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Diss Factsheets
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EC number: 601-790-5 | CAS number: 12156-55-7
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
Move exposed person to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-tomouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. The exposed person may need to be kept under medical surveillance for 48 hours.
-Ingestion:
Wash out mouth with water. Move exposed person to fresh air. Keep person warm and at rest. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
-Skin contact:
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.
-Eye contact:
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 15 minutes. Get medical attention if irritation occurs.
Fire-fighting measures
Suitable:
In case of fire, use water spray (fog), foam, dry chemical or CO2.
Not suitable:
None known.
-Special exposure hazards:
No specific fire or explosion hazard.
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. This material is toxic to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
-Hazardous combustion products:
Decomposition products may include the following materials:
carbon oxides
-Special protective equipment for fire-fighters:
Fire-fighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Accidental release measures
No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Provide adequate ventilation. Put on appropriate personal protective equipment.
-Environmental precaution:
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
-Large spill:
Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labelled waste container. Dispose of via a licensed waste disposal contractor.
-Small spill:
Move containers from spill area. Vacuum or sweep up material and place in a designated, labelled waste container. Dispose of via a licensed waste disposal contractor.
Handling and storage
Put on appropriate personal protective equipment.. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not get in eyes or on skin or clothing. Do not ingest. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous.
Storage:
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (oxidants) and food and drink.Keep container tightly closed and sealed until ready for use..Do not store in unlabelled containers.Use appropriate containment to avoid environmental contamination.
Remarks: Avoid all possible sources of ignition (spark or flame). Take precautionary measures against electrostatic discharges.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 1993
Shipping information
- Proper shipping name and description:
- LIQUIDO INFLAMABLE , N.E.P.
- Chemical name:
- Bis-(p-metoxifenil) titanoceno en solución
- Language:
- Spanish
- Labels:
- Inflamable
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 1993
Shipping information
- Proper shipping name and description:
- LIQUIDO INFLAMABLE , N.E.P.
- Chemical name:
- Bis-(p-metoxifenil) titanoceno en solución
- Labels:
- inflamable
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 1993
Shipping information
- Proper shipping name and description:
- LIQUIDO INFLAMABLE , N.E.P.
- Chemical name:
- Bis-(p-metoxifenil) titanoceno en solución
- Labels:
- inflamable
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 1993
Shipping information
- Proper shipping name and description:
- LIQUIDO INFLAMABLE , N.E.P.
- Chemical name:
- Bis-(p-metoxifenil) titanoceno en solución
- Labels:
- inflamable
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
VLA-ED: 50 ppm / 150 mg/m3 (inhalation) Tetrahydrofuran
VLA-EC: 100 ppm / 300 mg/m3 (skin) Tetrahydrofuran
TWA: 50 ppm / 150 mg/m (2000/39/ CE Directive) Tetrahydrofuran
TWA: 100 ppm / 200 mg/m (2000/39/ CE Directive) Tetrahydrofuran
Recommended monitoring procedures:
If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances.
Risk management measures - Occupational exposure controls:
Technical measures: If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits.
Risk management measures - Personal protection measures:
Respiratory protection:
Respiratory protection with filter type AXBEK (EN 14387) that covers the whole face.
Hand protection:
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical
products if a risk assessment indicates this is necessary.After contamination with product change the gloves immediately and dispose of them according to relevant national and local regulations <1 hours (breakthrough time): Nitrile rubber - NBR , Polyvinyl chloride - PVC , Polychloroprene - CR
Eye protection:
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Recommended: Tightly fitting safety goggles.
Skin protection:
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Hygiene measures:
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing.Ensure that eyewash stations and safety showers are close to the workstation location.
Stability and reactivity
Conditions to avoid: Keep away from all possible sources of ignition (heat, spark or flame)
Materials to avoid: strong oxidants.
Hazardous decomposition products: ND
Disposal considerations
Examine possibilities for re-utilisation.Product residues and uncleaned empty containers should be packaged, sealed, labelled, and disposed of or recycled according to relevant national and local regulations.Where large quantities are concerned, consult the supplier.When uncleaned empty containers are passed on, the recipient must be warned of any possible hazard that may be caused by residues.For disposal within the EC, the appropriate code according to the European Waste List (EWL) should be used. It is among the tasks of the polluter to assign the waste to waste codes specific to industrial sectors and processes according to the European Waste List (EWL).
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.