Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

General advice:
Immediately remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:
Wash thoroughly with soap and water.

On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention..

Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11 of the MSDS. Further important symptoms and effects are so far not known.
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

Suitable extinguishing media:
water spray, dry powder, foam

Specific hazards:
harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire.

Advice for firefighters:
Special protective equipment: Wear a self-contained breathing apparatus

Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.

Accidental release measures

Personal precautions:
Use personal protective clothing.

Environmental precautions:
Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.

Methods for cleaning up or taking up:
For small amounts: Pick up with suitable appliance and dispose of.
For large amounts: Pick up with suitable appliance and dispose of.

Handling and storage

Handling
No special measures necessary provided product is used correctly.

Protection against fire and explosion:
No special precautions necessary.

Storage

Suitable materials for containers: Stainless steel 1.4401, Stainless steel 1.4301 (V2), Glass reinforced plastic (GRP), High density polyethylene (HDPE), carbon steel (iron), tin (tinplate), glass, Low density polyethylene (LDPE)
Further information on storage conditions: Keep container tightly closed and dry; store in a cool place.

Storage stability:
Storage temperature: -5 - 40 °C
Protect from temperatures above: 40 °C

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

Components with workplace control parameters
141-43-5: 2-aminoethanol
TWA value 2.5 mg/m3 ; 1 ppm (OEL (EU)) indicative
STEL value 7.6 mg/m3 ; 3 ppm (OEL (EU)) indicative
Skin Designation (OEL (EU))
The substance can be absorbed through the skin.
50-00-0: formaldehyde
Hazardous Components with PNEC
4719-04-4: 2,2',2"-(hexahydro-1,3,5-triazine-1,3,5-triyl)triethanol
freshwater: 0.0066 mg/l
marine water: 0.00066 mg/l
intermittent release: 0.06 mg/l
sediment (freshwater): 0.0304 mg/kg
sediment (marine water): 0.00304 mg/kg
soil: 0.00219 mg/kg
STP: 5.5 mg/l
Hazardous Components with DNEL
4719-04-4: 2,2',2"-(hexahydro-1,3,5-triazine-1,3,5-triyl)triethanol
worker: Long-term exposure- systemic effects, Inhalation: 19 mg/m3

Personal protective equipment
Respiratory protection:
Suitable respiratory protection for lower concentrations or short-term effect: Particle filter with high efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P3 or FFP3).

Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment.

Stability and reactivity

Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Formation of flammable gases:
Remarks: Forms no flammable gases in the presence of water.

Chemical stability
The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions
No hazardous reactions when stored and handled according to instructions. If product is heated above decomposition temperature toxic vapours may be released. The product tends to decompose under the impact of acids in the presence of moisture or water

Conditions to avoid:
Avoid heat. Avoid dust formation. Avoid evaporation/volatilization of the solvent.
Incompatible materials
Substances to avoid: acids
Hazardous decomposition products:
formaldehyde, 2-aminoethanol

The substances/substance groups mentioned are formed by hydrolysis., Traces of the substances/groups of substances are released as decomposition products of the dry substance. Traces of the substances/groups of substances mentioned can be released at elevated temperatures.,
The substances/groups of substances mentioned may be released upon the reaction with acids.

Disposal considerations

Must be dumped or incinerated in accordance with local regulations.

Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.