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EC number: 279-420-3 | CAS number: 80206-82-2
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Short-term toxicity to fish
Administrative data
Link to relevant study record(s)
- Endpoint:
- short-term toxicity to fish
- Type of information:
- (Q)SAR
- Adequacy of study:
- key study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- results derived from a valid (Q)SAR model and falling into its applicability domain, with adequate and reliable documentation / justification
- Justification for type of information:
- QSAR prediction: US EPA accepted QSAR method for chemicals properties assessment.
- Qualifier:
- according to guideline
- Guideline:
- other: QSAR
- Principles of method if other than guideline:
- EPI Suite v 4.1/ECOSARv1.00
- GLP compliance:
- no
- Remarks:
- not applicable to QSAR models
- Analytical monitoring:
- not specified
- Vehicle:
- not specified
- Test organisms (species):
- other: Fishes species
- Details on test organisms:
- no further information
- Test type:
- other: QSAR model
- Water media type:
- freshwater
- Limit test:
- no
- Total exposure duration:
- 96 h
- Hardness:
- not applicable. QSAR model
- Test temperature:
- not applicable. QSAR model
- pH:
- not applicable. QSAR model
- Dissolved oxygen:
- not applicable. QSAR model
- Salinity:
- not applicable. QSAR model
- Details on test conditions:
- CAS Number:80206-82-2
SMILES : CCCCCCCCCCCCO
CHEM : Alcohols, C12-14
MOL FOR: C12 H26 O1
MOL WT : 186.34
Log Kow: 4.77 (KowWin estimate)
Wat Sol: 4 mg/L (experimental database) - Reference substance (positive control):
- no
- Duration:
- 96 h
- Dose descriptor:
- LC50
- Effect conc.:
- 0.525 mg/L
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: (Q)SAR prediction
- Remarks on result:
- other: non-toxic at the limit of solubility, as determined by (Q)SAR
- Duration:
- 96 h
- Dose descriptor:
- LC50
- Effect conc.:
- 131.25 mg/L
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: (Q)SAR prediction
- Remarks on result:
- other: Predicted, at an water solubility loading rates of 1000 mg/L
- Details on results:
- A 96 h LC50 value of 0.525 mg/L has been calculated for the effects of the test substance on the mortality of the fish taxonomic group. This result signifies that the test substance is not expected to be toxic at the limit of solubility.
A reliable 96 h LC50 value of 131.25 mg/L has been calculated for the effects of the test substance towards fish taxonomic group.Therefore the test substance has been predicted to be non toxic at the limit of solubility, so the LC50 is 0.525 mg/L. Predicted to be non-toxic at the limit of solubility.
The water solubility of the Alcohols, C12-14 is 4.0 mg/l at 1000 mg/L loading rate at 25 degC (experimental database).This is about 250 times the water solubility of the test substance. - Results with reference substance (positive control):
- A 96 h LC50 value of 0.525 mg/L has been calculated for the effects of the test substance on the mortality of the fish taxonomic group. This result signifies that the test substance is not expected to be toxic at the limit of solubility.
- Validity criteria fulfilled:
- yes
- Remarks:
- US EPA accepted QSAR method for chemicals properties assessment.
- Conclusions:
- A 96 h LC50 value of 0.525 mg/L has been calculated for the effects of the test substance on the mortality of the fish taxonomic group. This result signifies that the test substance is not expected to be toxic at the limit of solubility.
A reliable 96 h LC50 value of 131.25 mg/L has been calculated for the effects of the test substance towards fish taxonomic group.Therefore the test substance has been predicted to be non toxic at the limit of solubility, so the LC50 is 0.525 mg/L. Predicted to be non-toxic at the limit of solubility.
The water solubility of the Alcohols, C12-14 is 4.0 mg/l at 1000 mg/L loading rate at 25 degC (experimental database).This is about 250 times the water solubility of the test substance. - Executive summary:
- The ECOSAR QSAR model predicts that the 96hr LC50 for freshwater fish would to be 0.525 mg/l .This result signifies that the test substance is not expected to be toxic at the limit of solubility.This result is above the LoS (limit of solubility), therefore the substance is non-toxic at the limit of LoS and LC50 is >LoS. The water solubility of the Alcohols, C12-14 is 4.0 mg/l at 1000 mg/L loading rate at 25 degC (experimental database). This is about 250 times the water solubility of the test substance.
- Endpoint:
- short-term toxicity to fish
- Type of information:
- (Q)SAR
- Adequacy of study:
- key study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- results derived from a valid (Q)SAR model and falling into its applicability domain, with adequate and reliable documentation / justification
- Justification for type of information:
- QSAR prediction: US EPA accepted QSAR method for chemicals properties assessment.
- Qualifier:
- according to guideline
- Guideline:
- other: QSAR
- Principles of method if other than guideline:
- EPI Suite v 4.1/ECOSARv1.00
- GLP compliance:
- no
- Remarks:
- not applicable to QSAR models
- Analytical monitoring:
- not specified
- Vehicle:
- not specified
- Test organisms (species):
- other: Fishes species
- Details on test organisms:
- no further information
- Test type:
- other: QSAR model
- Water media type:
- saltwater
- Limit test:
- no
- Total exposure duration:
- 96 h
- Hardness:
- not applicable. QSAR model
- Test temperature:
- not applicable. QSAR model
- pH:
- not applicable. QSAR model
- Dissolved oxygen:
- not applicable. QSAR model
- Salinity:
- not applicable. QSAR model
- Details on test conditions:
- CAS Number:80206-82-2
SMILES : CCCCCCCCCCCCO
CHEM : Alcohols, C12-14
MOL FOR: C12 H26 O1
MOL WT : 186.34
Log Kow: 4.77 (KowWin estimate)
Wat Sol: 4 mg/L (experimental database) - Reference substance (positive control):
- no
- Duration:
- 96 h
- Dose descriptor:
- LC50
- Effect conc.:
- 0.591 mg/L
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: (Q)SAR prediction
- Remarks on result:
- other: non-toxic at the limit of solubility, as determined by (Q)SAR
- Duration:
- 96 h
- Dose descriptor:
- LC50
- Effect conc.:
- 147.75 mg/L
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- other: (Q)SAR prediction
- Remarks on result:
- other: Predicted, at an water solubility loading rates of 1000 mg/L
- Details on results:
- A 96 h LC50 value of 0.591 mg/L has been calculated for the effects of the test substance on the mortality of the fish taxonomic group. This result signifies that the test substance is not expected to be toxic at the limit of solubility.
A reliable 96 h LC50 value of 147.75 mg/L has been calculated for the effects of the test substance towards fish taxonomic group.Therefore the test substance has been predicted to be non toxic at the limit of solubility, so the LC50 is 0.591 mg/L. Predicted to be non-toxic at the limit of solubility.
The water solubility of the Alcohols, C12-14 is 4.0 mg/l at 1000 mg/L loading rate at 25 degC (experimental database).This is about 250 times the water solubility of the test substance. - Results with reference substance (positive control):
- A 96 h LC50 value of 0.591 mg/L has been calculated for the effects of the test substance on the mortality of the fish taxonomic group. This result signifies that the test substance is not expected to be toxic at the limit of solubility.
- Validity criteria fulfilled:
- yes
- Remarks:
- US EPA accepted QSAR method for chemicals properties assessment.
- Conclusions:
- A 96 h LC50 value of 0.591 mg/L has been calculated for the effects of the test substance on the mortality of the fish taxonomic group. This result signifies that the test substance is not expected to be toxic at the limit of solubility.This result is above the LoS (limit of solubility), therefore the substance is non-toxic at the limit of LoS and LC50 is >LoS.
A reliable 96 h LC50 value of 147.75 mg/L has been calculated for the effects of the test substance towards fish taxonomic group.Therefore the test substance has been predicted to be non toxic at the limit of solubility, so the LC50 is 0.591 mg/L. Predicted to be non-toxic at the limit of solubility.
The water solubility of the Alcohols, C12-14 is 4.0 mg/l at 1000 mg/L loading rate at 25 degC (experimental database).This is about 250 times the water solubility of the test substance. - Executive summary:
- The ECOSAR QSAR model predicts that the 96hr LC50 for marinewater fish would to be 0.591 mg/l .This result signifies that the test substance is not expected to be toxic at the limit of solubility.This result is above the LoS (limit of solubility), therefore the substance is non-toxic at the limit of LoS and LC50 is >LoS. The water solubility of the Alcohols, C12-14 is 4.0 mg/l at 1000 mg/L loading rate at 25 degC (experimental database). This is about 250 times the water solubility of the test substance.
- Endpoint:
- short-term toxicity to fish
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- study well documented, meets generally accepted scientific principles, acceptable for assessment
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 203 (Fish, Acute Toxicity Test)
- Principles of method if other than guideline:
- German standard methods for the examination of water, waste water and sludge; bioassays (group L); determination of the effect of substances in water on fish-fish test (L15). Test method corresponds to OECD Guideline 203.
- GLP compliance:
- yes
- Analytical monitoring:
- no
- Vehicle:
- yes
- Test organisms (species):
- Leuciscus idus
- Details on test organisms:
- Species: Leuciscus idus (Fish, fresh water)
- Test type:
- static
- Water media type:
- freshwater
- Limit test:
- no
- Total exposure duration:
- 48 h
- Post exposure observation period:
- none reported
- Test temperature:
- 21.4 - 23.8C
- pH:
- pH mean: 6.6-7.5
- Dissolved oxygen:
- 65-100% saturation
- Salinity:
- Not Applicable
- Nominal and measured concentrations:
- Concentrations: 0, 3000, 5000, 10000 mg/l
Renewal of test solution: daily
Exposure vessel type: 5 L aquarium - Details on test conditions:
- Number of replicates: 1
Fish per replicate: 10
Test temperature: 21.4 - 23.8C
Dissolved oxygen: 65-100% saturation
pH mean: 6.6-7.5
Adjustment of pH: not reported
Photoperiod: not reported
DURATION OF THE TEST: 48 h
TEST PARAMETER: mortality - Reference substance (positive control):
- no
- Duration:
- 48 h
- Dose descriptor:
- LC50
- Effect conc.:
- > 5 000 mg/L
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- mortality (fish)
- Remarks on result:
- other: non-toxic at the limit of solubility
- Duration:
- 48 h
- Dose descriptor:
- LC0
- Effect conc.:
- 3 000 mg/L
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- mortality (fish)
- Duration:
- 48 h
- Dose descriptor:
- LC100
- Effect conc.:
- > 10 000 mg/L
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- mortality (fish)
- Details on results:
- RESULTS: EXPOSED
LC0 = 3000 mg/l
LC50 > 5000 mg/l
LC100 > 10000 mg/l
Based on nominal concentrations
RESULTS: CONTROL
Number/% showing adverse effects: Not reported - Validity criteria fulfilled:
- yes
- Conclusions:
- A 48 h LC50 >5000 mg/L has been determined for the effects of Alcohols, C12-14 on the mortality of the freshwater fish Leuciscus idus . However this result is above the LoS (limit of solubility), therefore the substance is non-toxic at the limit of LoS and LC50 is >LoS.
- Executive summary:
A 48 h LC50 >5000 mg/L has been determined for the effects of Alcohols, C12-14 on the mortality of the freshwater fish Leuciscus idus . However this result is above the LoS (limit of solubility), therefore the substance is non-toxic at the limit of LoS and LC50 is >LoS.
- Endpoint:
- short-term toxicity to fish
- Type of information:
- other: published data
- Adequacy of study:
- weight of evidence
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- study well documented, meets generally accepted scientific principles, acceptable for assessment
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 203 (Fish, Acute Toxicity Test)
- Deviations:
- no
- GLP compliance:
- not specified
- Analytical monitoring:
- no
- Vehicle:
- yes
- Test organisms (species):
- Danio rerio (previous name: Brachydanio rerio)
- Details on test organisms:
- TEST ORGANISM
- Common name: rainbow trout
- Strain: Oncorhynchus mykiss
- Source: Donnington fish Farm, Upper Swell, Gloucestershire, UK
- Length at study initiation (length definition, mean, range and SD): 4.5 cm (SD = 0.2)
- Weight at study initiation (mean and range, SD): 1.2 g (SD = 0.26)
- Feeding during test: no the animals were starved from 24 h prior to the study initiation
ACCLIMATION
- Acclimation period: 7 days
- Acclimation conditions (same as test or not): yes
- Type and amount of food: commercial trout pellets
- Health during acclimation (any mortality observed): 2% mortality - Test type:
- semi-static
- Water media type:
- freshwater
- Limit test:
- yes
- Total exposure duration:
- 96 h
- Post exposure observation period:
- none reported
- Hardness:
- none reported
- Test temperature:
- none reported
- pH:
- range: 7.4-7.9
- Dissolved oxygen:
- none reported
- Salinity:
- Not Applicable
- Duration:
- 96 h
- Dose descriptor:
- LC50
- Effect conc.:
- > 10 mg/L
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- mortality (fish)
- Remarks on result:
- other: non-toxic at the limit of solubility
- Details on results:
- Five acute toxicity tests were conducted with hexadecanol using four different preparation methods. None of the tests resulted in significant mortality due to the action of hexadecanol. Although the deaths in the control (typicaly 10-30%) complicate the interpretation, the data demonstrate that the 96 hour LC50 was greater than the highest concentration tested (10 mg/L). This is about 1000 times the water solubility of hexadecanol.
- Validity criteria fulfilled:
- yes
- Conclusions:
- A 96 h LC50 >10 mg/L has been determined for the effects of hexadecanol on the mortality of the freshwater fish Brachydanio rerio (new name: Danio rerio). However this result is above the LoS (limit of solubility), therefore the substance is non-toxic at the limit of LoS and LC50 is >LoS.
- Executive summary:
Five acute toxicity tests were conducted with hexadecanol using four different preparation methods. None of the tests resulted in significant mortality due to the action of hexadecanol. Although the deaths in the control (typicaly 10-30%) complicate the interpretation, the data demonstrate that the 96 hour LC50 was greater than the highest concentration tested (10 mg/L). This is about 1000 times the water solubility of hexadecanol.
- Endpoint:
- short-term toxicity to fish
- Type of information:
- other: published data
- Adequacy of study:
- weight of evidence
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- study well documented, meets generally accepted scientific principles, acceptable for assessment
- Justification for type of information:
- Dodecan-1-ol (C12) is supporting substance for Alcohols,C12-C14 and the main component.
- Qualifier:
- according to guideline
- Guideline:
- other: US EPA 1975
- GLP compliance:
- not specified
- Analytical monitoring:
- yes
- Details on sampling:
- - Sampling method: Concentrations of chemicals in water were measured in each tank throughout the test in all exposure treatments, although analysis details (methods and results) were not reported.
- Vehicle:
- no
- Details on test solutions:
- PREPARATION AND APPLICATION OF TEST SOLUTION
- Method: the test substance was tested at a level below the limit of solubility, no details on the method of dispersion were provided - Test organisms (species):
- Pimephales promelas
- Details on test organisms:
- TEST ORGANISM
- Common name: fathead minnow
- Source: Environmental Research Laboratory-Duluth culture
- Age at study initiation (mean): 30d
- Weight at study initiation (mean): 0.12 g
- Feeding during test: none
ACCLIMATION
- Acclimation period: not reported - Test type:
- flow-through
- Water media type:
- freshwater
- Limit test:
- no
- Total exposure duration:
- 96 h
- Post exposure observation period:
- None
- Hardness:
- 56.3 mg/L as CaCO3
- Test temperature:
- 25 ± 1°C
- pH:
- 7.5
- Dissolved oxygen:
- >60%
- Salinity:
- N.A.
- Nominal and measured concentrations:
- Five concentrations were tested in order to obtain 0 to 100% mortality, the values were not reported.
- Details on test conditions:
- TEST SYSTEM
- Type of flow-through: proportional diluter
- No. of organisms per vessel: <30 fish per concentration
- No. of vessels per control: 2
- No. of vessels per concentration: 2
TEST MEDIUM / WATER PARAMETERS
- Source/preparation of dilution water: Lake Superior
- Alkalinity: 42.2 mg/L
- Intervals of water quality measurement: daily
EFFECT PARAMETERS MEASURED: mortality was recorded at 1, 3, 6, 12, 24, 48, 72 and 96h - Reference substance (positive control):
- not specified
- Duration:
- 96 h
- Dose descriptor:
- LC50
- Effect conc.:
- 1.01 mg/L
- Nominal / measured:
- meas. (not specified)
- Conc. based on:
- not specified
- Basis for effect:
- mortality (fish)
- Remarks on result:
- other: non-toxic at the limit of solubility
- Details on results:
- - Mortality of control: The mortality values in the control are not reported; however fish mortalities were monitored daily.
- Reported statistics and error estimates:
- The LC50 was calculated using the trimmed Spearman-Karber method (Hamilton et al. 1977) on a PDP-11/70 computer.
- Validity criteria fulfilled:
- yes
- Conclusions:
- A reliable 96h LC50 of 1.01 mg/L has been determined for the effects of the test substance on mortality of the fish Pimephales promelas.This result is above the LoS (limit of solubility), therefore the substance is non-toxic at the limit of LoS and LC50 is >LoS.
Dodecan-1-ol (C12) is supporting substance for Alcohols,C12-C14 and the main component. - Executive summary:
A reliable 96h LC50 of 1.01 mg/L has been determined for the effects of the test substance on mortality of the fish Pimephales promelas.This result is above the LoS (limit of solubility), therefore the substance is non-toxic at the limit of LoS and LC50 is >LoS.
Dodecan-1-ol (C12) is supporting substance for Alcohols,C12-C14 and the main component.
Referenceopen allclose all
Description of key information
A reliable 96 h LC50 value of 131.25 mg/L has been calculated for the effects of the test substance towards freshwater fish taxonomic group.Therefore the test substance has been predicted to be non toxic at the limit of solubility, so the LC50 is 0.525 mg/L. Predicted to be non-toxic at the limit of solubility. This result is above the LoS (limit of solubility), therefore the substance is non-toxic at the limit of LoS and LC50 is >LoS.
The water solubility of the Alcohols, C12-14 is 4.0 mg/l at 1000 mg/L loading rate at 25 degC (experimental database).This is about 250 times the water solubility of the test substance.
A reliable 96 h LC50 value of 147.75 mg/L has been calculated for the effects of the test substance towards fish taxonomic group.Therefore the test substance has been predicted to be non toxic at the limit of solubility, so the LC50 is 0.591 mg/L. Predicted to be non-toxic at the limit of solubility.
This result signifies that the test substance is not expected to be toxic at the limit of solubility.This result is above the LoS (limit of solubility), therefore the substance is non-toxic at the limit of LoS and LC50 is >LoS.
The water solubility of the Alcohols, C12-14 is 4.0 mg/l at 1000 mg/L loading rate at 25 degC (experimental database).This is about 250 times the water solubility of the test substance.
A reliable 48 h LC50 >5000 mg/L has been determined for the effects of Alcohols, C12-14 on the mortality of the freshwater fish Leuciscus idus . However this result is above the LoS (limit of solubility), therefore the substance is non-toxic at the limit of LoS and LC50 is >LoS.
Key value for chemical safety assessment
Fresh water fish
Fresh water fish
- Effect concentration:
- 131.25 mg/L
Marine water fish
Marine water fish
- Effect concentration:
- 147.75 mg/L
Additional information
A reliable 96 h LC50 value of 131.25 mg/L has been calculated for the effects of the test substance towards freshwater fish taxonomic group.Therefore the test substance has been predicted to be non toxic at the limit of solubility, so the LC50 is 0.525 mg/L. Predicted to be non-toxic at the limit of solubility. This result is above the LoS (limit of solubility), therefore the substance is non-toxic at the limit of LoS and LC50 is >LoS.
The water solubility of the Alcohols, C12-14 is 4.0 mg/l at 1000 mg/L loading rate at 25 degC (experimental database).This is about 250 times the water solubility of the test substance.
A reliable 96 h LC50 value of 147.75 mg/L has been calculated for the effects of the test substance towards fish taxonomic group.Therefore the test substance has been predicted to be non toxic at the limit of solubility, so the LC50 is 0.591 mg/L. Predicted to be non-toxic at the limit of solubility.
This result signifies that the test substance is not expected to be toxic at the limit of solubility.This result is above the LoS (limit of solubility), therefore the substance is non-toxic at the limit of LoS and LC50 is >LoS.
The water solubility of the Alcohols, C12-14 is 4.0 mg/l at 1000 mg/L loading rate at 25 degC (experimental database).This is about 250 times the water solubility of the test substance.
A reliable 48 h LC50 >5000 mg/L has been determined for the effects of Alcohols, C12-14 on the mortality of the freshwater fish Leuciscus idus . However this result is above the LoS (limit of solubility), therefore the substance is non-toxic at the limit of LoS and LC50 is >LoS.
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