Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General information
CAUTION! First aid personnel must be aware of own risk during rescue!
Inhalation
Move the exposed person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues.
Ingestion
Immediately rinse mouth and provide fresh air. Get medical attention if any discomfort continues.
Skin contact
Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water.
Get medical attention if any discomfort continues.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

Most important symptoms and effects, both acute and delayed:
General information
The severity of the symptoms described will vary dependant of the concentration and the length of exposure.
Inhalation
NOTE! Effects may be delayed. Keep affected person under observation. Dust irritates the respiratory system, and may cause coughing
and difficulties in breathing. May cause nausea, headache, dizziness and intoxication. Frequent inhalation of dust over a long period of
time increases the risk of developing lung diseases.
Ingestion
Metallic taste. May cause stomach pain or vomiting. Diarrhoea. Fumes from the stomach contents may be inhaled resulting in the same
symptoms as inhalation.
Skin contact
Irritating and may cause redness and pain. Discoloration of the skin. The molten product can cause serious burns.
Eye contact
Irritating and may cause redness and pain.

Indication of any immediate medical attention and special treatment needed:
No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in
doubt, GET MEDICAL ATTENTION PROMPTLY!

Fire-fighting measures

Extinguishing media
This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials.
Unsuitable extinguishing media
DO NOT use water if avoidable.

Hazardous combustion products
Fire or high temperatures create: Toxic gases/vapours/fumes of: Metal oxides.
Unusual Fire & Explosion Hazards
High concentrations of dust may form explosive mixture with air.
Specific hazards
When heated and in case of fire, toxic vapours/gases may be formed.

Special Fire Fighting Procedures
Avoid breathing fire vapours. Fight advanced or massive fires from safe distance or protected location.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Wear protective clothing.
Environmental precautions
Do not discharge into drains, water courses or onto the ground. Avoid spreading dust or contaminated materials.
Methods and material for containment and cleaning up
Avoid generation and spreading of dust. Should be prevented from entering drains. Remove spillage with vacuum cleaner. If not possible,
collect spillage with shovel, broom or the like. Ensure that waste and contaminated materials are collected and removed from the work
area as soon as possible in a suitably labelled container.

Handling and storage

Precautions for safe handling
Avoid spilling, skin and eye contact. Avoid handling which leads to dust formation.
Conditions for safe storage, including any incompatibilities
Store in a cool and well-ventilated place.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

Control parameters
Workplace Exposure Limit: TWA-8hours= 0.1 mg/m³ as Te

Process conditions
Use engineering controls to reduce air contamination to permissible exposure level.
Engineering measures
Provide adequate ventilation. Observe occupational exposure limits and minimize the risk of inhalation of dust.
Respiratory equipment
If ventilation is insufficient, suitable respiratory protection must be provided.
Hand protection
Use suitable protective gloves if risk of skin contact. The most suitable glove must be chosen in consultation with the gloves supplier, who
can inform about the breakthrough time of the glove material.
Eye protection
Use approved safety goggles or face shield.
Hygiene measures
DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash
promptly if skin becomes contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or
smoke. Change work clothing daily if there is any possibility of contamination. Isolate contaminated clothing and wash before reuse.
Skin protection
Wear suitable protective clothing as protection against splashing or contamination.
Thermal hazards
The molten product can cause serious burns.
Environmental Exposure Controls
Avoid release to the environment.

Stability and reactivity

Reactivity
No specific reactivity hazards associated with this product.
Chemical stability
Stable under normal temperature conditions.
Possibility of hazardous reactions
Hazardous Polymerisation
Not relevant
Conditions to avoid
Avoid excessive heat for prolonged periods of time.
Incompatible materials
Materials To Avoid
Strong acids. Strong reducing agents.
Hazardous decomposition products
When heated, vapours/gases hazardous to health may be formed.

Disposal considerations

General information
When handling waste, consideration should be made to the safety precautions applying to handling of the product.

Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.