Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 223-893-0 | CAS number: 4111-54-0
Guidance on Safe Use
Guidance on Safe Use
Currently viewing:
Administrative data
First-aid measures
Description of first aid measures:
General advice:
- First-aid crew: Ensure self-protection.
- Move out of dangerous area.
- Take off contaminated clothing and shoes immediately.
If inhaled:
- Move to fresh air.
- If symptoms persist, call a physician.
In case of skin contact:
- Wash off immediately with plenty of water for at least 15 minutes.
- Call a physician immediately.
In case of eye contact:
- Rinse immediately with plenty of water, also under the eyelids,for at least 15 minutes.
- Call a physician immediately.
If swallowed:
- Rinse mouth with water.
- Immediately give large quantities of water to drink.
- Do NOT induce vomiting.
- Call a physician immediately.
Most important symptoms and effects, both acute and delayed:
Symptoms:
- Headache
- Nausea
- Dizziness
- Unconsciousness
Risks:
- Corrosive effects
Indication of any immediate medical attention and special treatment needed
Treatment:
- Treat symptomatically.
- For specialist advice physicians should contact the Poisons Information Service
General advice:
- First-aid crew: Ensure self-protection.
- Move out of dangerous area.
- Take off contaminated clothing and shoes immediately.
If inhaled:
- Move to fresh air.
- If symptoms persist, call a physician.
In case of skin contact:
- Wash off immediately with plenty of water for at least 15 minutes.
- Call a physician immediately.
In case of eye contact:
- Rinse immediately with plenty of water, also under the eyelids,for at least 15 minutes.
- Call a physician immediately.
If swallowed:
- Rinse mouth with water.
- Immediately give large quantities of water to drink.
- Do NOT induce vomiting.
- Call a physician immediately.
Most important symptoms and effects, both acute and delayed:
Symptoms:
- Headache
- Nausea
- Dizziness
- Unconsciousness
Risks:
- Corrosive effects
Indication of any immediate medical attention and special treatment needed
Treatment:
- Treat symptomatically.
- For specialist advice physicians should contact the Poisons Information Service
Fire-fighting measures
Extinguishing media:
Suitable extinguishing media:
- Dry sodium chloride
- Limestone powder
Unsuitable extinguishing media:
- Water
- Carbon dioxide (CO2)
- Foam
Special hazards arising from the substance or mixture:
Specific hazards during fire fighting:
- May form toxic gases on heating or in case of fire.
Advice for firefighters:
Special protective equipment for fire-fighters:
- In the event of fire, wear self-contained breathing apparatus.
Further information :
- Use water spray to cool unopened containers.
- Be aware of a dangerous reaction with water, if the container is ruptured.
- Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
- Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Suitable extinguishing media:
- Dry sodium chloride
- Limestone powder
Unsuitable extinguishing media:
- Water
- Carbon dioxide (CO2)
- Foam
Special hazards arising from the substance or mixture:
Specific hazards during fire fighting:
- May form toxic gases on heating or in case of fire.
Advice for firefighters:
Special protective equipment for fire-fighters:
- In the event of fire, wear self-contained breathing apparatus.
Further information :
- Use water spray to cool unopened containers.
- Be aware of a dangerous reaction with water, if the container is ruptured.
- Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
- Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Personal precautions:
- Wear personal protective equipment.
- Ensure adequate ventilation.
- Remove all sources of ignition.
- Do not smoke.
Environmental precautions:
- Do not flush into surface water or sanitary sewer system.
- Avoid subsoil penetration.
- If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and materials for containment and cleaning up:
Methods for cleaning up:
- Never allow contact with water.
- Cover spilled material with limestone powder.
- Sweep up and shovel into suitable containers for disposal.
Reference to IUCLID sections 11:
- Exposure controls/personal protection
- Disposal considerations
Personal precautions:
- Wear personal protective equipment.
- Ensure adequate ventilation.
- Remove all sources of ignition.
- Do not smoke.
Environmental precautions:
- Do not flush into surface water or sanitary sewer system.
- Avoid subsoil penetration.
- If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and materials for containment and cleaning up:
Methods for cleaning up:
- Never allow contact with water.
- Cover spilled material with limestone powder.
- Sweep up and shovel into suitable containers for disposal.
Reference to IUCLID sections 11:
- Exposure controls/personal protection
- Disposal considerations
Handling and storage
Precautions for safe handling:
Advice on safe handling:
- Handle under inert gas.
- Never allow water to come into contact with the product.
- Avoid dust formation.
- Avoid contact with skin and eyes.
- Have eye wash bottle or eye rinse ready at the work place.
Advice on protection against fire and explosion:
- Keep away from sources of ignition - No smoking.
- Take precautionary measures against static discharges.
- Electrical equipment should be protected to the appropriate standard.
Conditions for safe storage, including any incompatibilities:
Requirements for storage areas and containers:
- Keep container tightly closed in a dry and well-ventilated place.
- Protect from direct sunlight.
- Protect from moisture.
- Keep under inert gas.
Storage temperature:
- 5 - 30 °C
Specific end uses:
Specific use(s):
- Reagent for organic synthesis.
Advice on safe handling:
- Handle under inert gas.
- Never allow water to come into contact with the product.
- Avoid dust formation.
- Avoid contact with skin and eyes.
- Have eye wash bottle or eye rinse ready at the work place.
Advice on protection against fire and explosion:
- Keep away from sources of ignition - No smoking.
- Take precautionary measures against static discharges.
- Electrical equipment should be protected to the appropriate standard.
Conditions for safe storage, including any incompatibilities:
Requirements for storage areas and containers:
- Keep container tightly closed in a dry and well-ventilated place.
- Protect from direct sunlight.
- Protect from moisture.
- Keep under inert gas.
Storage temperature:
- 5 - 30 °C
Specific end uses:
Specific use(s):
- Reagent for organic synthesis.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3391
Shipping information
- Proper shipping name and description:
- ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC Lithium diisopropylamide
- Chemical name:
- Lithium diisopropylamide
- Language:
- English
- Labels:
- 4.2
Special provisions / remarks
- Special provisions:
- Hazard identification No:
- 43
Tunnel restriction code:
- (B/E) - Remarks:
- Environmentally hazardous:
- no
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- Not applicable
Shipping information
- Proper shipping name and description:
- ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC Lithium diisopropylamide
- Chemical name:
- Not applicable
- Language:
- English
- Labels:
- Not applicable
Special provisions / remarks
- Remarks:
- Not applicable
Marine transport (UN RTDG/IMDG)
- UN number:
- 3391
Shipping information
- Proper shipping name and description:
- ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC Lithium diisopropylamide
- Chemical name:
- Lithium diisopropylamide
- Labels:
- 4.2
Special provisions / remarks
- Remarks:
- Not applicable
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3391
Shipping information
- Proper shipping name and description:
- ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC Lithium diisopropylamide
- Chemical name:
- Lithium diisopropylamide
- Labels:
- Not permitted for transport
Special provisions / remarks
- Remarks:
- Not permitted for transport
Additional transport information
Additional information
- Special provisions / remarks / other:
- Not applicable
Exposure controls / personal protection
Control parameters:
- Contains no substances with occupational exposure limit values.
Exposure controls:
Engineering measures:
- Ensure adequate ventilation, especially in confined areas.
- Electrical equipment should be protected to the appropriate standard.
Personal protective equipment:
Respiratory protection:
- In case of insufficient ventilation, wear suitable respiratory equipment.
- Recommended Filter type: Half mask with a particle filter P2 (EN 143).
Hand protection:
- Flame retardant gloves.
- Protective gloves complying with EN 374.
- The exact break through time can be obtained from the protective glove producer and this has to be observed.
- Protective gloves have to be replaced at the first sign of deterioration.
Eye protection:
- Eye protection (EN 166).
- Tightly fitting safety goggles.
Skin and body protection:
- Flame retardant, antistatic and chemical resistant protective clothing.
Hygiene measures:
- Take off contaminated clothing and shoes immediately.
- Avoid contact with the skin and the eyes.
- Keep away from food, drink and animal feedingstuffs.
- When using, do not eat, drink or smoke.
- Wash hands before breaks and immediately after handling the product.
- Do not breathe dust.
Protective measures:
- Facilities storing or utilizing this material should be equipped with an eyewash facility and safety shower.
- Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls:
General advice:
- Do not flush into surface water or sanitary sewer system.
- Avoid subsoil penetration.
- If the product contaminates rivers and lakes or drains inform respective authorities.
- Contains no substances with occupational exposure limit values.
Exposure controls:
Engineering measures:
- Ensure adequate ventilation, especially in confined areas.
- Electrical equipment should be protected to the appropriate standard.
Personal protective equipment:
Respiratory protection:
- In case of insufficient ventilation, wear suitable respiratory equipment.
- Recommended Filter type: Half mask with a particle filter P2 (EN 143).
Hand protection:
- Flame retardant gloves.
- Protective gloves complying with EN 374.
- The exact break through time can be obtained from the protective glove producer and this has to be observed.
- Protective gloves have to be replaced at the first sign of deterioration.
Eye protection:
- Eye protection (EN 166).
- Tightly fitting safety goggles.
Skin and body protection:
- Flame retardant, antistatic and chemical resistant protective clothing.
Hygiene measures:
- Take off contaminated clothing and shoes immediately.
- Avoid contact with the skin and the eyes.
- Keep away from food, drink and animal feedingstuffs.
- When using, do not eat, drink or smoke.
- Wash hands before breaks and immediately after handling the product.
- Do not breathe dust.
Protective measures:
- Facilities storing or utilizing this material should be equipped with an eyewash facility and safety shower.
- Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls:
General advice:
- Do not flush into surface water or sanitary sewer system.
- Avoid subsoil penetration.
- If the product contaminates rivers and lakes or drains inform respective authorities.
Stability and reactivity
Reactivity:
- Risk of violent reaction.
Chemical stability:
- Decomposes on heating.
- Sensitive to air.
- Decomposition under influence of moisture is highly accelerated by heating.
Possibility of hazardous reactions:
Hazardous reactions:
- Reacts violently with water.
Conditions to avoid:
- Protect from frost, heat and sunlight.
- Keep away from open flames, hot surfaces and sources of ignition.
- Protect from moisture.
- Take precautionary measures static discharges.
Incompatible materials:
Materials to avoid:
- Water
- Acids
- Oxidizing agents
Hazardous decomposition products:
Risk of decomposition:
- Decomposes in contact with water
Decomposition products:
- Diisopropylamine
- Lithium hydroxide
Thermal decomposition:
- > 40 °C
- To avoid thermal decomposition, do not overheat.
- Risk of violent reaction.
Chemical stability:
- Decomposes on heating.
- Sensitive to air.
- Decomposition under influence of moisture is highly accelerated by heating.
Possibility of hazardous reactions:
Hazardous reactions:
- Reacts violently with water.
Conditions to avoid:
- Protect from frost, heat and sunlight.
- Keep away from open flames, hot surfaces and sources of ignition.
- Protect from moisture.
- Take precautionary measures static discharges.
Incompatible materials:
Materials to avoid:
- Water
- Acids
- Oxidizing agents
Hazardous decomposition products:
Risk of decomposition:
- Decomposes in contact with water
Decomposition products:
- Diisopropylamine
- Lithium hydroxide
Thermal decomposition:
- > 40 °C
- To avoid thermal decomposition, do not overheat.
Disposal considerations
Waste treatment methods:
Product:
- If recycling is not practicable, dispose of in compliance with local regulations.
Contaminated packaging:
- Refer to manufacturer/supplier for information on recovery/recycling.
Waste Code:
- Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
Product:
- If recycling is not practicable, dispose of in compliance with local regulations.
Contaminated packaging:
- Refer to manufacturer/supplier for information on recovery/recycling.
Waste Code:
- Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
