Registration Dossier
Registration Dossier
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EC number: 401-610-3 | CAS number: 122012-52-6 GENIPLEX A
Guidance on Safe Use
Administrative data
First-aid measures
Emergency measure - Inhalation: Remove patient to fresh air. Assist respiration if
necessary, and seek medical advice.
Emergency measure - Eyes: Wash contamination away immediately with water.
Emergency measure - Skin: Rinse immediately with plenty of water and seek medical
advice.
Emergency measure - Ingestion: Keep patient strictly at rest and transfer to hospital
without delay or seek medical advice.
Fire-fighting measures
Recommended extinguishing agent: Foam, carbon dioxide or dry powder. Water should not be used
since it causes the substance to evolve ammonia.
Product arising from burning: Combustion products: Ammonia, carbon oxides, nitrogen oxides
and possibly non-toxic zinc oxide airborne dust. No hydrogen
cyanide gas would be formed.
Undamaged containers of material exposed to, but not
directly involved in, a fire may be removed if without risk.
Product determined by test: N
Protective equipment: When fighting fires a self-contained breathing apparatus
should be worn.
Accidental release measures
Emergency measures in case of spillage: Wear suitable protective equipment (see 2.3.1). Do not
breathe dust or decomposition gases. Damp down any spilled
material (e.g. using damp sand or earth) and vacuum or
shovel into suitable labelled containers for disposal at an
approved landfill or incinerate. Do not allow entry of the
substance to water systems.
Handling and storage
Handling: Wear clean protective overall, protective gloves (PVC or
rubber), head covering, eye protection, and effective dust
mask when handling the concentrated material. Persons
previously sensitised to isocyanates should not work with
this material.
Storage: Store in original container, tightly closed in a safe place.
The substance has been stored for up to 18 months at 25 deg
C with no detectable build up of ammonia. Do not mix with
acids or allow to come into contact with copper.
Packaging of the substance and or preparation: Not given.
Transport information
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Marine transport (UN RTDG/IMDG)
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Air transport (UN RTDG/ICAO/IATA)
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Special provisions / remarks
- Remarks:
- Transport code: UN number: 2206
Transport: Transport only in a closed container, correctly labelled and
accompanied by a Safety Information Sheet.
Proper Shipping Name: Isocyanates, N.O.S.
(Diamminedi-isocyanato zinc)
Hazard Class: 6.1
Packing Group: II
Land (ADR/RID): Item no.: 19 b
HIN: 60
EAC: 2X
Air (IATA/DGR): Limits: 5 l passenger
60 l cargo
Sea (IMO/IMDG): IMDG code: 6166
MFAG: 370
EmS: 6.1-02
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Exposure controls / personal protection
Stability and reactivity
Danger other than fire: Ammonia is released if heated above 50 deg C.
Chemical reaction with water: No hazardous or vigorous reactions known but the substance
does evolve ammonia in contact with water and reacts to give
zinc compounds (see 5.2.2).
Dust explosion determined by test: N
Disposal considerations
Industry - Possibility of recovery/recycling: Sweep up and return to container.
Industry - Possibility of neutralisation: Treatment with acid will decompose the substance to release
carbon dioxide. Residues will contain ammonium salts, zinc
oxide/salts.
Industry - Possibility of destruction: controlled discharge: Disposal at an approved landfill site is possible.
Industry - Possibility of destruction - incineration: Ammonia, carbon oxides, nitrogen oxides and zinc oxide may
be formed. Minimum incineration temperature 1100 deg C,
minimum residence time 3 seconds.
Industry - Possibility of destruction - water purification: Substance is insoluble and will rapidly hydrolyse.
Therefore, this is not applicable.
Public at large - Possibility of recovery/recycling: The substance will not enter the public domain.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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