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EC number: 227-561-6 | CAS number: 5888-33-5
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Guidance on Safe Use
Administrative data
First-aid measures
4.1. Description of first aid measures
General advice:
First aider needs to protect himself.Take off all contaminated clothing immediately. Medical treatment is necessary if symptoms occur which are obviously caused by skin or eye contact with the product or by inhalation of its vapours.
Inhalation:
Move subject to fresh air and keep him calm. In case of discomfort: Supply with medical care.
Skin contact:
If skin irritation occurs consult a physician. Wash off immediately with soap and water.
Eye contact:
Flush eyes thoroughly with a large amount of water and consult a physician.
Ingestion:
Do not induce vomiting. Get medical attention immediately.
4.2. Most important symptoms and effects, both acute and delayed
Skin irritation Serious eye irritation cough, sneezing. sensitising effects
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
Fire-fighting measures
5.1. Extinguishing media
Suitable extinguishing media:
foam
dry chemical
carbon dioxide
Unsuitable extinguishing media:
High volume water jet
5.2. Special hazards arising from the substance or mixture
May be released in case of fire: carbon monoxide, carbon dioxide, organic products of decomposition.
5.3. Advice for firefighters
Special fire fighting procedures:
Keep away from sources of ignition - No smoking. Take action to prevent static discharges. In the event of fire, cool the endangered containers with
water. Vapors are heavier than air and may spread along floors. When heated above the flash point and/or during spraying (atomizing), ignitible
mixtures may form in air.
Special protective equipment for fire-fighters: Wear self-contained breathing apparatus.
Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Assure sufficient ventilation.
Use personal protective clothing.
Keep away sources of ignition.
Use breathing apparatus if exposed to vapours/dust/mist/aerosol.
Do not breathe vapours or spray mist.
Do not eat, drink or smoke when using this product.
6.2. Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
6.3. Methods and material for containment and cleaning up
Larger quantities: Remove mechanically (by pumping). Use explosion-proof equipment!
Smaller quantities and/or residues:
Contain with absorbent material (e.g. sand, diatomaceous earth, acid absorbent, universal absorbent or sawdust).
Dispose of contaminated material in accordance as prescribed
6.4. Reference to other sections
For personal protection see section 8.
For disposal considerations see section 13.
Handling and storage
7.1. Precautions for safe handling
Technical measures (e.g. Local and general ventilation):
For monitoring procedures refer for instance to "Empfohlene Analysenverfahren für Arbeitsplatzmessungen", Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for Occupational Safety and Health
Safe handling advice:
Do not breathe vapors. Avoid contact with skin and eyes. Do not eat, drink or smoke during use.Keep away from sources of ignition - No smoking.
Take action to prevent static discharges. In the event of fire, cool the endangered containers with water. Vapors are heavier than air and may
spread along floors. When heated above the flash point and/or during spraying (atomizing), ignitible mixtures may form in air.Keep container
tightly closed. Ensure there is good room ventilation.
7.2. Conditions for safe storage, including any incompatibilities
Safe storage conditions: Fill the container by approximately 90 % only as oxygen (air) is required for stabilisation. With large storage containers make sure the oxygen (air) supply is sufficient to ensure stability. Keep only in the original container at a temperature not exceeding 30 °C. Can polymerize with intense heat
release. Protect from the action of light.
7.3. Specific end use(s)
We are unaware of any specific end uses which go beyond the data reported in Section 1.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3082
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., STABILIZED (isobornyl acrylate), 9, III, (E)
Hazard no. 90 - Chemical name:
- Isobornyl acrylate
- Packing group:
- Packing group III: Substances presenting low danger
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 3082
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3082
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., STABILIZED (isobornyl acrylate)
- Chemical name:
- isobornyl acrylate
- Packing group:
- Packing group III: Substances presenting low danger
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3082
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, liquid, n.o.s., STABILIZED (isobornyl acrylate)
- Chemical name:
- isobornyl acrylate
- Packing group:
- Packing group III: Substances presenting low danger
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
8.1. Control parameters
see section 8.2.
8.2. Exposure controls
For monitoring procedures refer to for instance "Empfohlene Analysenverfahren für Arbeitsplatzmessungen", Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for Occupational Safety and Health
DNEL-Values
Critical component Type Route of Exposure Health Warnings Remarks
isobornyl acrylate Workers Inhalation Systemic, long-term; 4.9 mg/m3 Repeated dose toxicity
General population Inhalation Systemic, long-term; 1.45 mg/m3 Repeated dose toxicity
General population Dermal Systemic, long-term; 0.83 mg/kg Repeated dose toxicity
General population Oral Systemic, long-term; 0.83 mg/kg Repeated dose toxicity
Workers Dermal Systemic, long-term; 1.39 mg/kg Repeated dose toxicity
General population Eyes Local effects; No hazard identified
Workers Eyes Local effects; No hazard identified
Remarks: DNEL-Values
Critical component Type Route of Exposure Health Warnings Remarks
isobornyl acrylate Workers Inhalation Systemic, long-term; 4.9 mg/m3 Repeated dose toxicity
General population Inhalation Systemic, long-term; 1.45 mg/m3 Repeated dose toxicity
General population Dermal Systemic, long-term; 0.83 mg/kg Repeated dose toxicity
General population Oral Systemic, long-term; 0.83 mg/kg Repeated dose toxicity
Workers Dermal Systemic, long-term; 1.39 mg/kg Repeated dose toxicity
General population Eyes Local effects; No hazard identified
Workers Eyes Local effects; No hazard identified
PNEC-Values
Critical component Environmental compartment PNEC-Values Remarks
isobornyl acrylate Soil 0.029 mg/kg
Sewage treatment plant 2 mg/l
marine water sediment 0.015 mg/kg
freshwater 0.001 mg/l
marine water 0 mg/l
freshwater sediment 0.145 mg/kg
Remarks: PNEC-Values
Critical component Environmental compartment PNEC-Values Remarks
isobornyl acrylate Soil 0.029 mg/kg
Sewage treatment plant 2 mg/l
marine water sediment 0.015 mg/kg
freshwater 0.001 mg/l
marine water 0 mg/l
freshwater sediment 0.145 mg/kg
Individual protection measures, such as personal protective equipment
Eye/face protection: Tightly fitting safety goggles
Hand Protection: Material: Butyl rubber.
Break-through time: 480 min
Glove thickness: 0.3 mm
Guideline: EN 374
Additional Information: Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of
the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the
contact time., The above mentioned hand protection is based on special knowledge of the chemical and the intended handling of this product,
however, it still may not be suited for all workplaces. A qualified hazard assessment should be made prior to the onset of work in order to determine
the suitability of gloves for specific working environments and processes.,
Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Skin and Body Protection: On handling of larger quantities: face mask, chemical-resistant boots and apron
Respiratory Protection: Breathing apparatus in case of high concentrations short term: filter appliance, filter A
Hygiene measures:
Store work clothing separately. Immediately remove contaminated clothing.
Follow the usual good standards of occupational hygiene. Clean skin thoroughly after work; apply skin cream.
Stability and reactivity
10.1. Reactivity
No data available.
10.2. Chemical stability
No decomposition if used as directed.
10.3. Possibility of hazardous reactions
Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing substances, and/or heavy metal ions.
10.4. Conditions to avoid
Ultraviolet light. Avoid high temperatures and sources of ignition.The product is normally supplied in a stabilized form. If the permissible storage period and/or storage temperature is exceeded, the product may polymerize with heat evolution.
10.5. Incompatible materials
Peroxides, amines, sulfur compounds, heavy metal ions, alkalis, reducing agents and oxidizing agents.
10.6. Hazardous decomposition products
None when used as directed.
Disposal considerations
13.1. Waste treatment methods
General information: Dispose of waste and residues in accordance with local authority requirements.
Disposal methods: Waste is hazardous. It must be disposed of in accordance with the regulations after consultation of the competent local authorities and the
disposal company in a suitable and licensed facility. Strictly controlled conditions during disposal or treatment to air, wastewater and waste. Do
not add wastewater to a biological wastewater treatment plant Bring wastewater containing AOX for professional disposal. The waste key
number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the
disposal firm / producing firm / official authority
Contaminated packaging:
Contaminated packaging should ideally be emptied; it can then be recycled after having been decontaminated.
Packaging that cannot be cleaned should be disposed of professionally.
Uncontaminated packaging may be taken for recycling.
Code of waste EWC:
07 02 08
waste from the manufacture, formulation, supply and use (MFSU) of plastics, synthetic rubber and man-made fibres - other still bottoms and reaction residues
Always check the given waste codes according to the actual conditions of manufacturing, formulation or use in your facilities.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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