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Physical & Chemical properties

Surface tension

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Reference
Endpoint:
surface tension
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2009-12-09 to 2010-03-23
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.5 (Surface Tension)
Deviations:
no
Qualifier:
according to guideline
Guideline:
OECD Guideline 115 (Surface Tension of Aqueous Solutions)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
OECD harmonised ring method
Specific details on test material used for the study:
- Batch Number: TL00910581
Key result
Surface tension:
74 mN/m
Temp.:
20.3 °C
Conc.:
1.07 g/L

The calibration factor Fbwas determined to be 1.0222 for double distilled water (Table1). The data are part ofHarlan Laboratories' instruments files and a copy is presented in the raw data of thepresent study. Table 2 shows the individual measurements for the surface tension of the aqueous test item solution. From these, the mean and the corrected value for the given solution were calculated and shown in Table 2. The tabulated values represent rounded results obtained from calculation using the exact raw data.

Table 1: Determination of the Calibration Factor Using Water

Time expired

Temperature

Surface tension

[mN/m]

Calibration factor

measured

 

mean value

calculated from the bold values

[hours:min]

[°C]

 

sg

Fb

00:31

20.1

71.3

71.17

1.0222

00:33

20.1

71.2

20.0

71.1

00:37

20.0

71.2

00:39

20.0

71.1

00:41

20.0

71.1

 

 

with:

so     =      72.75 mN/m at 20.0 °C

Fb    =      so/sg

Fb    =      72.75 / 71.17 = 1.0222

 

where:

 Fb    =      calibration factor

so     =      the surface tension of water at the test temperature

sg     =      measured value of the surface tension of water at the test temperature

Table 2: Determination of Surface Tension for the Test Item Solution

Time expired

Temperature

Surface tension

[mN/m]

 

 

measured

mean value calculated from the bold values

mean value corrected for calibration

s1corrected for Harkins-Jordan

[hours:min]

[°C]

 

(s *)

(s 1)

(s)

First sample

 

 

 

 

00:41

19.9

72.7

72.67

74.28

74.28

00:44

20.4

72.7

00:47

20.4

72.6

00:49

20.4

72.7

00:50

20.4

72.6

00:51

20.4

72.7

Second sample

 

 

 

 

00:45

20.4

72.1

72.13

73.74

73.74

00:46

20.4

72.1

00:47

20.3

72.2

00:48

20.2

72.1

00:49

20.2

72.2

00:51

20.2

72.1

 Mean value from both samples: s = 74.0 mN/m

 

Conclusions:
The surface tension of the test item in water (at a concentration of about 0.1%) was determined to be 74.0 mN/m at 20.3 °C ± 0.5 °C. Based on the criteria as outlined in the EEC Guideline and the results of this study,the test item has to be considered as a non surface active substance.
Executive summary:

The surface tension of the test item in water (at a concentration of about 0.1%) was determined to be 74.0 mN/m at 20.3 °C ± 0.5 °C. Based on the criteria as outlined in the EEC Guideline and the results of this study,the test item has to be considered as a non surface active substance.

 

Description of key information

The surface tension of the test item in water (at a concentration of about 0.1%) was determined to be 74.0 mN/m at 20.3 °C ± 0.5 °C. Based on the criteria as outlined in the EEC Guideline and the results of this study, the test item has to be considered as a non surface active substance.

Key value for chemical safety assessment

Surface tension:
74
in mN/m at 20°C and concentration in mg/L:
1 070

Additional information

The surface tension of the test item in water (at a concentration of about 0.1%) was determined to be 74.0 mN/m at 20.3 °C ± 0.5 °C. Based on the criteria as outlined in the EEC Guideline and the results of this study, the test item has to be considered as a non surface active substance.