Registration Dossier
Registration Dossier
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EC number: 288-896-1 | CAS number: 85940-08-5 This substance is identified in the Colour Index by Colour Index Constitution Number, C.I. 53015.
Flammability
Administrative data
- Endpoint:
- self-heating substances / mixtures
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 2017-08-11 - 2018-04-06
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 018
- Report date:
- 2018
Materials and methods
Test guidelineopen allclose all
- Qualifier:
- according to guideline
- Guideline:
- UN Manual of Tests and Criteria: Test N.4 (Test method for self-heating substances)
- Version / remarks:
- Rev. 6, 2015
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- other: VDI 2263, sheet 1, Grewer Oven
- Version / remarks:
- 1990
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
Test material
- Reference substance name:
- Acetamide, N-(2,4-dinitrophenyl)-, reaction products with 1-methyl-2,4-dinitrobenzene and sodium sulfide (Na2(Sx)), leuco derivatives
- EC Number:
- 288-896-1
- EC Name:
- Acetamide, N-(2,4-dinitrophenyl)-, reaction products with 1-methyl-2,4-dinitrobenzene and sodium sulfide (Na2(Sx)), leuco derivatives
- Cas Number:
- 85940-08-5
- Molecular formula:
- not applicable
- IUPAC Name:
- Reaction product of N-(2,4-dinitrophenyl)acetamide with 1-methyl-2,4-dinitrobenzene and polysulfide, leuco derivatives
- Test material form:
- solid: particulate/powder
- Details on test material:
- Test item: Leuco Sulphur Brown 46
Appearance: Brown powder
CAS No: 85940-08-5
Constituent 1
- Specific details on test material used for the study:
- Reagents: Kieselguhr
Batch No.: TA2082010
Identity and content: Conforms
Certificate of analysis: Certificate of Analysis dated 2016-10-20; Merck KGaA, Frankfurter Straße 250, 64293 Darmstadt
Expiry date: 2021-10-31
Results and discussion
Self-heating substances / mixtures
- Key result
- Test procedure:
- other: Onset temperature in the Grewer oven
- Result:
- negative outcome (no effect observed)
- Remarks on result:
- other:
Any other information on results incl. tables
Self-ignition in the Grewer Oven
In the investigation of self-ignition in the Grewer Oven for the pure test item, an endothermic effect was detected in the temperature range of 50 – 110 °C, which may be caused by the drying of the test item. No further thermal effects could be observed up to maximum test temperature of 425 °C. After the measurement a black residue remained in the basket.
For the test item in mixture with Kieselguhr an endothermic effect was detected, in the temperature range of 40 – 70 °C, which may also be caused by the drying of the test item. No further thermal effects could be observed up to maximum test temperature of 425 °C.
Table 1 summarizes the results of the Grewer Oven experiment.
Table 1: Results of the screening test for self-ignition in the Grewer Oven
Experiment |
Onset self- |
Maximum temperature / °C |
Remarks |
Pure test item |
--- |
--- |
|
Test item in mixture |
--- |
--- |
Applicant's summary and conclusion
- Interpretation of results:
- GHS criteria not met
- Conclusions:
- The pure test item Leuco Sulphur Brown 46 indicated no self-heating at atmospheric pressure up to maximum test temperature of 425 °C.
On the basis of the results of the tests on the self-ignition in the Grewer Oven the test item is classified as follows:
UN Transport Regulation: The test item has not to be classified as self-heating substance in class 4, division 4.2 according to the UN Transport Regulation.
GHS / CLP Regulation EC 1272/2008 Annex 1: 2.11: The test item has not to be classified as self-heating substance according to GHS/CLP Regulation EC 1272/2008 Annex 1: 2.11. - Executive summary:
Summary
The pure test item Leuco Sulphur Brown 46 indicated no self-heating at atmospheric pressure up to maximum test temperature of 420 °C.
On the basis of the results of the tests on the self-ignition in the Grewer Oven the test item is classified as follows:
UN Transport Regulation: The test item has not to be classified as self-heating substance in class 4, division 4.2 according to the UN Transport Regulation.
GHS / CLP Regulation EC 1272/2008 Annex 1: 2.11: The test item has not to be classified as self-heating substance according to GHS/CLP Regulation EC 1272/2008 Annex 1: 2.11.
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