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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
1997-01-31
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
other: 92/69/EWG, A.4 (static method)
Version / remarks:
1992
Deviations:
no
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Version / remarks:
1981
Deviations:
no
GLP compliance:
yes
Type of method:
static method
Key result
Temp.:
20 °C
Vapour pressure:
0.064 Pa

Table 1 Determination of the vapour pressure of the test item at 3 different temperatures, using the static technique

Measurement

Temperature °C

Mean vapour pressure +/- SD

 

 

ln (p)

Pa

70 - 96

37.79

-1.86 +/- 0.03

0.156 +/- 0.004

100 - 121

31.66

-2.17 +/- 0.04

0.114 +/- 0.004

130 - 164

24.93

-2.48 +/- 0.08

0.084 +/- 0.005

Conclusions:
The vapour pressure of the test item at 20 °C was determined to be 0.064 Pa.
Executive summary:

The determination of the vapour pressure was based on the following guidelines:

European Economic community (EE), EEC directive 92/69 EEC, Part A, Methods for the determination of the physico-chemical properties, A.4 “Vapour pressure”. EEC Publication No. L383, December 1992.

Organization for Economic Co-operation and Development (OECD), OECD guidelines for testing chemicals, Guideline No. 104: “Vapour pressure curve”, adopted May 12, 1981.

Using the Static Technique, the vapour pressure of the test item at 20°C was determined to be

P (20 °C) = (6.4 +/- 0.6) x 10^-2 Pa = (4.8 +/- 0.5) x 10^-4 mmHg

Description of key information

The vapour pressure of the test item at 20 °C was determined to be 0.064 Pa (reference 4.6 -1).

Key value for chemical safety assessment

Vapour pressure:
0.064 Pa
at the temperature of:
20 °C

Additional information

The determination of the vapour pressure was based on the following guidelines:

European Economic community (EE), EEC directive 92/69 EEC, Part A, Methods for the determination of the physico-chemical properties, A.4 “Vapour pressure”. EEC Publication No. L383, December 1992.

Organization for Economic Co-operation and Development (OECD), OECD guidelines for testing chemicals, Guideline No. 104: “Vapour pressure curve”, adopted May 12, 1981.

Using the Static Technique, the vapour pressure of the test item at 20°C was determined to be

P (20 °C) = (6.4 +/- 0.6) x 10^-2 Pa = (4.8 +/- 0.5) x 10^-4 mmHg