Registration Dossier
Registration Dossier
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EC number: 205-743-6 | CAS number: 149-57-5
Guidance on Safe Use
Administrative data
First-aid measures
4.1. Description of first aid measures
Remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.
Fire-fighting measures
5.1. Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide
5.2. Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire.
5.3. Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.
Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing.
6.2. Environmental precautions
Do not empty into drains.
6.3. Methods and material for containment and cleaning up
For small amounts: Pick up with absorbent material (e.g. sand, sawdust, general-purpose binder).
For large amounts: Pump off product.
Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.
6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.
Handling and storage
7.1. Precautions for safe handling
Ensure thorough ventilation of stores and work areas.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
7.2. Conditions for safe storage, including any incompatibilities
Segregate from alkalies and alkalizing substances.
Further information on storage conditions: Keep container tightly closed in a cool, well-ventilated place.
Storage stability:
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.
7.3. Specific end use(s)
See exposure scenario(s) in the attachment to this safety data sheet.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
8.1. Control parameters
Components with occupational exposure limits
No occupational exposure limits known.
PNEC
freshwater: 0.36 mg/l
marine water: 0.036 mg/l
intermittent release: 0.493 mg/l
sediment (freshwater): 6.37 mg/kg
sediment (marine water): 0.637 mg/kg
soil: 1.06 mg/kg
STP: 71.7 mg/l
DNEL
worker:
Long-term exposure- systemic effects, dermal: 2 mg/kg
worker:
Long-term exposure- systemic effects, Inhalation: 14 mg/m3
consumer:
Long-term exposure- systemic effects, dermal: 1 mg/kg
consumer:
Long-term exposure- systemic effects, Inhalation: 3.5 mg/m3
consumer:
Long-term exposure- systemic effects, oral: 1 mg/kg
8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)
Consider the risk management measures as outlined in the exposure scenario.
Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Do not breathe vapour/spray. Avoid contact with skin and eyes. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Take off immediately all contaminated clothing. Store work clothing separately.
Stability and reactivity
10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
No corrosive effect on metal.
Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.
10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated.
10.3. Possibility of hazardous reactions
Reacts with strong alkalies. Exothermic reaction.
10.4. Conditions to avoid
See MSDS section 7 - Handling and storage.
10.5. Incompatible materials
Substances to avoid:
strong alkalies
10.6. Hazardous decomposition products
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
Disposal considerations
13.1. Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
