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Diss Factsheets

Administrative data

Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
test procedure in accordance with national standard methods
Remarks:
Directive VDI 2263, Sheet 1

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2016
Report date:
2016

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: Directive VDI 2263, Part 1

Test material

Constituent 1
Chemical structure
Reference substance name:
Disodium 4,8-diamino-1,5-dihydroxy-9,10-dioxoanthracene-2,6-disulphonate
EC Number:
220-678-3
EC Name:
Disodium 4,8-diamino-1,5-dihydroxy-9,10-dioxoanthracene-2,6-disulphonate
Cas Number:
2861-02-1
Molecular formula:
C14H10N2O10S2.2Na
IUPAC Name:
disodium 4,8-diamino-1,5-dihydroxy-9,10-dioxo-9,10-dihydroanthracene-2,6-disulfonate

Results and discussion

Relative self-ignition temperature (solids)open allclose all
Relative self-ignition temperature:
>= 220 °C
Remarks on result:
other: pure test substance
Remarks:
at atm. press. of ca.1013.0 hPa
Relative self-ignition temperature:
>= 240 °C
Remarks on result:
other: 1:1 mixture of test substance with Kieselguhr
Remarks:
at atm. press. of ca.1013.0 hPa

Any other information on results incl. tables

In the screening test according to Grewer with the pure product an endothermal effect was observed in the temperature range 70 - 180°C, followed by an exothermal effect starting at 230°C. A multistage reaction was observed which led to a maximum product temperature of more than 550°C.

In the screening test with the kieselgur mixture (1:1) an endothermal effect was observed in the temperature range 70 - 140°C. At a temperature of 250 °C an exothermal effect started. Self-heating led to a temperature of approximately 650 °C

After the test the test item was black.

See figures 1 and 2 (attachment)

Applicant's summary and conclusion

Conclusions:
The substance has not to be classified as self-heating according to Regulation (EC) No 1272/2008, Annex I, 2.11.4