3
Classification code:
F1
Packaging group:
II
Labels:
3
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (1-Chloro-3-methylbut-2-ene)
Chemical name:
1-Chloro-3-methylbut-2-ene
Language:
English
Class:
3
Classification code:
F1
Packaging group:
II
Labels:
3
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (1-Chloro-3-methylbut-2-ene)
Chemical name:
1-Chloro-3-methylbut-2-ene
Class:
3
Packaging group:
II
EmS code:
F-E, S-E
Labels:
3
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S. (1-Chloro-3-methylbut-2-ene)
Chemical name:
1-Chloro-3-methylbut-2-ene
Class:
3
Packaging group:
II
Labels:
3
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Personal protective equipment:

General safety and hygiene measures:
The usual precautionary measures for handling chemicals should be followed. When using do not eat or drink - no smoking. Wash hands before breaks and at end of work.

Eye / face protection:
Suitable eye protection: Eye glasses with side protection (according to EN 166).

Skin protection:
- Hand protection:
- By long-term hand contact:
Suitable gloves type (recommended protective index 6, corresponding >480 min of permeation time according to EN 374):
Butyl caoutchouc (butyl rubber), 0.7 mm coating thickness
- By short-term hand contact:
Suitable gloves type (recommended at least protective index 2, corresponding >30 min of permeation time according to EN 374):
CR (polychloroprene, chloroprene rubber) 0.5 mm coating thickness.

Supplementary note:
The specifications are based on literature and information of glove manufacturer or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the determined permeation time.

For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.

- Other safety measures:
Wear impervious, flame retardant antistatic protective clothing.

Respiratory protection:
Respiratory protection necessary if insufficient ventilation.
Self-contained respirator (DIN EN 133) or container device with compressed air (DIN EN 137).
Filtering device (full mask or mouthpiece) with filter A (EN 14387).

Environmental exposure controls:
Do not allow to enter drains/surface water/ground-water.
Do not allow to enter into soil/subsoil.

Stability and reactivity

Reactivity
There is no data available on the product.

Chemical stability
There is no data available on the product.

Possibility of hazardous reactions
No dangerous reaction known under conditions of normal use.

Conditions to avoid
Heat, flames and sparks. Extremes of temperature and direct sunlight.

Incompatible materials
Strong oxidizing agents

Hazardous decomposition products
There is no data available on the product.

Disposal considerations

07 WASTES FROM ORGANIC CHEMICAL PROCESSES
07 06 Wastes from the manufacture, formulation, supply and use (MFSU) of fats, grease, soaps, detergents, disinfectants and cosmetics.
07 06 99 Wastes not otherwise specified
07 07 Wastes from the manufacture, formulation, supply and use (MFSU) of fine chemicals and chemical products not otherwise specified.
07 07 99 Wastes not otherwise specified

Appropriate disposal / Package: Contaminated packages must be completely emptied and can be re-used following proper cleaning.