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Diss Factsheets

Environmental fate & pathways

Monitoring data

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Administrative data

Endpoint:
monitoring data
Type of information:
experimental study
Adequacy of study:
supporting study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
study well documented, meets generally accepted scientific principles, acceptable for assessment

Data source

Reference
Reference Type:
publication
Title:
Monitoring of environmental fingerprints of alcohol ethoxylates in Europe and Canada
Author:
Eadsforth C V, Sherren A J, Selby M A, Toy R, Eckhoff W S, McAvoy D C, Matthijs E
Year:
2006
Bibliographic source:
Ecotox. and Environ Safety, 64(1): 14-29

Materials and methods

Principles of method if other than guideline:
The EU samples were obtained during 2001-2 from municipa waste water treatment plants. Each was obtained over a 24-hour period, and preserved by addition of formalin at the time of sampling.
Samples of 4 litres ware obtained and extracted onto a succession of cartridges, followed by solvent elution.
Quantitative analysis of the eluates was by a derivatisation .Liquid-chromatography-mass spectrometric (LCMS) technique.
Samples from Canada were grab samples obtained during August 2003, and were preserved with formalin.
GLP compliance:
not specified
Type of measurement:
other: Concentrations of alcohols and alcohol ethoxylates were measured.
Media:
other: Effluent monitoring of 20 biofilm and activated sludge wastewater treatment plants from Europe and Canada receiving predominantly municipal effluent.

Test material

Constituent 1
Chemical structure
Reference substance name:
Alcohols, C12-14
EC Number:
279-420-3
EC Name:
Alcohols, C12-14
Cas Number:
80206-82-2
Molecular formula:
C13H28O
IUPAC Name:
Alcohols, C12-14

Results and discussion

Any other information on results incl. tables

Result:   In the results, Provinces are indicated as 2-letter abbreviations.

Results are presented as µg/concentrations as:

 

  

Location:

C12

C13

C14

C15

C16

C18

Total

Treatment Type

 

 

 

 

 

 

 

Vernon, BC: TF

0.393

0.174

0.428

0.886

0.452

0.718

3.051

Kelowna, BC: AS

0.243

0.102

0.107

0.181

0.095

0.121

0.849

Toronto, ON: AS

0.027

0.235

0.548

0.312

0.883

0.492

2.497

La Prairie,QC: AS    

0.070

0.030

0.029

0.041

0.057

0.068

0.295

Victoriaville, QC: AS

0.069

0.019

0.014

0.048

0.026

0.109

0.285

Paris, ON, AS

0.036

0.030

0.033

0.059

0.083

0.060

0.301

Cardston, AB: RBC

1.251

0.961

3.354

3.257

3.180

2.174

14.2

Waterloo, ON: AS

0.301

0.122

0.156

0.172

0.160

0.127

1.038

 

 

 

TF = trickling filter

AS = activated sludge

RBC = rotating biological contactor

 

 

Data from activated sludge plants in Europe:

 

Total alcohol µg/L

Location:

C12

C13

C14

C15

C16

C18

Total

Northwich, UK

0.468

0.319

0.305

0.154

0.485

0.591

2.322

Cannock, UK

0.104

0.087

0.069

0.084

0.179

0.318

0.841

Rushmoor, UK

0.134

0.104

0.095

0.125

0.338

0.408

1.204

Kralingse Veer, NL

0.410

0.147

0.138

0.125

0.368

0.138

1.326

De Meern, NL

0.282

0.208

0.174

0.155

0.472

0.239

1.53

Horstermeer,NL

0.360

0.211

0.212

0.136

0.598

1.209

2.726

Estepona, ES

0.214

0.073

0.182

0.148

0.999

1.144

2.76

La Vibora, ES

1.179

0.533

1.741

1.181

4.172

2.426

11.23

Munich, DE

0.010

0.023

0.007

0.034

0.005

0.008

0.087

Torino, IT

0.070

0.094

0.057

0.058

0.419

0.038

0.736

Robecco, IT

0.092

0.130

0.072

0.206

0.187

0.266

0.953

Ratingen, DE

0.046

0.052

0.033

0.083

0.037

0.068

0.319

 

 

(usual country and US state designators)

 

Results for all carbon numbers are considered alongside each other to enable the context of every data point to be seen.

In the overall interpretation of the data, the results have been used with those from other studies to determine the contribution of measured alcohol concentrations from various sources.

 

 

Applicant's summary and conclusion