Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 801-260-5 | CAS number: 96383-55-0
Adsorption / desorption
Administrative data
Link to relevant study record(s)
- Endpoint:
- adsorption / desorption: screening
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: GLP guideline study
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 121 (Estimation of the Adsorption Coefficient (Koc) on Soil and on Sewage Sludge using High Performance Liquid Chromatography (HPLC))
- GLP compliance:
- yes (incl. QA statement)
- Remarks:
- Ministry if Health, Welfare and Sport, The Netherlands
- Type of method:
- HPLC estimation method
- Test temperature:
- Column temperature 35 °C
- Details on study design: HPLC method:
- EQUIPMENT
- Apparatus: Acquity UPLC system (Waters, Milford, MA, USA)
- Type, material and dimension of analytical (guard) column: Acquity UPLC HSS Cyano, 100 mm x 2.1 mm i.d., dp = 1.8 µm (Waters)
- Detection system: Acquity UPLC TUV detector (Waters)
MOBILE PHASES
- Type: 55/45 (v/v) methanol/water
DETERMINATION OF DEAD TIME
- Method: by inert substances which are not retained by the column (Formamide)
REFERENCE SUBSTANCES
- Identity:
Acetanilide (CAS 103-84-4)
Monuron (CAS 150-68-5)
2,5-Dichloroaniline (CAS 95-82-9)
Naphthalene (CAS 91-20-3)
Benzoic acid phenylester (CAS 93-99-2)
Fenthion (CAS 55-38-9)
Phenanthrene (CAS 85-01-8)
4,4'-DDT (CAS 50-29-3)
DETERMINATION OF RETENTION TIMES
- Quantity of test substance introduced in the column: injection volume: 5 µL, conc. 91.3 mg/L
- Quantity of reference substances: conc. 1 g/L
REPETITIONS
- Number of determinations: The reference substance and the test substance solutions were injected in duplicate. Blank solutions were analysed by single injection.
EVALUATION
- Calculation of capacity factors k': (tr-t0)/t0; where tr = retention time, t0 = mean column dead time
- Determination of the log Koc value: regression line of calibration curve: log k' = 0.341 x log Koc - 0.780 - Type:
- log Koc
- Value:
- 5.2
- Temp.:
- 35 °C
- Type:
- Koc
- Value:
- 160 000
- Temp.:
- 35 °C
Reference
Description of key information
Koc = 160000 (log Koc = 5.2) (OECD 121, HPLC)
Key value for chemical safety assessment
- Koc at 20 °C:
- 160 000
Additional information
The adsorption potential of 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-chloropropenoic acid ester (CAS 96383-55-0) was determined by the HPLC method according to OECD guideline 121 and GLP (Brekelmans, 2013). Based on the calibration curve with eight reference substances a log Koc value of 5.2 was derived. Thus it can be expected that the substance can adsorb under environmental conditions to sediment and soil particles.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
