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Physical & Chemical properties

Auto flammability

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Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
October 31, 2016 to November 2, 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
GLP compliance:
no
Remarks:
The study described in this report was conducted in a facility which operates in accordance with Good Laboratory Practice principles, however no claim of GLP compliance was intended nor is made for this study.
Specific details on test material used for the study:
Identification: Butyl Phenyl Ether
Appearance/Physical state: Clear colorless liquid
Batch: 22466
Purity: 99.41%
Expiry date: 25 April 2018
Storage conditions: Room temperature in the dark
Key result
Auto-ignition temperature:
458 °C
Atm. press.:
>= 99.9 - <= 100.2 kPa
Remarks on result:
other: Room temperature: 19 to 20 °C. The test item has been determined to have an auto-ignition temperature of 458 ± 5 °C.

Results of the auto-ignition temperature determination are shown in the following table:

Test

temperature

(ºC)

Test volume

(μL)

Ignition delay

(s)

Observations

200 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

250 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

300 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

350

70

>300

No ignition. Grey fumes were emitted.

400

70

>300

No ignition. Grey fumes were emitted.

450

70

>300

No ignition. Grey fumes were emitted.

500

70

3

An orange flame. Grey fumes were emitted.

490 (clean flask)

70

5

An orange flame. Grey fumes were emitted.

480 (clean flask)

70

6

An orange flame. Grey fumes were emitted.

470 (clean flask)

70

>300

No ignition. Grey fumes were emitted.

472

70

11

An orange flame. Grey fumes were emitted.

470 (clean flask)

200

5

An orange flame. Grey fumes were emitted.

468 (clean flask)

200

7

An orange flame. Grey fumes were emitted.

466 (clean flask)

200

5

An orange flame. Grey fumes were emitted.

464 (clean flask)

200

6

An orange flame. Grey fumes were emitted.

462 (clean flask)

200

8

An orange flame. Grey fumes were emitted.

460 (clean flask)

200

7

An orange flame. Grey fumes were emitted.

458 (clean flask)

200

7

An orange flame. Grey fumes were emitted.

456 (clean flask)

200

>300

No ignition. Grey fumes were emitted.

456 (clean flask)

400

>300

No ignition. Grey fumes were emitted.

456 (clean flask)

600

>300

No ignition. Grey fumes were emitted.

456 (clean flask)

800

>300

No ignition. Grey fumes were emitted.

456 (clean flask)

1000

>300

No ignition. Grey fumes were emitted.

Room temperature: 19 to 20 °C

Atmospheric pressure: 99.9 to 100.2 kPa

Conclusions:
Room temperature: 19 to 20 °C
Atmospheric pressure: 99.9 to 100.2 kPa
The test item has been determined to have an auto-ignition temperature of 458 ± 5 °C.
Executive summary:

Room temperature: 19 to 20 °C

Atmospheric pressure: 99.9 to 100.2 kPa

The test item has been determined to have an auto-ignition temperature of 458 ± 5 °C.

Description of key information

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
458 °C

Additional information

Room temperature: 19 to 20 °C

Atmospheric pressure: 99.9 to 100.2 kPa

The test item has been determined to have an auto-ignition temperature of 458 ± 5 °C.