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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2016-03-31
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
GLP compliance:
no
Type of method:
dynamic method
Remarks:
Vapour Liquid Equilibrium
Key result
Temp.:
ca. 20 °C
Vapour pressure:
0.29 hPa
Remarks on result:
other: calculated by extrapolation
Temp.:
ca. 25 °C
Vapour pressure:
ca. 0.39 hPa
Remarks on result:
other: calculated by extrapolation
Temp.:
ca. 50 °C
Vapour pressure:
ca. 1.56 hPa
Remarks on result:
other: calculated by extrapolation

Results of the thermal stability screening test showed no exothermic effects in the temperature range of 25 -300 °C.

The vapour pressure was measured in the temperature range of 86.4 to 158.4 °C.

No.

Temperature

(°C)

Vapour pressure

(hPa)

Remark

1

86.4

8.2

Measured up

2

114.1

24.8

Measured up

3

129.9

39.7

Measured up

4

142.1

59.5

Measured up

5

149.3

74.6

Measured up

6

158.4

99.5

Measured up

7

152.3

82.1

Measured down

8

144.8

64.8

Measured down

9

135.3

49.8

Measured down

From the measured data points of the vapour pressure curve, the constants A, B and C of the Antoine equation were derived:

log10 p = A + (B / C + θ)

with:

A = 9.3464

B = -2311.13

C = 273.15

Conclusions:
The test item has a vapour pressure of 0.29 hPa at 20°C.
Executive summary:

The vapour pressure of the test item was calculated by extrapolation of the measured vapour pressure curve for the temperatures 20, 25 and 50 °C, according to Regulation EC No. 440/2008 Method A.4. Vapour Pressure and OECD Test Guideline 104 (2006).

The vapour pressure is 0.29 hPa at 20°C, 0.39 hPa at 25°C and 1.56 hPa at 50°C.

Description of key information

The test item has a vapour pressure of 0.29 hPa at 20°C.

Key value for chemical safety assessment

Vapour pressure:
0.29 hPa
at the temperature of:
20 °C

Additional information

For this end point, 1 study is available in which the vapour pressure of the test item was calculated by extrapolation of the measured vapour pressure curve for the temperatures 20, 25 and 50 °C, according to Regulatoin EC No. 440/2008 Method A.4. and OECD Test Guideline 104. The vapour pressure is 0.29 hPa at 20°C, 0.39 hPa at 25°C and 1.56 hPa at 50°C.