Ethanol, 2-(2-butoxyethoxy)-, reaction products with phosphorus oxide (P2O5), compds. with N,N-dimethylcyclohexanamine

Auto flammability

Administrative data

Endpoint:

auto-ignition temperature (liquids)

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2018

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

guideline study

Data source

Reference

Reference Type:

study report

Title:

Unnamed

Year:

2019

Report date:

2018

Materials and methods

Test guideline

Qualifier:

according to guideline

Guideline:

EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))

Deviations:

no

GLP compliance:

yes (incl. QA statement)

Test material

Test material information

Constituent 1

Reference substance name:

Ethanol, 2-(2-butoxyethoxy)-, reaction products with phosphorus oxide (P2O5), compds. with N,N-dimethylcyclohexanamine

EC Number:

948-066-8

Molecular formula:

C16H36NO6P C24H52NO8P C24H53NO11P2 C32H68NO10P C8H17N H3O4P

IUPAC Name:

Ethanol, 2-(2-butoxyethoxy)-, reaction products with phosphorus oxide (P2O5), compds. with N,N-dimethylcyclohexanamine

Test material form:

liquid: viscous

Specific details on test material used for the study:

3.1. TEST ITEM


Name: Ethanol, 2-(2-butoxyethoxy)-, reaction products with phosphorus oxide (P2O5), compds. with N,N-dimethylcyclohexanamine
Appearance: High-viscous, colourless to yellowish liquid
Purity: Considered as 100%
Expiry date: 22 November 2019

Results and discussion

Auto-ignition temperature (liquids / gases)

Key result

Auto-ignition temperature:

ca. 380 °C

Atm. press.:

ca. 97 kPa

Any other information on results incl. tables

1.1.              RESULTS

 

 

Temperature was measured in case of each experiment at the outside and inside of the flask. The starting temperature was approximately 231°C, the steps for increasing the temperaturewasapproximately50°Cfirstlyandifpositiveignitionoccurs,thestepsfor increasing/decreasing wassmaller.

 

The temperature distribution was steady outside the flask.

The ignition delay time was determined in each case when ignition was observed. The test was carried out at 97 kPa atmospheric pressure.

 

The details are summarised in Table 1.

 

Table 1. Determination of auto-ignition temperature of test item

 

Temperature (flask inside)	External Temperature	Ignition	Sample amount	Ignition delay time
231°C	242°C	-	100 µL	-
278°C	291°C	-	100 µL	-
321°C	337°C	-	100 µL	-
369°C	387°C	+	100 µL	11 sec
345°C	362°C	-	100 µL	-
360°C	377°C	-	100 µL	-
364°C	382°C	-	100 µL	-
367°C	385°C	-	100 µL	-
369°C	389°C	-	200 µL	-
372°C	392°C	-	200 µL	-
400°C	421°C	+	200 µL	4 sec
388°C	408°C	+	200 µL	12 sec
380°C	400°C	+	200 µL	16 sec
376°C	394°C	-	200 µL	-
-       - not ignited -       + ignited

The measured auto-ignition temperature of the test item was: 380°C.

Applicant's summary and conclusion

Conclusions:

The measured auto-ignition temperature of Ethanol, 2-(2-butoxyethoxy)-, reaction products with phosphorus oxide (P2O5), compds. with N,N-dimethylcyclohexanamine was 380°C.

Executive summary:

The auto-ignition temperature is the lowest temperature of the inner surface of an enclosure that results in ignition of a gas, vapour or liquid injected into the enclosure. The objective of this study was to determine the auto-ignition temperature of the test item in air at atmospheric pressure. A small sample of the test item (liquid) was inserted into an uniformly heated 500 mL glass flask containing air at a predetermined temperature. The lowest temperature at which hot-flame ignition occurs for a series of prescribed sample volumes was taken to be the hot-flame auto-ignition temperature of the chemical.

The measured auto-ignition temperature of Ethanol, 2-(2-butoxyethoxy)-, reaction products with phosphorus oxide (P2O5), compds. with N,N-dimethylcyclohexanamine was 380°C.

.