Trihexylaluminium

GHS

General Information

Implementation:

EU

Remarks:

Hexane and/or hexene may be generated by degradation of the material; hence classification and labelling contribution of these substances is considered to be an appropriate consideration. The classification is made according to CLP, with due application of the mixture rule to classify the substance containing hexane or hexane as an impurity. Variation in composition and classification is appropriate as degradation products differ per manufacturer for the substance.

Related composition

Related composition:

Trihexylaluminium, where hexene / hexane content is 0 to <2.5%

Classification

Physical hazards

Explosives

Reason for no classification:

data conclusive but not sufficient for classification

Flammable gases and chemically unstable gases

Reason for no classification:

data conclusive but not sufficient for classification

Aerosols

Reason for no classification:

data conclusive but not sufficient for classification

Reason for no classification:

hazard class not assessed

Oxidising gases

Reason for no classification:

data conclusive but not sufficient for classification

Gases under pressure

Reason for no classification:

data conclusive but not sufficient for classification

Flammable liquids

Reason for no classification:

data conclusive but not sufficient for classification

Flammable solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-reactive substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric liquids

Hazard category:

Pyr. Liquid 1

Hazard statement:

H250: Catches fire spontaneously if exposed to air.

Pyrophoric solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-heating substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Substances and mixtures which in contact with water emit flammable gases

Hazard category:

Water React. Flam. Gas 1

Hazard statement:

H260: In contact with water releases flammable gases which may ignite spontaneously.

Oxidising liquids

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising solids

Reason for no classification:

data conclusive but not sufficient for classification

Organic peroxides

Reason for no classification:

data conclusive but not sufficient for classification

Corrosive to metals

Reason for no classification:

data lacking

Desensitized explosives

Reason for no classification:

data lacking

Health hazards

Acute toxicity - oral

Reason for no classification:

data lacking

Acute toxicity - dermal

Reason for no classification:

data lacking

Acute toxicity - inhalation

Reason for no classification:

data lacking

Skin corrosion / irritation

Hazard category:

Skin Corr. 1B

Hazard statement:

H314: Causes severe skin burns and eye damage.

Serious eye damage / eye irritation

Reason for no classification:

data lacking

Respiratory sensitisation

Reason for no classification:

data lacking

Skin sensitisation

Reason for no classification:

data lacking

Aspiration hazard

Reason for no classification:

data lacking

Reproductive toxicity

Reason for no classification:

data lacking

Effects on or via lactation

Reason for no classification:

data lacking

Germ cell mutagenicity

Reason for no classification:

data lacking

Carcinogenicity

Reason for no classification:

data lacking

1. Specific target organ toxicity - single (STOT-SE)

Reason for no classification:

data lacking

1. Specific target organ toxicity - repeated (STOT-RE)

Reason for no classification:

data lacking

Environmental hazards

Hazardous to the aquatic environment (acute / short-term)

Reason for no classification:

data conclusive but not sufficient for classification

Hazardous to the aquatic environment (long-term)

Reason for no classification:

data conclusive but not sufficient for classification

Hazardous to the ozone layer

Reason for no classification:

data lacking

Labelling

Signal word:

Danger

Hazard pictogram

GHS02: flame

GHS05: corrosion

Hazard statements

H250: Catches fire spontaneously if exposed to air.

H260: In contact with water releases flammable gases which may ignite spontaneously.

H314: Causes severe skin burns and eye damage.

Precautionary statements

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P222: Do not allow contact with air.

P223: Do not allow contact with water.

P231+P232: Handle and store contents under inert gas/… . Protect from moisture.

P260: Do not breathe dust/fume/gas/mist/vapours/spray.

P264: Wash ... thoroughly after handling.

hands and clothing

P280: Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P302+P334: IF ON SKIN: Immerse in cool water [or wrap in wet bandages].

P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].

P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310: Immediately call a POISON CENTER/doctor/…

P321: Specific treatment (see ... on this label).

guidance

P302+P335+P334: IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].

P363: Wash contaminated clothing before reuse.

P370+P378: In case of fire: Use... to extinguish.

CO2 or dry powder. DO NOT USE WATER or FOAM

P402+P404: Store in a dry place. Store in a closed container.

P405: Store locked up.

P501: Dispose of contents/container to ...

industrial waste processor.

Additional labelling requirements

EUH014: Reacts violently with water.