Registration Dossier
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Diss Factsheets
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EC number: 202-870-9 | CAS number: 100-61-8
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
• General information:
Personal protection for the First Aider.
Take affected persons out of danger area and lay down.
Immediately remove any clothing soiled by the product.
Remove breathing equipment only after contaminated clothing have been completely removed.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident the accident.
• After inhalation:
Supply fresh air or oxygen; call for doctor.
In case of unconsciousness place patient stably in side position for transportation.
If breathing stops, provide artificial respiration.
• After skin contact:
Clean with water and soap. If possible, also wash with polyethylene glycol 400.
Take off immediately all contaminated clothing
Call a doctor immediately.
• After eye contact:
Remove contact lenses.
Protect unharmed eye.
Rinse opened eye for several minutes under running water. Then consult a doctor.
• After swallowing:
Rinse out mouth and then drink plenty of water.
Induce vomiting and call for medical help.
Do not give alcohol, milk or fatty oils.
A person vomiting while laying on their back should be turned onto their side.
Never give anything to the mouth of an unconscious person.
• Information for doctor: No specific therapy is known.
• Most important symptoms and effects, both acute and delayed
Breathing difficulty
Headache
Dizziness
Cramp
Dizziness
Cyanosis
Methaemoglobinaemia
Unconsciousness
Nausea
Drowsiness
Vomiting
Fire-fighting measures
Extinguishing media
• Suitable extinguishing agents:
Use fire extinguishing methods suitable to surrounding conditions.
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
• For safety reasons unsuitable extinguishing agents: Water with full jet
• Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
In case of fire, the following can be released:
Nitrogen oxides (NOx)
Carbon monoxide and carbon dioxide
• Advice for firefighters
• Protective equipment:
Do not inhale explosion gases or combustion gases.
Wear fully protective suit.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Accidental release measures
• Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Use respiratory protective device against the effects of fumes/dust/aerosol.
Avoid contact with any product
• Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to penetrate the ground/soil.
In case of seepage into the ground inform responsible authorities.
• Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Send for recovery or disposal in suitable receptacles.
Dispose contaminated material as waste according to disposal considerations.
Ensure adequate ventilation.
Handling and storage
• Handling:
• Precautions for safe handling
Keep receptacles tightly sealed.
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Restrict the quantity stored at the work place.
Wear suitable respiratory protective device when aerosols are formed.
• Information about fire - and explosion protection:
Keep respiratory protective device available.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Fumes can combine with air to form an explosive mixture.
When heatet the product forms flammable fumes.
• Conditions for safe storage, including any incompatibilities
• Storage:
• Requirements to be met by storerooms and receptacles:
Provide solvent resistant, sealed floor.
Provide floor trough without outlet.
Prevent any seepage into the ground.
Store only in unopened original receptacles.
Store in a cool, dry place.
• Information about storage in one common storage facility:
Store away from feed and foodstuffs.
Do not store together with oxidizing and acidic materials.
• Further information about storage conditions:
Keep container tightly sealed.
Avoid contact with air / oxygen.
Protect from exposure to the light.
Store under lock and key and with access restricted to technical experts or their assistants only.
Store in the dark.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 2294
Shipping information
- Proper shipping name and description:
- N-METHYLANILINE
- Chemical name:
- N-Methylaniline
- Language:
- English
- Labels:
- 6.1, Enviromentally Hazardous
Special provisions / remarks
- Special provisions:
- CV13 CV28
- Remarks:
- Danger code: 60
Limited quantity:5 l
Packing instruction: P001, IBC03, LP01, R001
Mixed packing provision: MP19
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 2294
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 2294
Shipping information
- Proper shipping name and description:
- N-METHYLANILINE
- Chemical name:
- N-Methylaniline
- Labels:
- 6.1
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 2294
Shipping information
- Proper shipping name and description:
- N-METHYLANILINE
- Chemical name:
- N-Methylaniline
- Labels:
- 6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Additional information about design of technical facilities: No further data; see item 7.
• Control parameters
• Ingredients with limit values that require monitoring at the workplace:
100-61-8 N-Methylaniline
WEL Long-term value: 2.2 mg/m³, 0.5 ppm Sk
• Additional information: The lists valid during the making were used as basis.
• Exposure controls
• Personal protective equipment:
• General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Do not inhale gases / fumes / aerosols.
Be sure to clean skin thoroughly after work and before breaks.
Ensure that washing facilities are available at the work place.
• Respiratory protection:
If vapours or aerosols occur wear suitable respiratory device.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
Short term filter device:
Filter A
• Protection of hands:
Chemicals resistant gloves.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Softening of the callus when wearing air-impermeable gloves is possible.
Check protective gloves prior to each use for their proper condition.
If only a short-term loading of the glove material by splashes is expected, tricoted gloves with higher
wearability for the better acceptance of the users are recommended.
After use of gloves apply skin-cleaning agents and skin cosmetics.
• Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
Fluorocarbon rubber (Viton)
Recommended thickness of the material: 0.4 mm
• Penetration time of glove material
Breakthrough time 8 h
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
• As protection from splashes gloves made of the following materials are suitable:
Butyl rubber, BR
Fluorocarbon rubber (Viton)
• Not suitable are gloves made of the following materials:
Natural rubber, NR
Chloroprene rubber, CR
Nitrile rubber, NBR
PVC gloves
• Eye protection:
Safety glasses
• Body protection:
Protective work clothing
Boots
Apron
Use protective suit.
Selection of protective clothing is subject to the specific kind of work and the corresponding risk potential.
Stability and reactivity
• Reactivity
• Chemical stability
• Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
To avoid thermal decomposition do not overheat.
• Possibility of hazardous reactions
Reacts with strong acids and oxidizing agents.
Reacts with inorganic acid chlorides.
Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomised.
With nitrosing agents, nitrous acid, nitrites forming of nitrosamines possible.
• Conditions to avoid No further relevant information available.
• Incompatible materials:
oxidizing agents
Exposure to light.
• Hazardous decomposition products:
Danger of forming toxic pyrolysis products.
In case of fire, the following can be released:
Nitrogen oxides (NOx)
Carbon monoxide and carbon dioxide
• Additional information: light sensitive
Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
· European waste catalogue
16 00 00 WASTES NOT OTHERWISE SPECIFIED IN THE LIST
16 03 00 off-specification batches and unused products
16 03 05* organic wastes containing dangerous substances
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.