Registration Dossier
Registration Dossier
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EC number: 944-271-1 | CAS number: -
Auto flammability
Administrative data
- Endpoint:
- auto-ignition temperature (liquids)
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 10 - 18 Sep 2019
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 020
- Report date:
- 2020
Materials and methods
Test guidelineopen allclose all
- Qualifier:
- according to guideline
- Guideline:
- ASTM E659 (Standard test method for autoignition temperature of liquid chemicals)
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
- GLP compliance:
- yes
Test material
- Reference substance name:
- Reaction mass of (((1,3-phenylenebis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate) and (1,3-phenylenebis(oxy))bis(propane-3,1-diyl) bis(2-methylacrylate) and 3-(3-(2-(2-(methacryloyloxy)ethoxy)ethoxy)phenoxy)propyl methacrylaterate
- EC Number:
- 944-271-1
- Cas Number:
- 2305048-54-6
- Molecular formula:
- not applicable for multi-constituent.
- IUPAC Name:
- Reaction mass of (((1,3-phenylenebis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate) and (1,3-phenylenebis(oxy))bis(propane-3,1-diyl) bis(2-methylacrylate) and 3-(3-(2-(2-(methacryloyloxy)ethoxy)ethoxy)phenoxy)propyl methacrylaterate
Constituent 1
- Specific details on test material used for the study:
- SOURCE OF TEST MATERIAL
- Lot/batch number of test material: 653940
- Purity, including information on contaminants, isomers, etc.: 100% UVCB (45.11% DiBrOE2RMA; 32.31% DiBrORMA; 15.24% DiBrE4RMA)
- Expiration date: February 2020
STABILITY AND STORAGE CONDITIONS OF TEST MATERIAL
- Storage condition of test material: Stored at room temperature in a dark, ventilated cabinet in the original container
Results and discussion
Auto-ignition temperature (liquids / gases)
- Key result
- Auto-ignition temperature:
- 390 °C
- Atm. press.:
- >= 764.538 - <= 770.613 mm Hg
- Remarks on result:
- other: auto-ignition likely due to reaction during decomposition
Any other information on results incl. tables
The average lowest temperature that ignition was observed to be 393.99 °C, which is greater than the decomposition temperature determined in the boiling point test. Following DIN 51794 guidelines, the auto-ignition temperature would be considered 390 °C. The auto-ignition temperature observed is dependent on the mass of the sample, which impacts the thermal transfer and kinetic properties during decomposition. Although auto-ignition was observed, the resulting flame was most likely due to the generation and ignition of gaseous degradation material produced during decomposition.
| Injection Volume (µL) | Internal Temperature (°C) | Vessel Temperature Prior to ignition (°C) | Ignition Delay Time (sec) | Barometirc Pressure (mmHg) | Observation |
| 100 | 152.28 | NA | NA | 768.138 | No ignition |
| 100 | 209.58 | NA | NA | 768.138 | No ignition |
| 100 | 433.92 | 433.53 | 7.09 | 768.138 | Bright Orange Flame |
| 100 | 434.17 | 434.08 | 6.37 | 768.138 | Bright Orange Flame |
| 100 | 404.17 | 405.55 | 26.19 | 768.138 | Bright Orange Flame |
| 100 | 405.53 | NA | NA | 768.138 | No ignition |
| 100 | 404.28 | NA | NA | 768.138 | No ignition |
| 100 | 403.93 | 404.45 | 12.56 | 768.138 | Bright Orange Flame |
| 100 | 372.83 | NA | NA | 768.138 | No ignition |
| 100 | 375.67 | NA | NA | 770.613 | No ignition |
| 100 | 379.27 | NA | NA | 770.613 | No ignition |
| 100 | 384.17 | NA | NA | 770.613 | No ignition |
| 100 | 387.86 | NA | NA | 770.613 | No ignition |
| 100 | 392.19 | 393.62 | 15.56 | 770.613 | Bright Orange Flame |
| 100 | 392.23 | NA | NA | 770.613 | No ignition |
| 100 | 390.89 | NA | NA | 770.613 | No ignition |
| 100 | 391.50 | 390.93 | 14.62 | 770.613 | Bright Orange Flame |
| 150 | 381.25 | NA | NA | 770.613 | No ignition |
| 150 | 384.56 | NA | NA | 770.613 | No ignition |
| 150 | 387.79 | NA | NA | 770.613 | No ignition |
| 150 | 392.55 | 393.31 | 20.31 | 770.613 | Bright Orange Flame |
| 150 | 392.70 | NA | NA | 770.613 | No ignition |
| 150 | 393.65 | NA | NA | 770.613 | No ignition |
| 150 | 392.51 | NA | NA | 764.838 | No ignition |
| 150 | 393.46 | 393.68 | 16.66 | 764.838 | Bright Orange Flame |
| 200 | 391.35 | 392.02 | 15.85 | 764.838 | Bright Orange Flame |
| 200 | 388.26 | NA | NA | 764.838 | No ignition |
| 200 | 392.22 | 391.88 | 14.15 | 764.838 | Bright Orange Flame |
| 250 | 389.42 | NA | NA | 764.838 | No ignition |
| 250 | 391.69 | 392.33 | 18.81 | 764.838 | Bright Orange Flame |
| 250 | 391.49 | NA | NA | 764.838 | No ignition |
| 250 | 392.69 | 394.42 | 23.75 | 765.438 | Bright Orange Flame |
| 70 | 390.21 | NA | NA | 765.438 | No ignition |
| 70 | 393.65 | 392.85 | 11.84 | 765.438 | Bright Orange Flame |
| 70 | 392.98 | NA | NA | 765.438 | No ignition |
| 70 | 392.35 | NA | NA | 765.438 | No ignition |
| 70 | 393.66 | NA | NA | 765.438 | No ignition |
| 70 | 392.96 | NA | NA | 765.438 | No ignition |
| 70 | 392.55 | NA | NA | 765.438 | No ignition |
| 70 | 393.53 | NA | NA | 764.538 | No ignition |
| 70 | 395.08 | NA | NA | 764.538 | No ignition |
| 70 | 394.96 | 394.33 | 14.53 | 764.538 | Bright Orange Flame |
| 50 | 392.97 | NA | NA | 764.538 | No ignition |
| 50 | 396.38 | 395.39 | 10.66 | 764.538 | Bright Orange Flame |
| 50 | 395.48 | NA | NA | 764.538 | No ignition |
| 50 | 396.32 | NA | NA | 764.538 | No ignition |
| 50 | 395.65 | NA | NA | 764.538 | No ignition |
| 50 | 394.32 | NA | NA | 764.988 | No ignition |
| 50 | 396.02 | NA | NA | 764.988 | No ignition |
| 50 | 396.76 | NA | NA | 764.988 | No ignition |
| 50 | 398.20 | 397.77 | 12.79 | 764.988 | Bright Orange Flame |
| 50 | 398.78 | NA | NA | 764.988 | No ignition |
| 50 | 397.52 | NA | NA | 764.988 | No ignition |
| 50 | 397.32 | NA | NA | 764.988 | No ignition |
| 50 | 398.57 | NA | NA | 764.988 | No ignition |
| 50 | 398.64 | NA | NA | 764.988 | No ignition |
| 50 | 398.90 | NA | NA | 764.988 | No ignition |
| 50 | 400.36 | NA | NA | 764.988 | No ignition |
| 50 | 397.62 | NA | NA | 764.988 | No ignition |
| 50 | 397.02 | NA | NA | 768.663 | No ignition |
| 50 | 398.67 | 399.40 | 20.85 | 768.663 | Bright Orange Flame |
| Overall | Mean: | 393.99 | 16.18 | ||
| St. Dev | 2.39 | 3.81 | |||
| %RSD | 0.605 | 23.5 |
Applicant's summary and conclusion
- Conclusions:
- The auto ignition of DiBrORMA was determined to be 390 °C at 764.538 - 770.613 mmHg (ASTM E659).
- Executive summary:
The auto ignition temperature of DiBrORMA was determined to be 393.99 °C. This value was rounded down to 390 °C per guideline. The auto-ignition temperature was dependent on the mass of the sample, which impacts the thermal transfer and kinetic properties during decomposition. It is also likely the resulting flame was due to the generation and ignition of gaseous degradation material produced during decomposition. The study was conducted in accordance with ASTM E659 and was GLP compliant. Therefore, the study is considered reliable without restrictions.
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