Registration Dossier

Administrative data

First-aid measures

General information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
After inhalation of dust
Supply fresh air. If required, provide artificial respiration. Consult doctor if symptoms persist.
In case of unconsciousness place patient securely in side position for transportation.
After skin contact
remove any contaminated clothing.
Wash affected area with water and soap immediately and rinse thoroughly.
After eye contact
Rinse opened eye for several minutes under running water. if symptoms persist, consult a doctor.
After swallowing
Rinse mouth with water
Call for a doctor immediately.
Show this safety data sheet

Fire-fighting measures

Suitable extinguishing agents
CO2, powder or water spray. Fight larger fire with alcohol resistant foam.
For safety reasons unsuitable extinguishing agents Water with full jet. Protective equipment: Use respiratory protective equipment.
Additional information
Smoldering fire can go without oxygen, damp with water. Possible re-ignition if fresh surface exposed to air.

Accidental release measures

Person-related safety precautions:
Avoid formation of dust.
Wear suitable respiratory protective equipment
Keep away from ignition sources
Measures for environmental protection:
Do not allow to enter sewers / surface or ground water.
In case of spillage to water course or public sewers inform responsible authorities.
Measures for cleaning/collecting:
Arrange for recovery or disposal in suitable containers.
Dispose contaminated material as hazardous waste.
Ensure adequate ventilation.

Handling and storage

Handling
Information for safe handling:
Thorough dedusting.
Ensure good ventilation/extraction at the workplace.
Open and handle receptacle with care.
Information about fire - and explosion protection:
May form an explosive dust/air mixture.
Use only in explosion protected area.
Keep ignition sources away - Do not smoke.
Keep respiratory protective equipment available.
Storage
Conditions to be met by storerooms and receptacles: Keep container closed
Further information about storage conditions:
Store in dry condition
Keep receptacle tightly sealed.

Transport information

Land transport (ADR/RID)

UN number:
UN 2989
Shippingopen allclose all
Class:
4.1
Classification code:
F3
Packaging group:
II
Labels:
4.1
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 2989
Shippingopen allclose all
Class:
4.1
Classification code:
F3
Packaging group:
II
Labels:
4.1
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 2989
Proper shipping name and description:
LEAD PHOSPHITE, DIBASIC
Chemical name:
trilead dioxide phosphonate
Class:
4.1
Packaging group:
II
EmS code:
F-A, S-G
Labels:
4.1
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 2989
Proper shipping name and description:
LEAD PHOSPHITE, DIBASIC
Chemical name:
trilead dioxide phosphonate
Class:
4.1
Packaging group:
II
Labels:
4.1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Additional information about design of technical facilities: Local exhaust
Ingredients with limit values that require monitoring at the workplace:
MAK-list, lead and his compounds:
Austria , 0,10 mg/m³
Germany, 0,10 mg/m³
EC , 0,15 mg/m³
UK , 0,15 mg/m³
Belgium , 0,15 mg/m³
Spain , 0,15 mg/m³
BAT-list, lead and his compounds:
EU , 70 µg/dl
Austria , 70µg/dl
45µg/dl (for women, age below 45 year`s)
Germany ,40µg/dl
30µg/dl (for woman, age below 45 year`s)
Additional information: The lists valid during the making were used as basis.
Personal protective equipment
General protective and hygienic measures
Do not eat, drink, smoke or sniff whilst working.
Shower or take a bath at the end of work.
Keep away from foodstuffs, beverages and feed.
Immediately remove all contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Respiratory protection:
Suitable respiratory protective device recommended.
In case of brief exposure or low pollution use dust mask or half mask with particle filter P2
Protection of hands:
Protective gloves.
Material of gloves: Neoprene or Leather gloves
Eye protection: Safety glasses
Body protection: Protective work clothing.

Stability and reactivity

Hazardous reactions:
Risk of dust explosion.
Hazardous decomposition products:
No decomposition if used as directed.
Materials to avoid:
Strong oxidizing agents

Disposal considerations

Must be disposed as hazardous chemical waste. Do not allow product to reach sewage system.
European waste catalogue:
06 03 13* solid salts and solutions containing heavy metals or
06 04 05* wastes containing other heavy metals