N,N',N'',N'''-tetrakis(4,6-bis(butyl-(N-methyl-2,2,6,6-tetramethylpiperidin-4-yl)amino)triazin-2-yl)-4,7-diazadecane-1,10-diamine

Guidance on Safe Use

First-aid measures

General information: As a general rule, in case of doubt or if symptoms persist, always call a doctor. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and seek medical advice.

In case of inhalation: Remove victim to fresh air and keep at rest in a position comfortable and well-ventilated for breathing. In case of irritation of respiratory system or mucous membranes and/or indisposition and/or prolonged exposure, seek medical attention.

In case of skin contact: Wipe away excess material with dry towel and then wash with soap or mid detergent and large amounts of water until no evidence of chemical remains (at least 15-20 minutes). Do not use organic solvents. Get medical attention immediately.

In case of eye contact: Check for and remove any contact lenses. Immediately flush eyes with running clean water for at least 15 minutes, keeping eyelids open. Get medical attention immediately.

In case of ingestion:  Wash out mouth with water and then drink plenty of water (>2000 ml, if possible charcoal slurry). In case of spontaneous vomiting be sure that vomitus can freely drain due of danger of suffocation. Give water repeatedly. If vomiting occurs, keep head lower than hips to help prevent aspiration. Do not induce vomiting/risk of damage to lungs exceeds poisoning risk. Give nothing by mouth in cases of unconsciousness or convulsion. Get medical attention immediately and show the container or label.

In case of body contact: Remove contaminated clothing. Wash contaminated clothing before reusing.

Self-protection of the first-aiders: No action shall be taken involving any personal risk or without suitable training.

Notes to physician: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Most important symptoms and effects, both acute and delayed: No specific information.

Indication of any immediate medical attention and special treatment needed: No specific information.

Fire-fighting measures

Suitable extinguishing media: Carbon dioxide, foam, dry chemical, water spray. Fight larger fires with water spray or alcohol resistant foam. Use fire fighting measures that suit the environment.

Extinguishing media which must not be used for safety reason: High volume water jet.

Special hazards arising from the substance or mixture: Thermal decomposition and burning may produce carbon monoxide, nitrogen oxides and other toxic gases and vapours.

Advice for fire-fighters: Wear full protective clothing. Wear self-contained breathing apparatus.

Hazard decomposition products: Oxides of carbon; Oxides of nitrogen (NOx); Toxic gases/vapours.

Other information: Do not enter fire area without proper protection. Fight fire from safe distance/protected location. Move container from fire area if you can do it without risk. Do not scatter spilled material with high-pressure water streams. Use agents suitable for type of surrounding fire. Avoid breathing hazardous vapours, keep upwind. Prevent fire-fighting water from entering surface water or groundwater. Contaminated water from fire hoses or sprinkler etc must be prevented from draining into watercourses, sewers or the ground water. Sufficient measures must be taken to retain water used for extinguishing. Contaminated water and soil must be disposed of in conformity with local regulations. Notify authorities if liquid enters sewer/public waters.

Accidental release measures

Personal precautions, protective equipment and emergency procedures: No action shall be taken involving any personal risk or without suitable training. Remove all sources of ignition. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spit material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Avoid inhalation of vapours/dust. Avoid contact with eyes, skin and clothing. Put on appropriate personal protective equipment.

Environmental precautions: Avoid releasing to the environment. Do not flush into surface water, sanitary sewer or ground water system. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body.

Methods and material for containment and cleaning up Spills/Leaks:

Remove unnecessary people. Shut off all sources of ignition. Pick up mechanically. Wearing appropriate personal protective equipment, carefully sweep up material and place in suitable labelled, tightly sealed containers for disposal. Do not flush spilled material into sewer. Avoid dust formation.

Precautions if chemical is spilled or released: Released material poses a dust explosion hazard if it becomes airborne in the presence of an ignition source. Extinguish all ignition sources. On land sweep/shovel into suitable disposal containers or vacuum using equipment which avoids ignition risk. Avoid making dust.

Handling and storage

Precautions for safe handling: As a general rule,

- not to eat, drink and smoke in work areas;

- to wash hands after use and;

- to remove contaminated clothing and protective equipment before entering eating areas.

In accordance with good industrial practice, handle with care and avoid unnecessary personal contact. Avoid generation of dusts. Avoid skin and eye contact. Provide good ventilation. Keep away from ignition sources. Handle according to industrial hygiene principles and relevant legal provisions.

This chemical is not expected to present an explosion hazard during normal transportation and storage operations. However, when dispersed in air and subject to sufficient energy of ignition, it may pose a dust explosion hazard. Minimize the energy of ignition, it may pose a dust explosion hazard. Minimize the potential for dust explosion by eliminating/controlling ignition sources (bond and ground), and by using good housekeeping practices during storage, transfer, handling and use to avoid excessive dust accumulation.

Containers of this chemical may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

Handling requirement: Substance may cause an allergic skin reaction and is dangerous for the environment. Handle and open container with care. Do not get in eyes/, on skin/clothing. Avoid dust formation and ignition source. Do not inhale dusts. Do not taste/ingest. Ensure good local exhaust ventilation. Do not eat, drink or smoke at the workplace.

Fire and explosion hazard: When mixed with air and exposed to an ignition source, sufficient dust may become an explosion hazard. Use good housekeeping practices to avoid rendering dust airborne and prevent electrostatic charge formation during transfer and use of this chemical. Ensure that all equipment and containers are adequately grounded. Vapours generated from overheating/decomposition may be flammable and may cause fire/explosion if source of ignition is present. Protection against fire and explosion.

Condition and materials to avoid: Direct sunlight, excessive light, moisture, oxidizing conditions, excessively high temperatures, sparks and open flame, dusting conditions.

Conditions for safe storage, including any incompatibilities: Keep container tightly closed in a dry, cool and well-ventilated place against strong oxidizers when not in use and during transport, prevent contamination with foreign materials. Keep chemical away from direct sunlight, heat, sparks, open flame and other ignition sources. Keep away from food and drink. Store in the original container securely closed. Protect from moisture and physical damage.

Risk of explosion if an air-dust mixture forms. Avoid creating dusty conditions. Empty only into earthed containers or use a system other designed to prevent or contain an explosion-seek expert advice.

Shelf life: 2 year minimum in sealed containers protected from light and air.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3077

Shipping

Labels:

9

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3077

Shipping

Labels:

9

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

3077

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contain N,N',N'',N'''-tetrakis(4,6-bis(butyl-(N-methyl-2,2,6,6-tetramethylpiperidin-4-yl)amino)triazin-2-yl)-4,7-diazadecane-1,10-diamine)

Chemical name:

N,N',N'',N'''-tetrakis(4,6-bis(butyl-(N-methyl-2,2,6,6-tetramethylpiperidin-4-yl)amino)triazin-2-yl)-4,7-diazadecane-1,10-diamine

Labels:

9

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

3077

Shipping information

Proper shipping name and description:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contain N,N',N'',N'''-tetrakis(4,6-bis(butyl-(N-methyl-2,2,6,6-tetramethylpiperidin-4-yl)amino)triazin-2-yl)-4,7-diazadecane-1,10-diamine)

Chemical name:

N,N',N'',N'''-tetrakis(4,6-bis(butyl-(N-methyl-2,2,6,6-tetramethylpiperidin-4-yl)amino)triazin-2-yl)-4,7-diazadecane-1,10-diamine

Labels:

9

Remarks

SpecialProvisions

Exposure controls / personal protection

Appropriate engineering controls: Work in well ventilated areas. Local exhaust ventilation is generally required because it can control the emissions of the contaminant and its source, preventing dispersion of it into the general work area. Use mechanical ventilation for general area control. Refrigerant concentration monitors may be necessary to determine vapour concentration in work areas prior to use torches or other open flames, or if employees are entering enclosed areas.

Individual protection measures, such as personal protective equipment

Precautionary measures: Do not handle this chemical near heat, sparks or open flame. Prevent electrostatic discharge formation. Avoid accumulation of dust in enclosed space. Keep container closed when not in use. Avoid contact with eyes, skin and clothing. Do not breathe dust. Use only with adequate ventilation / personal protection. Before using this chemical or products containing this chemical, read SDS.

Hygiene measures: Wash hands, forearms and face thoroughly after handling this chemical or products containing this chemical, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Do not eat, drink or smoke while working. Keep away from foodstuffs, beverages and food. During synthesis,  formulation or application, follow good industrial hygiene practice. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure.

Respiratory protection: No necessary if room is well-ventilated. In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Use respirators and components tested and approved under appropriate government standards such CEN (EU).

Hand protection: Protective gloves should be worn at all times when handling chemical product. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove’s outer surface) to avoid skin contact with this chemical. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The glove material has to be impermeable and resistant to the product/substance/the preparation. Material of gloves: Butyl rubber, BR; Nitrile rubber, NBR; PVC gloves.

Glove thickness: 0.7 mm. Break through time: > 480 min. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

Eye protection: Suitable goggles or face protection. Use equipment for eye protection tested and approved under appropriate government standards such as EN 166 (EU).

Skin protection: Protective working clothes, closed footwear. The skin protection equipments should be cleaned thoroughly after each use.

Body protection: Protective work clothing, closed footwear.

Environmental exposure control: This chemical is toxic to aquatic life with long lasting effects. Do not allow this chemical or products containing this chemical or contaminated containers to enter drains, sewers or water courses. Do not allow to directly enter the environment. Any potential releases to air, water or soil should be avoid.

Stability and reactivity

Reactivity: No specific information.

Chemical stability: Stable under ordinary conditions of use and storage. Heat will contribute to instability.

Decomposition temperature: ca. 300 °C

Possibility of hazardous reactions: No hazardous reactions known.

Conditions to avoid: Heat, ignition sources and incompatibilities. Static discharges.

Incompatible materials: Strong acids, strong bases and strong oxidising agents.

Hazardous decomposition products: Thermal decomposition and burning may produce carbon monoxide, nitrogen oxides and other toxic gases and vapours.

Polymerisation: Hazardous polymerisation has not been reported to occur under normal temperatures and pressures.

Disposal considerations

Waste treatment methods: The generation of waste should be avoided or minimised wherever possible. Disposal of this substance or product containing this chemical, solutions and any by-products must be dumped or incinerated in accordance with local/regional/national/international regulations. Incinerate in a chemical incinerator equipped with an afterburner and scrubber. Non contaminated packaging material should be treated as household waste or as recycling material.

Waste from residues/unused products: Residual chemical should be disposed by incineration or by other modes or disposal in compliance with local/regional/national/international regulations.

Contaminated packaging: Contaminated packaging material should be treated equivalent to residual chemical. Clean packaging material should be subjected to waste management schemes (recovery recycling, reuse) according to local/regional/national/international regulations.

Recommendation: Released material poses a dust explosion hazard.