Registration Dossier
Registration Dossier
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EC number: 225-207-5 | CAS number: 4717-96-8
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
A Description of first aid measures
General advice: In the case of accident or if you feel unwell, seek medical ad-vice immediately. When symptoms persist or in all cases of doubt seek medical advice.
Protection of first-aiders: First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists.
If inhaled:
If inhaled, remove to fresh air.
If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Get medical attention immediately.
In case of skin contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical attention immediately.
Wash clothing before reuse.
Thoroughly clean shoes before reuse.
In case of eye contact:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Get medical attention immediately.
If swallowed:
If swallowed, DO NOT induce vomiting.
If vomiting occurs have person lean forward.
Call a physician or poison control centre immediately.
Rinse mouth thoroughly with water.
Never give anything by mouth to an unconscious person.
B Most important symptoms and effects, both acute and delayed
Risks:
Causes serious eye damage.
Causes severe burns.
Causes digestive tract burns.
C Indication of any immediate medical attention and special treatment needed
Treatment:
Treat symptomatically and supportively.
(Source: substance SDS, version 02)
General advice: In the case of accident or if you feel unwell, seek medical ad-vice immediately. When symptoms persist or in all cases of doubt seek medical advice.
Protection of first-aiders: First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists.
If inhaled:
If inhaled, remove to fresh air.
If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Get medical attention immediately.
In case of skin contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical attention immediately.
Wash clothing before reuse.
Thoroughly clean shoes before reuse.
In case of eye contact:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Get medical attention immediately.
If swallowed:
If swallowed, DO NOT induce vomiting.
If vomiting occurs have person lean forward.
Call a physician or poison control centre immediately.
Rinse mouth thoroughly with water.
Never give anything by mouth to an unconscious person.
B Most important symptoms and effects, both acute and delayed
Risks:
Causes serious eye damage.
Causes severe burns.
Causes digestive tract burns.
C Indication of any immediate medical attention and special treatment needed
Treatment:
Treat symptomatically and supportively.
(Source: substance SDS, version 02)
Fire-fighting measures
A Extinguishing media
Suitable extinguishing media:
Water spray
Foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing media:
High volume water jet
B Special hazards arising from the substance or mixture
Specific hazards during fire-fighting:
Do not use a solid water stream as it may scatter and spread fire.
Flash back possible over considerable distance.
Vapours may form explosive mixtures with air.
Exposure to combustion products may be a hazard to health.
Hazardous combustion products:
Carbon oxides
C Advice for firefighters
Special protective equipment for firefighters:
In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
Specific extinguishing methods:
Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do so.
Evacuate area.
(Source: substance SDS, version 02)
Suitable extinguishing media:
Water spray
Foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing media:
High volume water jet
B Special hazards arising from the substance or mixture
Specific hazards during fire-fighting:
Do not use a solid water stream as it may scatter and spread fire.
Flash back possible over considerable distance.
Vapours may form explosive mixtures with air.
Exposure to combustion products may be a hazard to health.
Hazardous combustion products:
Carbon oxides
C Advice for firefighters
Special protective equipment for firefighters:
In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
Specific extinguishing methods:
Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do so.
Evacuate area.
(Source: substance SDS, version 02)
Accidental release measures
A Personal precautions, protective equipment and emergency procedures
Personal precautions:
Remove all sources of ignition.
Ventilate the area.
Use personal protective equipment.
Follow safe handling advice and personal protective equip-ment recommendations.
B Environmental precautions
Environmental precautions::
Discharge into the environment must be avoided.
Prevent further leakage or spillage if safe to do so.
Prevent spreading over a wide area (e.g. by containment or oil barriers).
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages cannot be contained.
C Methods and material for containment and cleaning up
Methods for cleaning up:
Non-sparking tools should be used.
Soak up with inert absorbent material.
Suppress (knock down) gases/vapours/mists with a water spray jet.
For large spills, provide dyking or other appropriate contain-ment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container.
Clean up remaining materials from spill with suitable absorbent.
Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to deter-mine which regulations are applicable.
(Source: substance SDS, version 02)
Personal precautions:
Remove all sources of ignition.
Ventilate the area.
Use personal protective equipment.
Follow safe handling advice and personal protective equip-ment recommendations.
B Environmental precautions
Environmental precautions::
Discharge into the environment must be avoided.
Prevent further leakage or spillage if safe to do so.
Prevent spreading over a wide area (e.g. by containment or oil barriers).
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages cannot be contained.
C Methods and material for containment and cleaning up
Methods for cleaning up:
Non-sparking tools should be used.
Soak up with inert absorbent material.
Suppress (knock down) gases/vapours/mists with a water spray jet.
For large spills, provide dyking or other appropriate contain-ment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container.
Clean up remaining materials from spill with suitable absorbent.
Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to deter-mine which regulations are applicable.
(Source: substance SDS, version 02)
Handling and storage
7.1 Precautions for safe handling
Technical measures:
See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation:
Use with local exhaust ventilation.
Use only in an area equipped with explosion-proof exhaust ventilation if advised by assessment of the local exposure potential
Advice on safe handling:
Do not get on skin or clothing.
Do not breathe vapours or spray mist.
Do not swallow.
Do not get in eyes.
Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure assessment
Non-sparking tools should be used.
Keep container tightly closed.
Keep away from heat and sources of ignition.
Take precautionary measures against static discharges.
Take care to prevent spills, waste and minimize release to the environment.
Hygiene measures:
Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.
B Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers:
Keep in properly labelled containers. Store locked up. Keep tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition.
Advice on common storage:
Do not store with the following product types:
Strong oxidizing agents
Organic peroxides
Flammable solids
Pyrophoric liquids
Pyrophoric solids
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases
Explosives
Gases
(Source: substance SDS, version 02)
Technical measures:
See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation:
Use with local exhaust ventilation.
Use only in an area equipped with explosion-proof exhaust ventilation if advised by assessment of the local exposure potential
Advice on safe handling:
Do not get on skin or clothing.
Do not breathe vapours or spray mist.
Do not swallow.
Do not get in eyes.
Handle in accordance with good industrial hygiene and safety practice, based on the results of the workplace exposure assessment
Non-sparking tools should be used.
Keep container tightly closed.
Keep away from heat and sources of ignition.
Take precautionary measures against static discharges.
Take care to prevent spills, waste and minimize release to the environment.
Hygiene measures:
Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.
B Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers:
Keep in properly labelled containers. Store locked up. Keep tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition.
Advice on common storage:
Do not store with the following product types:
Strong oxidizing agents
Organic peroxides
Flammable solids
Pyrophoric liquids
Pyrophoric solids
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases
Explosives
Gases
(Source: substance SDS, version 02)
Transport information
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SpecialProvisionsopen allclose all
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Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
A Exposure controls
Engineering measures:
Minimize workplace exposure concentrations.
Use only in an area equipped with explosion-proof exhaust ventilation if advised by assessment of the local exposure potential
Use with local exhaust ventilation.
Personal protective equipment:
Eye protection:
Wear the following personal protective equipment:
Chemical resistant goggles must be worn.
If splashes are likely to occur, wear: Face-shield
Equipment should conform to BS EN 166
Hand protection:
Material: Chemical-resistant gloves
Remarks:
Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous sub-stance and specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Take note that the product is flammable, which may impact the selection of hand protection. Wash hands before breaks and at the end of workday.
Skin and body protection:
Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential.
Wear the following personal protective equipment:
Flame retardant antistatic protective clothing, unless as-sessment demonstrates that the risk of explosive atmos-pheres or flash fires is low.
Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).
Respiratory protection:
Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.
Filter type: Organic vapour type (A)
(Source: substance SDS, version 02)
Engineering measures:
Minimize workplace exposure concentrations.
Use only in an area equipped with explosion-proof exhaust ventilation if advised by assessment of the local exposure potential
Use with local exhaust ventilation.
Personal protective equipment:
Eye protection:
Wear the following personal protective equipment:
Chemical resistant goggles must be worn.
If splashes are likely to occur, wear: Face-shield
Equipment should conform to BS EN 166
Hand protection:
Material: Chemical-resistant gloves
Remarks:
Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous sub-stance and specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Take note that the product is flammable, which may impact the selection of hand protection. Wash hands before breaks and at the end of workday.
Skin and body protection:
Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential.
Wear the following personal protective equipment:
Flame retardant antistatic protective clothing, unless as-sessment demonstrates that the risk of explosive atmos-pheres or flash fires is low.
Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).
Respiratory protection:
Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.
Filter type: Organic vapour type (A)
(Source: substance SDS, version 02)
Stability and reactivity
A Reactivity
Not classified as a reactivity hazard.
B Chemical stability
Stable under normal conditions.
C Possibility of hazardous reactions
Hazardous reactions: Highly flammable liquid and vapour. Vapours may form explosive mixture with air. Can react with strong oxidizing agents.
D Conditions to avoid
Conditions to avoid: Heat, flames and sparks.
E Incompatible materials
Materials to avoid: Oxidizing agents
F Hazardous decomposition products
No hazardous decomposition products are known.
(Source: substance SDS, version 02)
Not classified as a reactivity hazard.
B Chemical stability
Stable under normal conditions.
C Possibility of hazardous reactions
Hazardous reactions: Highly flammable liquid and vapour. Vapours may form explosive mixture with air. Can react with strong oxidizing agents.
D Conditions to avoid
Conditions to avoid: Heat, flames and sparks.
E Incompatible materials
Materials to avoid: Oxidizing agents
F Hazardous decomposition products
No hazardous decomposition products are known.
(Source: substance SDS, version 02)
Disposal considerations
Waste treatment methods
Product:
Dispose of in accordance with local regulations.
According to the European Waste Catalogue, Waste Codes are not product specific, but application specific.
Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
Contaminated packaging:
Empty containers should be taken to an approved waste han-dling site for recycling or disposal.
Empty containers retain residue and can be dangerous.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury and/or death.
If not otherwise specified: Dispose of as unused product.
(Source: substance SDS, version 02)
Product:
Dispose of in accordance with local regulations.
According to the European Waste Catalogue, Waste Codes are not product specific, but application specific.
Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
Contaminated packaging:
Empty containers should be taken to an approved waste han-dling site for recycling or disposal.
Empty containers retain residue and can be dangerous.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury and/or death.
If not otherwise specified: Dispose of as unused product.
(Source: substance SDS, version 02)
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
