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Diss Factsheets

Environmental fate & pathways

Endpoint summary

Administrative data

Description of key information

Not readily biodegradable (37% biodegradation in 28 days; OECD 301 B); based on RA to 2,6-dibromo-4-cyanophenyl octanoate (CAS 1689-99-2)

 

DT50 in sediment at 20 °C: <2 to 4 hours (4.2 to 8.5 hours, recalculated to 12 °C), aerobic conditions; based on RA to 2,6-dibromo-4-cyanophenyl octanoate (CAS 1689-99-2)

 

DT50 in freshwater at 20 °C: >1000 days, aerobic conditions; based RA to 3,5-dibromo-4-hydroxybenzonitrile (CAS 1689-84-5)

 

DT50 in soil at 19.4 °C: 0.14 – 0.62 days (0.28 – 1.25 days, recalculated to 12 °C), aerobic conditions; based on RA to 2,6-dibromo-4-cyanophenyl octanoate (CAS 1689-99-2)

Additional information

Reliable data on the biodegradation of 2,6-dibromo-4-cyanophenyl heptanoate (CAS 56634-95-8) is not available. Therefore the assessment was based on reliable and adequate read-across data available for the structural analogues 2,6-dibromo-4-cyanophenyl octanoate (CAS 1689-99-2) and 3,5-dibromo-4-hydroxybenzonitrile (CAS 1689-84-5).

 

The assessment of the ready biodegradability is based on data available for the structural analogue 2,6-dibromo-4-cyanophenyl octanoate. According to OECD Guideline No 301B, the substance is not readily biodegradable.

 

The assessment of the biodegradation in water/sediment is based on data available for the structural analogue 2,6-dibromo-4-cyanophenyl octanoate in a simulation study, according to GLP and BBA Part IV. In two different sediments the formation of 14CO2 after 100 days accounted for 55.4 and 57.2%, respectively, of the applied radioactivity. The determined DT50 of the test compound ranged from <2 to 4 hours (4.2 to 8.5 hours, recalculated to 12 °C).

Moreover, the degradation of the structural analogue [14C]- 3,5-dibromo-4-hydroxybenzonitrile (CAS 1689-84-5) was investigated in natural water samples incubated in the dark under aerobic conditions at a temperature of 20 ± 2 °C in accordance with the OECD Test Guideline No. 309. The test-item remained stable under the conditions of the test (DT50 = >1000 days).

 

The assessment of the biodegradation in soil is based on data available for the structural analogue 2,6-dibromo-4-cyanophenyl octanoate. Following GLP and OECD Guideline 307, the test substance degraded with a half-life of 0.14 – 0.62 days (0.28 – 1.25 days, recalculated to 12 °C) in three different soils. After 35 days 29.4 – 55.1% of the applied radioactivity were mineralized.