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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
8 July 2008 and 22 August 2008
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Remarks:
Date of inspection: December 2002; Date of certificate: February 2003
Type of method:
effusion method: vapour pressure balance
Temp.:
25 °C
Vapour pressure:
0 Pa
Transition / decomposition:
no
Transition temp.:
25 °C

Summary of Results

Run

Log10[Vp(25ºC)]

1

-6.059

2

-6.005

3

-5.973

4

-5.842

5

-5.915

Mean

-5.959

Vapour Pressure

1.1 x 10-6Pa

The test material did not change in appearance under the conditions used in the determination.

Conclusions:
The vapour pressure of the test material has been determined to be 1.1 E-6 Pa at 25ºC.
Executive summary:

The vapour pressure of 'Paraffin waxes (Fischer-Tropsch), full-range, C15-50 - branched and linear' was determined using a vapour pressure balance. The temperature of the sample was controlled electronically. The mass and temperature readings were recorded automatically into a computer file. After evacuating the system, opening the shutter above the sample oven causes the escaping vapour jet to be directed at the scale pan. The difference in mass readings with the orifice covered and uncovered is proportional to the vapour pressure at the given oven temperature.

The vapour pressure of the test material has been determined to be 1.1 x 10-6 Pa at 25ºC

Description of key information

vapour pressure of the test material (determined using EU Method A.4, vapour pressure balance with measurements being made at several temperatures and linear regression analysis used to calculate the vapour pressure at 25 °C): 1.1 x 10E-6 Pa at 25 ºC (arithmetic mean of five determinations).

Key value for chemical safety assessment

Vapour pressure:
0 Pa
at the temperature of:
25 °C

Additional information

The test material did not change in appearance under the conditions used in the determination.

Predicted vapour pressure values, calculated using a validated QSAR method, are available for individual constituents of the registration substance. Predictions are in the range 9.7E-19 to 2.4 Pa at 25°C.