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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
auto-flammability
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2015
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: well performed study according to accepted standard

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2015
Report date:
2015

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: VDI 2263 sheet 1
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Sodium bis[3-[[1-(3-chlorophenyl)-4,5-dihydro-3-methyl-5-oxo-1H-pyrazol-4-yl]azo]-4-hydroxy-N-methylbenzenesulphonamidato(2-)]cobaltate(1-)
EC Number:
275-863-1
EC Name:
Sodium bis[3-[[1-(3-chlorophenyl)-4,5-dihydro-3-methyl-5-oxo-1H-pyrazol-4-yl]azo]-4-hydroxy-N-methylbenzenesulphonamidato(2-)]cobaltate(1-)
Cas Number:
71701-14-9
Molecular formula:
C34H28Cl2CoN10O8S2.Na
IUPAC Name:
Cobaltate(1-), bis[3-[2-[1-(3-chlorophenyl)-4,5-dihydro-3-methyl-5-(oxo-kO)-1H-pyrazol-4-yl]diazenyl-kN1]-4-(hydroxy-kO)-N-methylbenzenesulfonamidato(2-)]-, sodium (1:1)
Details on test material:
purity: 94.3 %

Results and discussion

Auto-ignition temperature (liquids / gases)open allclose all
Auto-ignition temperature:
> 230 °C
Atm. press.:
ca. 1 atm
Remarks on result:
other: pure substance
Auto-ignition temperature:
ca. 250 °C
Atm. press.:
ca. 1 atm
Remarks on result:
other: 1 : 1 mixture with kieselgur
Relative self-ignition temperature (solids)open allclose all
Relative self-ignition temperature:
> 230 °C
Remarks on result:
other: pure substance
Remarks:
at atm. press. of ca.1.0 atm
Relative self-ignition temperature:
ca. 250 °C
Remarks on result:
other: 1 : 1 mixture with kieselgur
Remarks:
at atm. press. of ca.1.0 atm

Applicant's summary and conclusion

Conclusions:
The substance has not to be classified as autoflammable according to EG 1272/2008 and to the transport classification
Executive summary:

The substance was tested for autoflammability according to VDI 2263 sheet 1 (screening in the Grewer oven). The pure substance showed selfignition starting with 230 °C. The 1:1 mixture with kieselgur had a selfignition at about 250°C