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EC number: 202-870-9 | CAS number: 100-61-8
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Cold water may be used. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before
reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate
medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation
when the inhaled material is toxic, infectious or corrosive. Seek medical attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
Fire-fighting measures
Classes of fires :
B Liquid or melting substances
Suitable extinguishing media :
Extinguishing powder
Carbon dioxide
Instructions :
Cool surrounding containers with water spray.
If possible, take container out of dangerous zone.
Heating causes a rise in pressure, risk of bursting and
explosion.
Shut off sources of ignition.
Stay on upwind side.
Do not allow runoff to get into the sewage system.
Special protective equipment :
Attention! Hazardous decomposition products may occur.
Nitrous gases (nitric oxides)
Wear self-contained breathing apparatus.
Wear a special tightly sealed suit.
Accidental release measures
Evacuate area. Warn affected surroundings.
The hazardous area may only be entered once suitable
protective measures are implemented. Only then can the
hazardous situation be removed.
Wear respiratory protection, eye protection, hand
protection and body protection (see chapter Personal
Protection).
Absorb any spilt liquid with an absorbent (e.g. diatomite,
vermiculite, sand) and dispose of according to regulations.
Pump off larger quantities.
Afterwards ventilate area and wash spill site.
Endangerment of drinking water and environment:
Prevent escape into water, drainage, sewer, or the ground.
A hazard for drinking water sources when only small
quantities get into groundwater.
Inform the responsible authorities.
Maybe a hazard to the surrounding atmosphere if larger
quantities of the substance escape. Inform the authorities.
Handling and storage
TECHNICAL MEASURES - HANDLING
Workplace :
Provision of very good ventilation in the working area.
Especially at higher temperatures.
The floor must be solvent resistant.
The floor should not have a floor drain.
Washing facility at the workplace required.
Eye bath required. These locations must be signposted
clearly.
When handling excessive amounts of the substance an
emergency shower is required.
Equipment :
Use only closed apparatus.
If release of the substance cannot be prevented, then it
should be suctioned off at the point of exit.
Consider emission limit values, a purification of waste
gases if necessary.
Label containers and pipelines clearly.
Advice on safer handling :
Take care to maintain clean working place.
The substance must not be present at workplaces in
quantities above that required for work to be progressed.
Do not leave container open.
Use leak-proof equipment with exhaust for refilling or
transfer.
Do not transport with/using compressed air.
Avoid splashing.
Fill only into labelled container.
Use solvent resistant utensils.
Avoid any contact when handling the substance.
Prevent seepage into flooring (use of a steel tub).
Use an appropriate exterior vessel when transporting in
fragile containers.
Cleaning and maintenance :
Use protective equipment while cleaning if necessary.
Only conduct maintenance and other work on or in the vessel
or closed spaces after obtaining written permission.
Only work with vessels and lines after they have been
thoroughly rinsed.
TECHNICAL MEASURES - STORAGE
Storage :
Keep in locked storage or only make accessible to
specialists or their authorised assistants.
Do not use any food containers - risk of mistake.
Containers have to be labelled clearly and permanently.
Store in the original container as much as possible.
Place fragile vessels in break-proof outer vessels.
Keep container tightly closed.
Keep container in a well-ventilated place.
If more than 200 kg of toxic and highly toxic substances
are to be stored, or if the proportion of highly toxic
substances is more than 50 kg, then follow the rules of
TRGS 514.
Conditions of collocated storage :
Storage class 6.1 A (Combustible toxic substances)
Only substances of the same storage class should be stored
together.
Collocated storage with the following substances is
prohibited:
- Pharmaceuticals, foods, and animal feeds including
additives.
- Infectious, radioactive und explosive substances.
- Compressed, liquefied or pressure dissolved gases.
- Spontaneously flammable substances.
- Substances liberating flammable gases in contact with
water.
- Organic peroxides.
- Oxidizing substances of group 1, TRGS 515.
- Preparations containing ammonium nitrate, TRGS 511.
- Flammable solid substances of storage class 4.1 A.
- Combustible materials, e.g. paper, carton, wood, plastic
film.
Under certain conditions the collocated storage with the
following substances is permitted (For more details see the
Guideline of collocated storage of the VCI):
- Spray bottles.
- Oxidizing substances of group 2 and 3, TRGS 515.
- Combustible solids of storage class 11.
- Flammable solid substances of storage class 4.1 B.
The substance should not be stored with substances with
which hazardous chemical reactions are possible.
TECHNICAL MEASURES - FIRE AND EXPLOSION PROTECTION
Technical, constructive measures :
Substance is combustible.
Fire fighting equipment must be available.
Precaution on handling :
Areas in which the substance is heated to above its flash
point and processed are areas of fire hazard.
No open flames in the range of the working place.
Welding only under supervision.
Work that requires fire or heat may only be carried out
with written permission (e.g. fire permit).
ORGANISATIONAL MEASURES
Instruction on the hazards and the protective measures
using instruction manual (TRGS 555) are required with
signature.
Instruction must be provided before employment and then at
a minimum of once per annum thereafter.
An escape and rescue plan must be prepared when the
location, scale, and use of the work-site so demand.
It must be assured that the workplace limit values are being
maintained.
The measurements must be recorded and kept on file.
The number of employees who work with the hazardous
substance must be kept to a minimum.
Observe the restrictions on juvenile employment as
defined in the "Jugendarbeitsschutzgesetz".
Observe the restrictions on the employment of expectant
and nursing mothers as defined in the
"Mutterschutzverordnung".
Only employees are permitted to enter the work areas.
Signposting to this effect must be displayed.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN2294
Shipping information
- Proper shipping name and description:
- N-Methylaniline
- Chemical name:
- N-Methylaniline
- Language:
- English
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN2294
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN2294
Shipping information
- Proper shipping name and description:
- N-Methylaniline
- Chemical name:
- N-Methylaniline
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN2294
Shipping information
- Proper shipping name and description:
- N-Methylaniline
- Chemical name:
- N-Methylaniline
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Body protection :
Depending on the risk, wear a tight, long apron and boots
or suitable chemical protection clothing.
Respiratory protection :
In an emergency (e.g.: unintentional release of the
substance, exceeding the occupational exposure limit value)
respiratory protection must be worn. Consider the maximum
period for wear.
Respiratory protection: Gas filter A
Colour code: brown
For details on the requirements and the maximum
concentrations for use, consult the "Regeln für den Einsatz
von Atemschutzgeräten" (BGR 190).
(also possible gas filter type B or K)
Respiratory protection: insulating device
Use for concentrations above the usage limits for filter
devices, for oxygen concentrations below 17% volume, or
in circumstances which are unclear.
Eye protection :
Sufficient eye protection should be worn.
Wear glasses with side protection. If the eyes may
potentially come in contact with the liquids, then
chemical safety goggles are necessary.
Hand protection :
Use protective gloves. The glove material must be
sufficiently impermeable and resistant to the substance.
Check the tightness before wear. Gloves should be well
cleaned before being removed, then stored in a well
ventilated location. Pay attention to skin care.
Textile or leather gloves are completely unsuitable.
The following materials are suitable for protective gloves
(Permeation time >= 8 hours):
Fluoro carbon rubber - FKM (0,4 mm)
Protective gloves of the following materials should
not be worn longer than 4 hours continually
(Permeation time >= 4 hours):
Butyl rubber - Butyl (0,5 mm)
Following materials are unsuitable for protective gloves:
Natural rubber/Natural latex - NR
Polychloroprene - CR
Nitrile rubber/Nitrile latex - NBR
Polyvinyl chloride - PVC
The times listed are suggested by measurements taken at
22 degree C and constant contact. Temperatures raised
by warmed substances, body heat, etc. and a weakening of
the effective layer thickness caused by expansion can lead
to a significantly shorter breakthrough time.
In case of doubt contact the gloves' manufacturer.
A 1.5-times increase / decrease in the layer thickness
doubles / halves the breakthrough time. This data only
applies to the pure substance. Transferred to mixtures of
substances, these figures should only be taken as an aid
to orientation.
Skin protection :
Skin protection preparations do not protect sufficiently
against the substance. Wear protective gloves.
The skin must be washed with soap and water before breaks
and at the end of work.
Apply fatty skin-care products after washing.
Industrial hygiene :
If at risk of contamination, foods, beverages and other
articles of consumption must not be stored or consumed at
the work areas. Special areas are to be designated for
these purposes.
Avoid contact with skin. Do not allow the substance or its
solution to dry on the skin. In case of contact wash skin.
Avoid contact with eyes. In case of contact rinse the
affected eye(s).
Avoid inhalation of vapour/dust.
In NO case, drink alcohol.
If it is possible that there has been any contact with the
substance, then do not consume any alcohol even after work.
Avoid contact with clothing. Contaminated clothes must be
exchanged and cleaned carefully.
Provide washrooms with showers and if possible rooms with
separate storage for street clothing and work clothing.
Take care of personal hygiene.
Stability and reactivity
Disposal considerations
Hazardous waste according to Waste Catalogue Ordinance
(AVV).
If there is no way of recycling it must be disposed of in
compliance with the respective national and local
regulations.
Collection of small amounts of substance:
Collect in container for toxic, flammable compounds.
Collection vessels must be clearly labelled with a
systematic description of their contents and with the
hazard symbol and the R and S phrases. Store the vessels in
a well-ventilated location. Entrust them to the appropriate
authorities for disposal.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.