Registration Dossier

Administrative data

First-aid measures

General advice:
Call a physician immediately.

If inhaled:
If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician immediately.

In case of skin contact:
Take off contaminated clothing and shoes immediately. Wash off withsoap and plenty of water. Call a physician immediately.

In case of eye contact:
In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call a physician immediately.

If swallowed:
Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting. Call a physician immediately.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media Carbon dioxide (CO2), Dry powder, Foam, Water spray Extinguishing media which must not be used for safety reasons. Do not use a solid water stream as it may scatter and spread fire.

Special hazards arising from the substance or mixture
Special exposure hazards arising from the substance or preparation itself, its combustion products, or released gases Carbon oxides, Sulphur oxides.

Advice for firefighters Special protective equipment for firefighting
Personal protection through wearing a tightly closed chemical protection suit and a self-contained breathing apparatus.
Additional information on firefighting
Remove all sources of ignition. Pay attention to flashback. Suppress (knock down) gases/vapours/mists with a water spray jet. Do not allow run-off from fire fighting to enter drains or water courses.

Accidental release measures

Personal precautions
Keep people away from and upwind of spill/leak. Wear as appropriate: Complete suit protecting against chemicals

Environmental precautions
Suppress (knock down) gases/vapours/mists with a water spray jet. Do not flush into surface water or sanitary sewer system.

Methods and material for containment and cleaning up
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations

Handling and storage

Precautions for safe handling

Advice on safe handling
Refill and handle product only in closed system. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin and eyes. Take precautionary measures against static discharges.Keep away from open flames, hot surfaces and sources of ignition.

Advice on protection against fire and explosion
Take precautionary measures against static discharges. Keep away from heat and sources of ignition. Vapours may form explosive mixture with air.

Conditions for safe storage, including any incompatibilities
Storage space and container requirements
Keep in an area equipped with acid resistant flooring. Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid moisture. Keep away from direct sunlight.

TRGS 510 8A

Transport information

Land transport (ADR/RID)

UN number:
3265
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Class:
8
Classification code:
C3
Packaging group:
III
Labels:
8
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Marine transport (IMDG)

UN number:
3265
Proper shipping name and description:
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Chemical name:
Benzenesulfonic acid methylester
Class:
8
Packaging group:
III
EmS code:
F-A;S-B
Labels:
8
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Air transport ICAO/IATA

UN number:
3265
Proper shipping name and description:
Corrosive liquid, acidic, organic, n.o.s.
Chemical name:
Benzenesulfonic acid methylester
Class:
8
Packaging group:
III
Labels:
8- Corrosive
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Exposure controls / personal protection

Respiratory protection
Respirator with a vapour filter Recommended Filter type: ABEK

Hand protection
Suitable material: butyl-rubber

Eye protection
Tightly fitting safety goggles

Skin and body protection
Long sleeved clothing
Wear as appropriate: Complete suit protecting against chemicals

General protective and hygiene measures
Smoking, eating and drinking should be prohibited in the application area. Take off contaminated clothing and shoes immediately. Avoid breathing vapors, mist or gas. Wash hands and face before breaks and immediately after handling the product. Avoid contact with skin, eyes and clothing. Keep away from food, drink and animal feedingstuffs. Use protective skin cream before handling the product.

Stability and reactivity

Conditions to avoid
Vapour/air-mixtures are explosive at intense warming. Extremes of temperature and direct sunlight. Exposure to moisture. Heat, flames and sparks.

Disposal considerations

Disposal considerations
Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities.

Uncleaned empty packaging
Dispose of as unused product.