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Physical & Chemical properties

Auto flammability

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2016
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study without detailed documentation
Qualifier:
according to guideline
Guideline:
ASTM E659 (Standard test method for autoignition temperature of liquid chemicals)
GLP compliance:
not specified
Key result
Auto-ignition temperature:
>= 420 - <= 425 °C
Atm. press.:
ca. 101 325 Pa

Table 1. Auto-ignition temperatures

 Sample size, mL  Flask temp., °C  Ignition, yes/no  Ignition delay, sec  Comments
 0.25  400  no    no flame
 0.25  410  no    no flame
 0.25  420  no    no flame
 0.25  422  no    no flame
 0.25  423  yes  18  hot flame
 0.25  425  yes  15  hot flame
 0.25  430  yes  10  hot flame
Conclusions:
Under the study conditions, the autoignition temperature of the test substance was determined to be between 420°C and 425°C (ASTM E-659).
Executive summary:

A study was conducted to determine the autoignition temperature of the test substance according to the standard method - ASTM E-659. The method was abbreviated for this study to determine a range for the autoignition temperature of the test substance. The sample size was held constant (0.25mL/500cc) throughout the study. Varying the sample size could have lowered autoignition temperature a couple of degrees. The test was run to a ~5°C level of accuracy. Under the study conditions, the autoignition temperature of the test substance was determined to be between 420°C and 425°C (Boutreau, 2016).

Description of key information

The autoignition temperature was determined according to the standard method - ASTM E-659 (Boutreau, 2016)

Key value for chemical safety assessment

Additional information

Between 420 and 425°C