Registration Dossier
Registration Dossier
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EC number: 236-437-0 | CAS number: 13368-45-1
Guidance on Safe Use
Administrative data
First-aid measures
General information: Immediately remove contaminated clothing.
Inhalation: If aerosol or mists are formed: Possible discomfort: severe irritation of mucous lining (nose, throat, eyes), cough, sneezing, flow of tears Move to fresh air. If breathing difficulties occur: Keep patient half sitting with upper body raised. Get medical attention immediately.
Skin contact: Wash off immediately with plenty of water. Seek medical advice.
Eye contact: With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes. Continue rinsing process with eye rinsing solution. Protect unharmed eye. Call ambulance. (Cue: caustic burn of the eyes) Immediate further treatment in ophthalmic hospital/ ophthalmologist. Continue rinsing eye until arrival at ophthalmic hospital.
Ingestion: Do NOT induce vomiting. Only when patient fully conscious: Have the mouth rinsed with water. Have patient drink plenty of water in small sips. Notify ambulance immediately (keyword: chemical burn).
Indication of immediate medical attention and special treatment needed
Treatment: Therapy as for chemical burn. If substance has been swallowed: Early endoscopy in order to assess mucosa lesions in the oesophagus and stomach which may appear. If necessary, suck away leftover substance.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: Water spray, foam, dry powder or carbon dioxide.
Unsuitable extinguishing media: High volume water jet.
Special hazards arising from the substance or mixture: Closed container may rupture if strongly heated. In case of fire cool endangered containers with water.
Advice for firefighters
Special fire-fighting procedures: Water used to extinguish fire should not enter drainage systems, soil or stretches of water. Ensure there are sufficient retaining facilities for water used to extinguish fire. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Fire water retention in Germany: cf. Art. 20 of the Ordinance on Facilities for Handling Substances Hazardous to Water (AwSV)
Special protective equipment for fire-fighters: In case of fire: wear a self-contained respiratory apparatus
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Use personal protective equipment. Avoid contact with skin and eyes. Ensure adequate ventilation. Keep away from sources of ignition - No smoking.
For non-emergency personnel: No data available.
For emergency responders: No data available.
Environmental Precautions: Do not allow entrance in sewage water, soil stretches of water, groundwater, drainage systems.
Methods and material for containment and cleaning up: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Transfer into suitable containers. To be disposed of in compliance with existing regulations.
Handling and storage
Precautions for safe handling
Technical measures (e.g. Local and general ventilation):
Provide for good ventilation if vapours/aerosols are formed.
Safe handling advice:
Provide adequate ventilation. Avoid breathing mists or vapors. Handle in accordance with good industrial hygiene and safety practice. The personal protective equipment used must meet the requirements of Regulation (EU) 2016/425 and amendments (CE certification). If workplace exposure limits are exceeded and/or larger amounts are released (leakage, spilling, dust) the indicated respiratory protection should be used. If there is the possibility of skin/eye contact, the indicated hand/eye/body protection should be used. Do not breathe in vapours or aerosols. Avoid contact with skin and eyes.
Contact avoidance measures:
No data available.
Conditions for safe storage, including any incompatibilities
Safe storage conditions:
Take precautionary measures against static discharges. Keep away from sources of ignition - No smoking. Danger of explosion from residual product fumes; therefore avoid spark production through cutting, grinding, or welding work in the area of the container. When repairs of the production system are to be made (e.g. welding work), the section to be repaired must be essentially free of product. Keep container tightly closed in a dry and well-ventilated place. Protect from moisture. Store under an inert atmosphere. Keep containers tightly closed in a cool, well-ventilated place. Protect from moisture.
Safe packaging materials:
No data available.
Storage Class: 3-Flammable Liquids
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Use personal protective equipment. Avoid contact with skin and eyes. Ensure adequate ventilation. Keep away from sources of ignition - No smoking.
Eye/face protection:
Safety glasses
Hand Protection:
Material: Butyl rubber.
Break-through time: >= 480 min
Glove thickness: 0,5 mm
Material: Fluorinated rubber (Viton)
Break-through time: >= 480 min
Glove thickness: 0,4 mm
Additional Information: Selection of protective gloves to meet the requirements of specific workplaces., The suitability for a specific workplace should be discussed with the producers of the protective gloves., The information is based on our own tests, references from the literature and information from glove manufacturers, or derived by analogy with similar materials., Be aware that in daily use the durability of a chemical resistant protective glove can be notably shorter than the break through time measured according to EN 374, due to the numerous outside influences (e.g. temperature).
Skin and Body Protection:
suitable protective clothing - Use disposable clothing if appropriate.
Respiratory Protection:
In case of dusts/vapours/aerosols being formed or if the limit values like TLV are exceeded: use respiratory equipment with suitable filter (filter type ABEK) or wear a self contained respiratory apparatus Use only respiratory protection equipment with CE-symbol including four digit test number. The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapor/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, self-contained breathing apparatus must be used. Note time limit for wearing respiratory protective equipment.
Hygiene measures:
When using, do not eat, drink or smoke. Wash face and/or hands before break and end of work. Immediately remove contaminated clothing. Wash contaminated clothing before reuse.
Stability and reactivity
Reactivity:
No dangerous reaction known under conditions of normal use.
Chemical Stability:
Stable under recommended storage conditions.
Possibility of hazardous reactions:
Reacts with water.
Conditions to avoid:
Keep away from heat, sparks and open flame.
Incompatible Materials:
Alcohols. Moisture. Oxidizing agents. Water. acids
Hazardous Decomposition Products:
Hydrolyses on contact with water. Possible decomposition products in case of hydrolysis are: dimethylamine
Disposal considerations
General information:
No data available.
Disposal methods:
With respect to local regulations, e.g. dispose of to suitable waste incineration plant. No waste key number as per the European Waste Types List can be assigned to this product, since such classification is based on the (as yet undetermined) use to which the product is put by the consumer. The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Contaminated Packaging:
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities. Incorrect disposal or reuse of this container is illegal and can be dangerous. Other countries: observe the national regulations
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
