Registration Dossier
Registration Dossier
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EC number: 814-155-4 | CAS number: 13188-82-4
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Immediately remove contaminated clothing.
If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.
On skin contact: Wash thoroughly with soap and water
On contact with eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.
On ingestion: Rinse mouth and then drink 200-300 ml of water. Do not induce vomiting unless told to by a poison
control center or doctor.
Most important symptoms and effects, both acute and delayed
Symptoms: Information, i.e. additional information on symptoms and effects may be included in the GHS labeling phrases available in Section 2 of sds and in the Toxicological assessments available in Section 11of sds.
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: water spray, dry powder, foam
Unsuitable extinguishing media for safety reasons: water jet
Special hazards arising from the substance or mixture
Endangering substances: harmful vapours
Advice: Evolution of fumes/fog. The substances/groups of substances mentioned can be released in
case of fire.
Danger of selfpolymerisation if container is overheated.
Advice for fire-fighters
Special protective equipment:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Use personal protective clothing. Breathing protection required.
Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations.
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13 of the sds.
Handling and storage
Precautions for safe handling
Handle in accordance with good industrial hygiene and safety practice. The substance/ product may be handled only by appropriately trained personnel. Facility parts must be checked for polymer residues and cleaned on regular basis in order to avoid hazardous reactions.
Ensure thorough ventilation of stores and work areas. Encapsulation or exhaust ventilation required. When filling, transferring, or emptying of containers, adequate local exhaust ventilation is necessary. Vent waste air to atmosphere only through suitable separators. Check the condition of seals and connector screw threads. Do not open warm or swollen product containers. Remove persons to safety and alert fire brigade.
The temperatures which must be avoided are to be considered. Protect against heat. Protect from direct sunlight. Protect contents from the effects of light.
Ensure adequate inhibitor and dissolved oxygen level.
Protection against fire and explosion:
Ground all transfer equipment properly to prevent electrostatic discharge. Containers should be grounded against electrostatic charge. It is recommended that all conductive parts of the machinery are grounded. Vapours may form ignitable mixture with air. Avoid all sources of ignition: heat, sparks, open flame.
Heated containers should be cooled to prevent polymerization. If exposed to fire, keep containers cool by spraying with water. Sealed containers should be protected against heat as this results in pressure build-up. Avoid influence of heat.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep container tightly closed in a cool, well-ventilated place. Keep container dry
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- Not applicable
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Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- Not applicable
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Marine transport (UN RTDG/IMDG)
- UN number:
- Not applicable
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- Not applicable
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Additional transport information
Additional information
- Special provisions / remarks / other:
- Not classified as a dangerous good under transport regulations
Exposure controls / personal protection
Control parameters
Components with occupational exposure limits:
No occupational exposure limits known.
Exposure controls
Personal protective equipment:
Respiratory protection:
Suitable respiratory protection for lower concentrations or short-term effect: Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)
Hand protection:
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures
Avoid contact with the skin, eyes and clothing. Avoid inhalation of vapour. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Handle in accordance with good industrial hygiene and safety practice.
Stability and reactivity
Reactivity
No applicable information available.
Corrosion to metals: Corrosive effects to metal are not anticipated.
Reactions with water/air:
Flammable gases: no
Toxic gases: no
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Peroxides:
The product/the substance has a tendency towards the formation of peroxide. The product is stabilized for transport.
Possibility of hazardous reactions:
Risk of spontaneous and violent self-polymerization if inhibitor is lost or product is exposed to excessive heat. Risk of spontaneous polymerization by oxygen depletion of the liquid phase.
The product is stabilized against spontaneous polymerization prior to despatch.
Conditions to avoid:
Avoid prolonged storage. Avoid oxygen content above the product of less than 5 %. Avoid excessive temperatures. Avoid heat. Avoid UV-light and other radiation with high energy.
Incompatible materials
Substances to avoid:
Inert gas, radical formers, free radical initiators, peroxides, mercaptans, nitro-compounds, perborates, azides, ether, ketones, aldehydes, amines, nitrates, nirides, oxidizing agents, reducing agents, strong bases, alkaline reactive substances, acid anhydrides, acid chlorides, concentrated acids, metal salts
Hazardous decomposition products
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
Disposal considerations
Waste treatment methods
Must be disposed of or incinerated in accordance with local regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Packs that cannot be cleaned should be disposed of in the same manner as the contents.
Uncontaminated packaging can be re-used.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
