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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
auto-flammability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
17 June 2014-07 September 2014
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: GLP-compliant study in accordance with UN-MTC Section 33.3.1.

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2014
Report date:
2014

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: UN ST/SG/AC.10/11/Rev.5: Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Part III Section 33.3.1 "Substances liable to spontaneous combustion” (2009).
Deviations:
no
Principles of method if other than guideline:
UN MTC Section 33.3.1.4 - Test N.4: Test method for self-heating substances (2009)
GLP compliance:
yes

Test material

Constituent 1
Chemical structure
Reference substance name:
Methyl DL-serinate hydrochloride
EC Number:
227-047-1
EC Name:
Methyl DL-serinate hydrochloride
Cas Number:
5619-04-5
Molecular formula:
C4H9NO3.ClH
IUPAC Name:
methyl 2-amino-3-hydroxypropanoate hydrochloride
Test material form:
solid: particulate/powder
Remarks:
migrated information: powder
Details on test material:
- Name of test material (as cited in study report): DL-serine Methylester HCl
- Molecular formula: C4H9NO3.HCl
- Molecular weight: 155.58 g/mol
- Description: White crystalline powder
- Storage condition of test material: At room temperature in the dark
- Expiration date of the lot/batch: 14 September 2014

Results and discussion

Auto-ignition temperature (liquids / gases)
Remarks on result:
other: No spontaneous ignition occurred and no exothermic effect of the test substance was observed in the test using a 100 mm sample cube at 140°C.
Relative self-ignition temperature (solids)
Remarks on result:
other: No spontaneous ignition occurred and no exothermic effect of the test substance was observed in the test using a 100 mm sample cube at 140°C.

Any other information on results incl. tables

After the experiment, the test substance had turned into an expanded black charred residue and was collected in a container that was placed below the cube. It indicated that the test substance melted, decomposed and/or reacted during the experiment.

Applicant's summary and conclusion

Conclusions:
In a GLP-compliant study performed in accordance with UN-MTC Section 33.3.1 (Test N.4), the substance has been determined to be not a self-heating substance.