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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
10.03.2021 - 11.03.2021
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2021
Report date:
2021

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
other: UN Manual of Tests and Criteria, 7th edition, New York and Geneva, 2019: Appendix 6 Screening Procedures, Division 4.2: Substances which may be liable to spontaneous combustion
Deviations:
not specified
Qualifier:
according to guideline
Guideline:
other: VDI 2263 (1990), Grewer Oven
Deviations:
not specified
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
4-chlorobenzoic acid
EC Number:
200-805-9
EC Name:
4-chlorobenzoic acid
Cas Number:
74-11-3
Molecular formula:
C7H5ClO2
IUPAC Name:
4-chlorobenzoic acid
Test material form:
solid: particulate/powder
Details on test material:
white to yellowish crytalline powder

Results and discussion

Relative self-ignition temperature (solids)
Key result
Relative self-ignition temperature:
> 410 °C
Remarks on result:
no self ignition observed under the test conditions

Any other information on results incl. tables

In the investigation of self-ignition in the Grewer Oven for the pure test item an endothermic effect could be observed starting at a temperature of 190 °C which can be assigned the melting to the test item. No further thermal effects could be observed up to the maximum test temperature of 410 °C. After the test the wire basket was empty.

For the test item in mixture with Kieselguhr an endothermic effect could be observed starting at a temperature of 190 °C which can be assigned the melting to the test item. No further thermal effects could be observed up to the maximum test temperature of 410 °C.A white residue (Kieselguhr) remained in the wire basket after the test.

Applicant's summary and conclusion

Conclusions:
On the basis to the results of the tests on the self-ignition in the Grewer Oven the test item is classified as follows:
UN Transport Regulation: The test item does not have to be classified as self-heating substance in Class 4, Division 4.2 according to the UN Transport Regulation.
GHS / CLP Regulation (EC) No. 1272/2008 Annex I: 2.11: The test item does not have to be classified as self-heating substance according to GHS / CLP Regulation (EC) No. 1272/2008 Annex I: 2.11
Executive summary:

The pure test item p-Chlorobenzoic acid showed an endothermic effect starting at a temperature of 200 °C which can be assigned the melting to the test item. No further thermal effects could be observed up to the maximum test temperature of 410 °C. The test item does not have to be classified as self-heating substance according to GHS / CLP Regulation (EC) No. 1272/2008 Annex I: 2.11.