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Diss Factsheets

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
oxidising solids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
24 August 2015 - 25 August 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
UN Manual of Tests and Criteria: Test O.1 (Test for oxidizing solids)
Deviations:
no
GLP compliance:
yes
Specific details on test material used for the study:
- Batch n°: I14KB4717
- Analytical purity: 105.7% (acid titration)
- Expiration date: 25 November 2016
- Storage condition: at room temperature
Contact with:
powdered cellulose
Duration of test (contact time):
30 min
Key result
Sample tested:
1:1 sample-to-cellulose ratio
Parameter:
mean burning time
Result:
> 180 s
Key result
Sample tested:
4:1 sample-to-cellulose ratio
Parameter:
mean burning time
Result:
> 180 s
Sample tested:
reference: 3:7 mixture potassium bromate + cellulose
Parameter:
mean burning time
Result:
106 s
Sample tested:
reference: 2:3 mixture potassium bromate + cellulose
Parameter:
mean burning time
Result:
56 s
Sample tested:
reference: 3:2 mixture potassium bromate + cellulose
Parameter:
mean burning time
Result:
24 s

Burning rates of test item / cellulose mixtures

 Test item/cellulose (w/w)  Burning time [s]  Mean burning time [s]
 4:1  >180   >180
    >180  
    >180  
    >180  
    >180  
 1:1   >180   >180
    >180  
    >180  
    >180  
    >180  

Burning rates of potassium bromate / cellulose mixtures

 Potassium bromate/cellulose (w/w)  Mean burning time [s]
 3:7  106
 2:3  56
 3:2  24
Interpretation of results:
GHS criteria not met
Conclusions:
Based on the results obtained it was concluded that the test item has no oxidizing properties and is therefore not classified as a Division 5.1 substance.

Description of key information

Based on a GLP study according to UN O.1 (K1, Ciric, 2017), T001202 is considered not to have oxidising properties. T001202 can be concluded to be incapable of causing fire or enhancing the risk of fire when in contact with combustible material.

Key value for chemical safety assessment

Oxidising properties:
non oxidising

Additional information

Justification for classification or non-classification

T001202 does not need to be classified as an oxidising substance since the mean burning time of the test item mixtures was higher than the mean burning time of the reference mixure.