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Diss Factsheets
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EC number: 219-835-9 | CAS number: 2549-53-3
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Guidance on Safe Use
Administrative data
First-aid measures
4.1. Description of first aid measures
General advice
Medical treatment is necessary if symptoms are evidently caused by effects of the
product on the skin, eyes or respiratory system. Remove contaminated, soaked
clothing.
Inhalation
Move subject to fresh air and keep him calm. In case of complaints get medical
advice.
Skin contact
Wash off immediately with soap and water. If skin irritation persists, call a
physician.
Eye contact
Flush eyes thoroughly with water.
Ingestion
Do not induce vomiting. Seek medical advice immediately.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact may provoke the following symptoms: Allergic appearance
4.3. Indication of any immediate medical attention and special treatment needed
Hazards: No data available.
Treatment: Treat symptomatically.
Fire-fighting measures
5.1. Extinguishing media
Suitable extinguishing media
Dry chemical. Carbon dioxide foam
Unsuitable extinguishing media:
High volume water jet
5.2. Special hazards arising from the substance or mixture
May be released in case of fire: carbon monoxide, carbon dioxide, organic products of decomposition.
Closed container may rupture if strongly heated.
5.3. Advice for firefighters
Special fire fighting procedures:
Keep away from sources of ignition - No smoking. Take action to prevent static discharges. In the event of fire, cool the endangered containers with water. When heated above the flash point and/or during spraying (atomizing), ignitible mixtures may form in air. Use only explosion-proof equipment.
Special protective equipment for fire-fighters: Wear self-contained breathing apparatus.
Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Assure sufficient ventilation. Use personal protective clothing. Keep away sources of ignition. Use breathing apparatus if
exposed to vapours/dust/mist/aerosol. Wash hands thoroughly with soap and water after handling.
6.2. Environmental precautions
Prevent product from getting into subsoil/soil. Prevent product from getting into drains/surface water/groundwater.
6.3. Methods and material for containment and cleaning up
Larger quantities: Remove mechanically (by pumping). Use explosion-proof equipment! Smaller quantities and/or residues:
Contain with absorbent material (e.g. sand, diatomaceous earth, acid absorbent, universal absorbent or sawdust). Dispose
of in accordance with regulations.
6.4. Reference to other sections
For personal protection see section 8. For disposal considerations see section 13.
Handling and storage
7.1. Precautions for safe handling
Safe handling advice
Keep container tightly closed. Ensure there is good room ventilation. Do not breathe vapors. Avoid contact with skin and eyes. Do not eat, drink or smoke during use. Keep away from sources of ignition - No smoking. Take action to prevent static discharges. In the event of fire, cool the endangered containers with water. When heated above the flash point and/or during spraying (atomizing), ignitible mixtures may form in air. Use only explosion-proof equipment.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
Keep only in the original container at a temperature not exceeding 30 °C. Protect
from the action of light. Fill the container by approximately 90 % only as oxygen
(air) is required for stabilisation. With large storage containers make sure the
oxygen (air) supply is sufficient to ensure stability. Can polymerize with intense
heat release.
7.3. Specific end use(s)
no
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- Not regulated as a dangerous good
Shippingopen allclose all
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not regulated as a dangerous good
Marine transport (UN RTDG/IMDG)
- UN number:
- Not regulated as a dangerous good
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not regulated as a dangerous good
Air transport (UN RTDG/ICAO/IATA)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not regulated as a dangerous good
SpecialProvisionsopen allclose all
Exposure controls / personal protection
8.1. Control parameters
Occupational Exposure Limits
None of the components have assigned exposure limits.
8.2. Exposure controls
Appropriate Engineering Controls:
For monitoring procedures refer for instance to "Empfohlene Analysenverfahren für Arbeitsplatzmessungen",
Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for
Occupational Safety and Health
Individual protection measures, such as personal protective equipment
Eye/face protection:
tightly fitting goggles
Hand Protection:
Material: Butyl rubber.
Break-through time: 60 min
Glove thickness: 0.3 mm
Guideline: EN 374
Additional Information: Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time., The above mentioned hand protection is based on special knowledge of the chemical and the intended handling of this product, however, it still may not be suited for all workplaces. A qualified hazard assessment should be made prior to the onset of work in order to determine the suitability of gloves for specific working environments and processes., Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Additional Information: nitrile rubber gloves, Suitable as spray protection.
Skin and Body Protection:
On handling of larger quantities: face mask, chemical-resistant boots and apron
Respiratory Protection:
not required on normal handling
Hygiene measures:
Store work clothing separately. Take off all contaminated clothing immediately. Follow the usual good standards of occupational hygiene. Use skin protective preparation as preventive skin protection. Clean skin thoroughly after work; apply skin cream.
Environmental Controls:
see section 6.
Stability and reactivity
10.1. Reactivity
No data available.
10.2. Chemical stability
No decomposition if stored and applied as directed.
10.3. Possibility of hazardous reactions
Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing
substances, and/or heavy metal ions. UV light causes radical polymerization.
10.4. Conditions to avoid
High temperature Depolymerization begins at 200 °C The product is normally supplied in a stabilized form. If the permissible storage period and/or storage temperature is exceeded, the product may polymerize with heat evolution.
10.5. Incompatible materials
Peroxides, amines, sulfur compounds, heavy metal ions, alkalis, reducing agents and oxidizing agents. Free radical initiators. Mineral Acid
10.6. Hazardous decomposition products
None when used as directed.
Under conditions of thermal decomposition: Methacrylates
Disposal considerations
13.1. Waste treatment methods
General information:
Dispose of waste and residues in accordance with local authority requirements.
Disposal methods:
Waste is hazardous. It must be disposed of in accordance with the regulations after consultation of the competent local authorities and the disposal company in a suitable and licensed facility. The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Contaminated Packaging:
Contaminated packaging should ideally be emptied; it can then be recycled after having been decontaminated. Packaging that cannot be cleaned should be disposed of professionally. Uncontaminated packaging may be taken for recycling.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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