Registration Dossier
Registration Dossier
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EC number: 206-788-4 | CAS number: 375-50-8
Guidance on Safe Use
Guidance on Safe Use
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Administrative data
First-aid measures
In case of inhalation
- Move to fresh air in case of accidental inhalation of vapours or decomposition products.
- Oxygen or artificial respiration if needed.
- Immediate medical attention is required.
In case of skin contact
- Wash off immediately with plenty of water for at least 15 minutes.
- Consult a physician.
In case of eye contact
- In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- Consult a physician.
In case of ingestion
- Drink 1 or 2 glasses of water.
- Do NOT induce vomiting.
- Consult a physician.
In case of ingestion
- Drink 1 or 2 glasses of water.
- Do NOT induce vomiting.
- Consult a physician.
- Move to fresh air in case of accidental inhalation of vapours or decomposition products.
- Oxygen or artificial respiration if needed.
- Immediate medical attention is required.
In case of skin contact
- Wash off immediately with plenty of water for at least 15 minutes.
- Consult a physician.
In case of eye contact
- In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- Consult a physician.
In case of ingestion
- Drink 1 or 2 glasses of water.
- Do NOT induce vomiting.
- Consult a physician.
In case of ingestion
- Drink 1 or 2 glasses of water.
- Do NOT induce vomiting.
- Consult a physician.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media
- Water
- powder
- Foam
- Dry chemical
- Carbon dioxide (CO2)
Unsuitable extinguishing media
- None
Special hazards arising from the substance or mixture
- The product is not flammable.
- Not explosive
- In case of fire hazardous decomposition products may be produced such as: Gaseous hydrogen fluoride (HF), Fluorophosgene
- Iodine compounds
- hydrogen iodide
Advice for firefighters
Special protective equipment for firefighters
- Wear self-contained breathing apparatus and protective suit.
- When intervention in close proximity wear acid resistant over suit.
Further information
- Evacuate personnel to safe areas.
- Approach from upwind.
- Protect intervention team with a water spray as they approach the fire.
- Keep containers and surroundings cool with water spray.
- Keep product and empty container away from heat and sources of ignition
Suitable extinguishing media
- Water
- powder
- Foam
- Dry chemical
- Carbon dioxide (CO2)
Unsuitable extinguishing media
- None
Special hazards arising from the substance or mixture
- The product is not flammable.
- Not explosive
- In case of fire hazardous decomposition products may be produced such as: Gaseous hydrogen fluoride (HF), Fluorophosgene
- Iodine compounds
- hydrogen iodide
Advice for firefighters
Special protective equipment for firefighters
- Wear self-contained breathing apparatus and protective suit.
- When intervention in close proximity wear acid resistant over suit.
Further information
- Evacuate personnel to safe areas.
- Approach from upwind.
- Protect intervention team with a water spray as they approach the fire.
- Keep containers and surroundings cool with water spray.
- Keep product and empty container away from heat and sources of ignition
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel
- Prevent further leakage or spillage if safe to do so.
Advice for emergency responders
- Ensure adequate ventilation.
- Sweep up to prevent slipping hazard.
- Keep away from open flames, hot surfaces and sources of ignition.
- Refer to protective measures listed in sections 7 and 8.
Environmental precautions
- Should not be released into the environment.
- Do not flush into surface water or sanitary sewer system.
Methods and materials for containment and cleaning up
- Soak up with inert absorbent material.
- Suitable material for picking up.
- Dry sand
- Earth
- Shovel into suitable container for disposal.
Advice for non-emergency personnel
- Prevent further leakage or spillage if safe to do so.
Advice for emergency responders
- Ensure adequate ventilation.
- Sweep up to prevent slipping hazard.
- Keep away from open flames, hot surfaces and sources of ignition.
- Refer to protective measures listed in sections 7 and 8.
Environmental precautions
- Should not be released into the environment.
- Do not flush into surface water or sanitary sewer system.
Methods and materials for containment and cleaning up
- Soak up with inert absorbent material.
- Suitable material for picking up.
- Dry sand
- Earth
- Shovel into suitable container for disposal.
Handling and storage
Precautions for safe handling
- Ensure adequate ventilation.
- Keep away from heat and sources of ignition.
- Use personal protective equipment.
- Take measures to prevent the build up of electrostatic charge.
- To avoid thermal decomposition, do not overheat.
- Clean and dry piping circuits and equipment before any operations.
- Ensure all equipment is electrically grounded before beginning transfer operations.
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Technical measures/Storage conditions
- Keep in properly labelled containers.
- Keep away from heat and sources of ignition.
- Keep away from combustible material.
- Keep away from incompatible products
- Protect against light.
- Avoid moisture.
- Keep in a dry place.
- Provide tight electrical equipment well protected against corrosion.
Packaging material
Suitable material
- stainless steel 304L / 316L
- Ensure adequate ventilation.
- Keep away from heat and sources of ignition.
- Use personal protective equipment.
- Take measures to prevent the build up of electrostatic charge.
- To avoid thermal decomposition, do not overheat.
- Clean and dry piping circuits and equipment before any operations.
- Ensure all equipment is electrically grounded before beginning transfer operations.
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Technical measures/Storage conditions
- Keep in properly labelled containers.
- Keep away from heat and sources of ignition.
- Keep away from combustible material.
- Keep away from incompatible products
- Protect against light.
- Avoid moisture.
- Keep in a dry place.
- Provide tight electrical equipment well protected against corrosion.
Packaging material
Suitable material
- stainless steel 304L / 316L
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3082
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (1,1,2,2,3,3,4,4-Octafluoro-1,4-diiodobutane)
- Labels:
- 9
Special provisions / remarks
- Special provisions:
- Hazard Identification Number: 90
Tunnel restriction code (-)
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 3082
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(1,1,2,2,3,3,4,4-Octafluoro-1,4-diiodobutane)
- Labels:
- 9
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3082
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(1,1,2,2,3,3,4,4-Octafluoro-1,4-diiodobutane)
- Labels:
- 9
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 3082
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (1,1,2,2,3,3,4,4-Octafluoro-1,4-diiodobutane)
- Labels:
- 9
Special provisions / remarks
- Remarks:
- Special precautions for user
Packing instruction (cargo aircraft) 964
Max net qty/pkg 450.00 L
Packing instruction (passenger aircraft) 964
Max net qty/pkg 450.00 L
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure controls
Control measures
Engineering measures
- Ensure adequate ventilation.
- Refer to protective measures listed in sections 7 and 8.
- Apply technical measures to comply with the occupational exposure limits.
Individual protection measures
Respiratory protection
- In case of insufficient ventilation, wear suitable respiratory equipment.
- In case of vapour or mist, face mask with combined ABEK-P2 cartridge.
- In case of decomposition (see section 10), use an air breathing apparatus with face mask.
- Use only respiratory protection that conforms to international/ national standards.
Hand protection
- Wear protective gloves.
Suitable material
- Nitrile rubber
- Neoprene gloves
Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
Eye protection
- Tightly fitting safety goggles
Skin and body protection
- Wear work overall and safety shoes.
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls
- Dispose of rinse water in accordance with local and national regulations.
Control measures
Engineering measures
- Ensure adequate ventilation.
- Refer to protective measures listed in sections 7 and 8.
- Apply technical measures to comply with the occupational exposure limits.
Individual protection measures
Respiratory protection
- In case of insufficient ventilation, wear suitable respiratory equipment.
- In case of vapour or mist, face mask with combined ABEK-P2 cartridge.
- In case of decomposition (see section 10), use an air breathing apparatus with face mask.
- Use only respiratory protection that conforms to international/ national standards.
Hand protection
- Wear protective gloves.
Suitable material
- Nitrile rubber
- Neoprene gloves
Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
Eye protection
- Tightly fitting safety goggles
Skin and body protection
- Wear work overall and safety shoes.
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls
- Dispose of rinse water in accordance with local and national regulations.
Stability and reactivity
Reactivity
- Contact with water liberates hazardous gas.
Chemical stability
- Stable under recommended storage conditions.
Possibility of hazardous reactions
- No dangerous reaction known under conditions of normal use.
Conditions to avoid
- Exposure to light.
- Exposure to moisture
- To avoid thermal decomposition, do not overheat.
- Keep away from flames and sparks.
Incompatible materials
- Water
- Alkaline earth metals
- Alkali metals
Hazardous decomposition products
- Thermal decomposition can lead to release of hazardous gases and vapors
- iodine
- The release of other hazardous decomposition products is possible.
- hydrogen iodide
- Gaseous hydrogen fluoride (HF).
- Fluorophosgene
- Contact with water liberates hazardous gas.
Chemical stability
- Stable under recommended storage conditions.
Possibility of hazardous reactions
- No dangerous reaction known under conditions of normal use.
Conditions to avoid
- Exposure to light.
- Exposure to moisture
- To avoid thermal decomposition, do not overheat.
- Keep away from flames and sparks.
Incompatible materials
- Water
- Alkaline earth metals
- Alkali metals
Hazardous decomposition products
- Thermal decomposition can lead to release of hazardous gases and vapors
- iodine
- The release of other hazardous decomposition products is possible.
- hydrogen iodide
- Gaseous hydrogen fluoride (HF).
- Fluorophosgene
Disposal considerations
Waste treatment methods
Product Disposal
- Can be incinerated, when in compliance with local regulations.
- The incinerator must be equipped with a system for the neutralisation or recovery of HF.
- In accordance with local and national regulations.
Advice on cleaning and disposal of packaging
- Empty containers can be landfilled, when in accordance with the local regulations.
Product Disposal
- Can be incinerated, when in compliance with local regulations.
- The incinerator must be equipped with a system for the neutralisation or recovery of HF.
- In accordance with local and national regulations.
Advice on cleaning and disposal of packaging
- Empty containers can be landfilled, when in accordance with the local regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
