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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

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Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2004
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
study well documented, meets generally accepted scientific principles, acceptable for assessment
Remarks:
Acceptable, well-documented study report which mets basic scientific principles.

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2004
Report date:
2004

Materials and methods

Principles of method if other than guideline:
Screening test according to Grewer and according to company guideline, similar to VDI 2263 sheet 1

Test material

Constituent 1
Chemical structure
Reference substance name:
N-(5-chloro-2-methylphenyl)-3-hydroxy-4-[[2-methoxy-5-[(phenylamino)carbonyl]phenyl]azo]naphthalene-2-carboxamide
EC Number:
269-389-4
EC Name:
N-(5-chloro-2-methylphenyl)-3-hydroxy-4-[[2-methoxy-5-[(phenylamino)carbonyl]phenyl]azo]naphthalene-2-carboxamide
Cas Number:
68227-78-1
Molecular formula:
C32H25ClN4O4
IUPAC Name:
N-(5-chloro-2-methylphenyl)-3-hydroxy-4-{[2-methoxy-5-(phenylcarbamoyl)phenyl]diazenyl}-2-naphthamide

Results and discussion

Relative self-ignition temperature (solids)
Key result
Relative self-ignition temperature:
ca. 260 °C
Remarks on result:
other:
Remarks:
at atm. press. of ca.1013.0 hPa

Any other information on results incl. tables

Self-heating of the test item as delivered was observed at 260 °C (small temperature rise up to ca. 330 °C).

The measurement of the mixture of the test item with kieselguhr (1:1) showed an exothermal reaction at 290 °C with a temperature rise up to above 800 °C.

Self-heating of the test substance occurs due to its decomposition.

Applicant's summary and conclusion

Conclusions:
The test substance shows weak self-heating at 260 °C. No classification as a self-heating substance class 4.2 of the transport regulations required.
Executive summary:

Self-ignition of the test substance was determined by heating a sample in the Grewer oven. The test substance shows weak self-heating at 260 °C.