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Diss Factsheets

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
oxidising solids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
May 27, 2013
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.17 (Oxidising Properties (Solids))
Deviations:
no
GLP compliance:
not specified
Key result
Sample tested:
test mixture as specified
Remarks:
ratio 2:1 test substance/cellulose
Parameter:
preliminary test
Remarks on result:
mixture does not ignite and burn
Remarks:
The test substance was milled with a centrifugal mill to < 0.125 mm. The test substance could not be dried with 105°C, because it melts. Therefore, the moist salaly was determined. Moist salaly = 0.38%.

The test substance was milled with a centrifugal mill to < 0.125 mm. The test substance could not be dried with 105°C, because it melts. Therefore, the moist salaly was determined. Moist salaly = 0.38%.

 

Preliminary test

The preliminary screening test showed no propagation of the flame and the flame ceased. Therefore, the full test was carried out.

 

Train test

The mixtures in the range of 10 to 90 % test substance/cellulose showed no propagation of the flame and the flame ceased after a few seconds.

 

Sample

Burning time (i.e., in s)

Burning rate(i.e., mm/s)

Mixture of Reference sample

154

1.3

Mixture of test substance

-

-

 

Interpretation of results:
GHS criteria not met
Conclusions:
Under the study conditions, the test substance was not oxidizing.
Executive summary:

A study was conducted to determine oxidizing properties of the test substance according to EU Method A.17. Initially, a preliminary screening study was carried out on a mixture of test substance with dried cellulose in a ratio of 2:1. This was followed by the full train test with range of mixtures of the test substance with cellulose and reference substances. A hot flame from a gas burner with a diameter of about 6 mm was used as ignition source in both tests. The preliminary screening test showed no propagation of the flame and the flame ceased. Therefore, the full train test was carried out. In the full train test, the mixtures in the range of 10 to 90 % test substance/cellulose showed no propagation of the flame and the flame ceased after a few seconds. Under the study conditions, the test substance was therefore not oxidizing (Bütfering, 2013).

Description of key information

The oxidizing properties were determined according to EU Method A.17 (Bütfering, 2013).

Key value for chemical safety assessment

Oxidising properties:
non oxidising

Additional information

Justification for classification or non-classification