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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Flammability

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Administrative data

Endpoint:
self-heating substances / mixtures
Type of information:
experimental study
Adequacy of study:
key study
Study period:
01 March 2017 - 05 May 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2018
Report date:
2018

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
UN Manual of Tests and Criteria: Test N.4 (Test method for self-heating substances)
Version / remarks:
Rev. 6 (2015)
Deviations:
no
GLP compliance:
yes (incl. QA statement)

Test material

1
Chemical structure
Reference substance name:
Xanthylium, 3,6-bis(ethylamino)-9-[2-(methoxycarbonyl)phenyl]-2,7-dimethyl-, molybdatesilicate
EC Number:
278-270-6
EC Name:
Xanthylium, 3,6-bis(ethylamino)-9-[2-(methoxycarbonyl)phenyl]-2,7-dimethyl-, molybdatesilicate
Cas Number:
75627-12-2
Molecular formula:
C54H58N4O6.MoO4 + C54H58N4O6.SiO3
IUPAC Name:
3,6-bis(ethylamino)-9-[2-(methoxycarbonyl)phenyl]-2,7-dimethyl-10λ⁴-xanthen-10-ylium dioxomolybdenumbis(olate) silicate
Test material form:
solid: particulate/powder
Details on test material:
- Appearance: Pink powder
- Storage conditions: At room temperature
Specific details on test material used for the study:
decomposition temp.: 175°C

Results and discussion

Self-heating substances / mixtures
Key result
Test procedure:
100 mm sample cube at 140°C
Result:
negative outcome (no effect observed)

Any other information on results incl. tables

An exothermic effect of the test item by self-heating was observed at an oven temperature of 142°C. During this effect the test item reached a temperature of 152°C. According to the guideline, the test is positive when the sample temperature exceeds the oven temperature by 60°C during the 24 hour testing time. Based on this, the result is considered negative and it demonstrated that the test item is “not a self-heating substance”.

After the experiment, the test item had turned into a darker pink residue. The change of colour might be due to decomposition/reaction.

 

Applicant's summary and conclusion

Interpretation of results:
other: not classified based on GHS or CLP criteria
Conclusions:
The substance is not self-heating.

Executive summary:

In a GLP study according to UN Test N.4, a negative result was obtained using a 10 cm sample cube at 140°C. From this it was concluded that C.I. Pigment Red 81:2 is not a self-heating substance.