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EC number: 228-560-3 | CAS number: 6294-89-9
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Guidance on Safe Use
Administrative data
First-aid measures
Inhalation: Get medical attention immediately. Move exposed person to fresh
air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. If unconscious,
place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband. In case of inhalation of decomposition products
in a fire, symptoms may be delayed. The exposed person may need
to be kept under medical surveillance for 48 hours.
Ingestion: Get medical attention immediately. Wash out mouth with water.
Move exposed person to fresh air. Keep person warm and at rest.
If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If
vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight
clothing such as a collar, tie, belt or waistband.
Skin contact: Get medical attention immediately. Wash skin immediately with
plenty of water and soap. Remove contaminated clothing and shoes.
Continue to rinse for at least 10 minutes. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 10 minutes. Get medical attention.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: In case of fire, use water spray (fog), foam, dry chemical or CO2.
Unsuitable extinguishing media: None known.
Special hazards arising from the substance or mixture
Hazards from the substance or mixture: No specific fire or explosion hazard
Hazardous combustion products: Decomposition products may include the following materials:
carbon oxides
nitrogen oxides
Advice for firefighters
Special precautions for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity
of the incident if there is a fire. No action shall be taken involving
any personal risk or without suitable training.
Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and selfcontained
breathing apparatus (SCBA) with a full face-piece
operated in positive pressure mode.
Accidental release measures
Personal precautions, protective equipment and emergency procedures: No action shall be taken involving
any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary
and unprotected personnel from entering. Do not touch or walk
through spilt material. Provide adequate ventilation. Put on
appropriate personal protective equipment.
Environmental precautions: Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil
or air).
Methods and material for containment and cleaning up
Small spill: Move containers from spill area. Vacuum or sweep up material and
place in a designated, labelled waste container. Dispose of via a
licensed waste disposal contractor.
Large spill: Move containers from spill area. Prevent entry into sewers, water
courses, basements or confined areas. Vacuum or sweep up
material and place in a designated, labelled waste container.
Dispose of via a licensed waste disposal contractor
Handling and storage
Manufacture and use of this chemical intermediate takes place under strictly controlled conditions, as described in Art. 17/18 REACH. The substance is rigorously contained during manufacturing and use and appropriate risk management measures including PPE (i.g. during charging or sampling) are applied. Occupational exposure is reduced to a minimum and well controlled by measurements. A management system covering all general aspects of a chemical production is in place, especially cleaning and maintenance of plants and equipment. An authorisation scheme based on instructions covering the whole process ensures that only trained and authorised staff handles the substance.
Precautions for safe handling: Put on appropriate personal protective equipment.
Eating, drinking and smoking should be prohibited in areas where
this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Do not get in
eyes or on skin or clothing. Do not ingest. Keep in the original
container or an approved alternative made from a compatible
material, kept tightly closed when not in use. Empty containers retain
product residue and can be hazardous. The product is registered
with strictly controlled conditions as defined in Article 17(3) or 18(4)
of regulation (EC) no. 1907/2006 (REACH Regulation) and must
therefore be handled as such. Refer to the industry guidance
prepared by Concawe/Cefic/EFCG for advice on the confirmation of
strictly controlled conditions.
Conditions for safe storage, including any incompatibilities
Do not store above the following temperature: 50°C (122°F). Store
in accordance with local regulations. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area,
away from incompatible materials and food and
drink. Keep container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabelled
containers. Use appropriate containment to avoid environmental
contamination.
Seveso III Directive - Reporting thresholds (in tonnes)
Danger criteria
Category: C2:Toxic
Notification and MAPP threshold: 50
Safety report threshold: 200
Remarks : Take precautionary measures against electrostatic discharges. Avoid
the formation of dust, if necessary siphoning the product off locally.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters
Exposure limit values: Not available.
Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to monitoring standards,
such as the following: European Standard EN 689 (Workplace
atmospheres - Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and
measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for
the assessment of exposure to chemical and biological agents)
European Standard EN 482 (Workplace atmospheres - General
requirements for the performance of procedures for the
measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous
substances will also be required.
Exposure controls
Risk management measures
Occupational exposure controls
Technical measures: The substance shall be rigorously contained by technical means
during its whole lifecycle including manufacture, purification,
cleaning and maintenance of equipment, sampling, analysis, loading
and unloading of equipment or vessels, waste disposal or
purification and storage. Procedural and control technologies shall
be used that minimise emission and any resulting exposure. In
cases of accident and where waste is generated, procedural and/or
control technologies shall be used to minimise emissions and the
resulting exposure during purification or cleaning and maintenance
procedures.
Organisational measures: Only properly trained and authorised personnel shall handle the
substance. In the case of cleaning and maintenance works, special
procedures such as purging and washing shall be applied before the
system is opened and entered.
Personal protection measures
Respiratory protection: If exposure cannot be ruled out, e.g. during product transfer,
sampling or maintenance, a well-fitting respiratory mask conforming
to standards or well-fitting respiratory device conforming to
standards must be worn. Respirator selection must be based on
known or anticipated exposure levels, the hazards of the product
and the safe working limits of the selected respirator.
Recommended: In case of dust formation particle filter.
Hand protection: Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical
products if product contact cannot be excluded. After contamination
with product change the gloves immediately and dispose of them
according to relevant national and local regulations
Recommended: (< 1 hour) Baypren , Viton® or nitrile rubber
Eye protection: Safety eyewear complying with an approved standard should be
used to avoid exposure to liquid splashes, mists, gases or dusts.
Recommended: safety glasses with side-shields
Skin protection: Wear protective clothing. Personal protective equipment for the
body should be selected based on the task being performed and the
risks involved and should be approved by a specialist before
handling this product.
Recommended: Wear protective clothing.
Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical
products, before eating, smoking and using the lavatory and at the
end of the working period. Appropriate techniques should be used
to remove potentially contaminated clothing. Wash contaminated
clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Environmental exposure controls
Technical measures: Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, special waste
water treatment, fume scrubbers, filters or engineering modifications
to the process equipment will be necessary to reduce emissions to
acceptable levels.
Stability and reactivity
Reactivity: No specific test data related to reactivity available for this product or
its ingredients.
Chemical stability: The product is stable.
Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions
will not occur.
Conditions to avoid: Contact with strong oxidising agents may cause hazardous reactions.
Incompatible with heavy metals.
Incompatible materials: No specific data.
Hazardous decomposition products: Under normal conditions of storage and use, hazardous
decomposition products should not be produced.
Disposal considerations
Waste treatment methods
Product
Methods of disposal: Examine possibilities for re-utilisation. Product residues and
uncleaned empty containers should be packaged, sealed, labelled,
and disposed of or recycled according to relevant national and local
regulations. Where large quantities are concerned, consult the
supplier. When uncleaned empty containers are passed on, the
recipient must be warned of any possible hazard that may be caused
by residues. For disposal within the EC, the appropriate code
according to the European Waste List (EWL) should be used. It is
among the tasks of the polluter to assign the waste to waste codes
specific to industrial sectors and processes according to the
European Waste List (EWL).
Hazardous waste: The classification of the product may meet the criteria for a
hazardous waste.
Packaging
Methods of disposal: The generation of waste should be avoided or minimised wherever
possible. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible.
Special precautions: This material and its container must be disposed of in a safe way.
Care should be taken when handling emptied containers that have
not been cleaned or rinsed out. Empty containers or liners may
retain some product residues. Avoid dispersal of spilt material and
runoff and contact with soil, waterways, drains and sewers.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.