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EC number: 232-433-8 | CAS number: 8028-48-6 Extractives and their physically modified derivatives such as tinctures, concretes, absolutes, essential oils, oleoresins, terpenes, terpene-free fractions, distillates, residues, etc., obtained from Citrus sinensis, Rutaceae.
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Guidance on Safe Use
Administrative data
First-aid measures
General information: If health disorder happens, call for medical help immediately. Immediately remove any clothing soiled by the product.
After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing: Do not induce vomiting; call for medical help immediately.
Fire-fighting measures
Extinguishing media
Suitable extinguishing agents: CO2, alcohol resistant foam, powder, water spray.
For safety reasons unsuitable extinguishing agents: Water with full jet
Special hazards arising from the substance or mixture In case of fire, the following can be released: Carbon monoxide (CO) Carbon dioxide (CO2) Smoke and soot
Do not use water with full jet to prevend fire spreading.
Advice for firefighters
Protective equipment: Wear self-contained respiratory protective device.
Additional information Cool endangered receptacles with water spray. Collect contaminated fire fighting water separately. It must not enter the sewage system. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Follow safety measures in chapter "Handling and Storage" and "Exposure contros/personal protection".
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow to penetrate the ground/soil. Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Wipe up little amounts with absorbent material like cloth or pulp. Water and cleansing agent Absorb with incombustible liquid-binding material (sand, diatomite, universal binders). Dispose of contaminated material as waste according to "Disposal considerations".
Ensure adequate ventilation. Keep ignition source away, do not smoke and avoid flames.
Handling and storage
Precautions for safe handling
personal protection equipment see point "Exposure controls/personal protection".
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about fire - and explosion protection:
Fumes can combine with air to form an explosive mixture.
Moistened solids (e.g. cloth, pulp, filter panel, binder) has to be stored hermetically sealed and/or watered and proper disposed.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:
Store only in unopened original receptacles.
Provide solvent resistant, sealed floor.
Information about storage in one common storage facility:
Store away from oxidising agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Storage class: 3
Classification according to Betriebssicherheitsverordnung (BetrSichV) Flammable liquid
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 1169
1993
2319
Shipping information
- Proper shipping name and description:
- UN1169 - Extracts, Aromatic, Liquid
UN1993 - Flammable Liquid, N.O.S. (Terpene hydrocarbons, mixture)
UN2319 - Terpene Hydrocarbons, N.O.S.
- Labels:
- 3
Symbol fish and tree
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 1169
1993
2319
Shipping information
- Proper shipping name and description:
- UN1169 - Extracts, Aromatic, Liquid
UN1993 - FLAMMABLE LIQUID, N.O.S. (d-limonene), ENVIRONMENTALLY HAZARDOUS
UN2319 - Terpene Hydrocarbons, N.O.S.
- Labels:
- 3
Symbol fish and tree
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 1993
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, N.O.S. (d-limonene, alpha-PINENE), MARINE POLLUTANT
- Labels:
- 3
Symbol fish and tree - Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 1169
1993
2319
Shipping information
- Proper shipping name and description:
- UN1169 - Extracts, Aromatic, Liquid
UN1993 - FLAMMABLE LIQUID, N.O.S. (d-limonene)
UN2319 - Terpene Hydrocarbons, N.O.S.
- Labels:
- 3
Remarksopen allclose all
Additional transport information
Additional information
- Special provisions / remarks / other:
- Product contains environmentally hazardous substances: d-limonene
Exposure controls / personal protection
Personal protective equipment:
General protective and hygienic measures:
Use personal protective equipment depending on concentration and amount of hazardous substance.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
Respiratory protection:
Suitable respiratory protection:
filter class A2 (brown colour).
Use the rules for application of respiratory protection systems.
In case of brief exposure or low pollution use respiratory filter device.
In case of intensive or longer exposure use self-contained respiratory protective device.
Protection of hands:
Preventive skin protection by use of skin-protecting agents is recommended.
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Penetration time of glove material > 480 minutes at layerthickness of 0,425 millimeter (Sol-Vex 37-695/Ansell).
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
For the permanent contact gloves made of the following materials are suitable: Nitrile rubber, NBR
E.g. following product: Sol-Vex (37-695) from Ansell.
As protection from splashes gloves made of the following materials are suitable:Nitrile rubber, NBR
Eye protection: Tightly sealed goggles according to EN 166:2001
Body protection: Protective work clothing
Stability and reactivity
Thermal decomposition / conditions to be avoided: Heating causes vaporisation and formation of ignitable atmosphere is possible.
Materials to be avoided:
Dangerous reactions: Formation of explosive gas mixture with air possible. In case of unpropitious storing conditions (air admission, heat accumulation) selfignition is possible for moistened solids (e.g. cloth, pulp, filter panel, binder). Reacts violently with oxidizing agents.
Dangerous decomposition products: No dangerous decomposition products expected by intended use.
Disposal considerations
Product:
Recommendation: Recycling is prefered to disposal or burning. Disposal must be made according to official regulations. Must not be disposed together with household garbage. Do not allow product to reach sewage system. European waste catalogue: e.g. 02 03 03 wastes from solvent extraction.
Uncleaned packaging:
Recommendation: Empty contaminated packagings thoroughly. They may be recycled after thorough and proper cleaning. Packagings that may not be cleansed are disposed of in the same manner as the product.
Contaminated solids:
Recommendation: Moistende solids (e.g. cloth, pulp, filter panels, binder) can be burnt after consulting with the waste disposal facility operator and the pertinent authorities and adhering to the necessary technical regulations. European waste catalogue: e.g. 15 02 02 Filter and absorption materials contaminated with hazardous agents.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.