Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Inhalation: Remove to fresh air. Artificial respiration and/or oxygen may be necessary. Call a physician immediately.
Skin contact: Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Wash contaminated clothing before re-use. Obtain medical attention.
Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention.
Ingestion: If conscious, drink plenty of water. Induce vomiting if person is conscious. Call a physician immediately.

Notes to physician
Symptoms: Product may hydrolyze upon contact with body fluids in the gastrointestinal tract to produce additional methanol; therefore, consider the signs/symptoms of methanol poisoning and also observe the known latency period of several days.

Fire-fighting measures

Suitable extinguishing media: Alcohol-resistant foam, Carbon dioxide (CO2), Dry chemical
Specific hazards during fire fighting: Vapors form from this product and may travel or be moved by air currents and ignited by pilot lights, other flames, sparks, heaters, electrical equipment, static discharges or other ignition sources at locations distant from product handling point. Vapor may be ignited by static sparks. Use proper bonding and grounding during material transfer.
Special protective equipment for fire-fighters: Wear self-contained breathing apparatus and protective suit.
Further information: Do not direct a solid stream of water or foam into hot, burning pools: this may cause frothing and increase fire intensity. Cool closed containers exposed to fire with water spray.

Accidental release measures

Personal precautions: Extinguish and do not turn on any ignition source until the area is determined to be free from fire or explosion hazards. Avoid contact with skin, eyes and clothing. Avoid contact with liquid and vapors. Use personal protective equipment.
Environmental precautions: Do not flush into surface water or sanitary sewer system.
Methods for cleaning up: Soak up with inert absorbent material. Shovel into suitable container for disposal.

Handling and storage

Handling
Advice on safe handling: Do not breathe vapours or spray mist. Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Ensure adequate ventilation, especially in confined areas. Use proper bonding and grounding during material transfer.
Storage
Requirements for storage areas and containers: Keep tightly closed. Keep away from open flames, hot surfaces and sources of ignition.

Transport information

Land transport (ADR/RID)

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S.
Chemical name:
trimethoxyvinylsilane
Language:
English
Class:
3
Classification code:
F1
Packaging group:
III
Labels:
3
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
1993
Shippingopen allclose all
Class:
3
Classification code:
F1
Packaging group:
III
Labels:
3
Remarksopen allclose all

Marine transport (IMDG)

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S.
Chemical name:
trimethoxyvinylsilane
Class:
3
Packaging group:
III
EmS code:
F-E, S-E
Labels:
3
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
1993
Proper shipping name and description:
FLAMMABLE LIQUID, N.O.S.
Chemical name:
trimethoxyvinylsilane
Class:
3
Packaging group:
III
Labels:
3
Remarksopen allclose all

Additional transport information

Additional transport information
Special provision
ADNR Special Provision 640E
ADR Special Provision 640E
RID Special Provision 640E

Exposure controls / personal protection

Engineering measures
Use only in an area equipped with a safety shower.
Eye wash bottle with pure water
General (mechanical) room ventilation is expected to be satisfactory if handled at low
temperatures or in covered equipment.
Special, local ventilation is needed at points where vapors can be expected to escape to the
workplace air.

Personal protective equipment
Respiratory protection :
Respirator with an ABEK filter; at high concentration use respiratory protection with independent air supply.
Hand protection :
Material : 898 Butoject
Minimum break through time: 480 min
Glove thickness : 0,7 mm
Eye protection :
Safety glasses with side-shields
Skin and body protection : Safety shoes, Protective suit

Stability and reactivity

Conditions to avoid : Stable under normal conditions.
Avoid temperatures:
>150 °C
Materials to avoid : Avoid contact with:
Halogens (chlorine) in the presence of sunlight or ultraviolet
light.
Peroxides
Reacts with water or moisture to form:
Methanol
Hazardous reactions : polymerisation
Avoid contact with: Peroxides Catalytic metals. Polymerization
catalysts. Avoid exposure to: High temperatures. >150 °C
Hazardous decomposition
products
: Carbon oxides Oxides of silicon.

Disposal considerations

Product : Can be incinerated, when in compliance with local regulations.
Contaminated packaging : Dispose of as unused product.