[No public or meaningful name is available]

Guidance on Safe Use

First-aid measures

Emergency measure - Inhalation: Remove patient from exposure. Obtain medical attention if

ill effects occur.

Emergency measure - Eyes: Immediately rinse thoroughly for least 15 minutes with the

lids wide open (eye rinse bottle)

Emergency measure - Skin: Treat hands with protection cream. In case of skin contact

with powders or solutions immediately rinse the areas

affected contionusly with water and then wash with soap and

water.

In no case it is permitted to clean the skin with solvents

(e.g. ethanol). Risk of absorption through the skin.

Emergency measure - Ingestion: Rinse mouth with lots of water.

Fire-fighting measures

Recommended extinguishing agent: Water jet, carbon dioxide, foam, powder

Product arising from burning: Carbon monoxide, carbon dioxide, nitrous gases

Product determined by test: N

Protective equipment: Self-contained breath apparatus and tightly closeable

chemical protective clothes.

Accidental release measures

Emergency measures in case of spillage: Take up spilt material avoiding formation of dust (e.g. by

previous wetting with water or by using an approved

industrial vacuum cleaner). Carefully transfer the spillage

into waste containers which have to be tightly closed and

labelled according to TRGS 201. Send these containers back

to the manufacturer. While taking up the spillage and

cleaning the polluted area avoid skin and eye contact as

well as inhalation of the substance e.g. by wearing

appropriate personal protective equipment (see section

"Handling"). Clean the contaminated area with plenty of

water.

Handling and storage

Handling: Alle Arbeitsverfahren sind grundsätzlich so zu gestalten,

dass der Haut- und Augenkontakt mit dem Stoff

ausgeschlossen ist. Das Einatmen des Stoffes ist zu

vermeiden. Bei Umfüll- und Dosierarbeiten sowie bei

Probenahmen sollten geschlossene Vorrichtungen verwendet

werden. Beim Umgang in offenen Systemen sollte möglicher

Staub unmittelbar am Entstehungsort abgesaugt werden.

Wenn technische Absaug- oder Lüftungsmaßnahmen nicht möglich

oder unzureichend sind, sollte Atemschutz (z.B. Filter Typ

P2) getragen werden. Auch wenn nur ein kurzzeitiger

Hautkontakt möglich ist, sind geprüfte Schutzhandschuhe

(z.B. aus Nitrilgummi) und geeignete Schutzkleidung (z.B.

Einmalschutzanzug beim offenen Umgang) zu tragen. Ein

sicherer Augenschutz (z.B. Korbbrille) ist unbedingt

erforderlich. In unmittelbarer Nähe des Arbeitsbereiches

sollten Notbrausen installiert sein, ausreichende

Waschgelegenheiten zur Verfügung stehen sowie Augenbrausen

bereitgestellt und ihr Standort auffällig gekennzeichnet

werden. Nach Hautkontakt sollten die betroffenen

Körperstellen sofort gründlich mit ::: gereinigt werden.

Kontaminierte Kleidung ist sofort zu wechseln. Besondere

Hautschutz- und Hautpflegemaßnahmen werden empfohlen. Es ist

ein Hautschutzplan aufzustellen. Bei möglicher

Staubentwickung sollten wegen der potentiellen

Staubexplosionsgefahr potentielle Zündquellen aus dem

Arbeitsbereich entfernt werden. Des weiteren sollten

Maßnahmen gegen elektrostatische Aufladungen getroffen

werden.

"ENGLISH"

All work process must always be designed so that skin and

eye contact with the substance is excluded. Inhalation of

the substance must be avoided. Closed equipment should be

used during transfer and metered feeding. In the case of

handling in open systems, any dust that may form should be

extracted directly at the point of origin., If technical

extraction or ventilation measures are not possible or are

insufficient, respiratory protection (e.g.:::) should be

worn. Tested protective gloves (e.g. made of nitrile rubber)

and suitable protective clothing (e.g.:::) must be worn even

if only short-term skin contact is possible. Safe eye

protection (e.g. tightly fitting goggles) is absolutely

essential. Emergency showers should be installed in the

immediate vicinity of the work area, sufficient washing

facilities and eye douches should be available and their

location conspicuously marked. After skin contact the

affected parts of the body should be immediately thoroughly

cleaned using :::. Contaminated clothing must be changed

immediately. Special skin protection and skin-care measures

are recommended. A skin-protection plan must be drawn up.

Due to the potential risk of a dust explosion, potential

ignition sources should be removed from the work area if

there is the possibility of dust formation. In addition,

measures should be taken to avoid static discharge.

Storage: Store tightly closed, dry and protected from light and heat

in according to the regulations labeled and secure PE-bags

which should be secured against falling. Avoid dust

formation and residues on the outside of the containers.

Packaging of the substance and or preparation: For transportation, use 25 kg fiber drums licensed in

accordance with commercial law.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3267

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.

Chemical name:

S,S-PYRROLOPIPERIDIN

Language:

English

Labels:

8

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3267

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.

Chemical name:

S,S-PYRROLOPIPERIDIN

Language:

English

Labels:

8

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

3267

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.

Chemical name:

S,S-PYRROLOPIPERIDIN

Labels:

8

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

3267

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.

Chemical name:

S,S-PYRROLOPIPERIDIN

Labels:

8

Special provisions / remarks

Remarks:

Transport: Transport only closed containers which are safeguarded
against falling, slipping and damage. Label according to
regulations.

SpecialProvisions

Exposure controls / personal protection

This intermediate is handled under Strictly Controlled Conditions in accordance with the ECHA REACH Guidance on Intermediates.  Site documentation to demonstrate safe handling arrangements in accordance with risk-based management systems is available at each Manufacturing site.

Personal protective equipment

Respiratory protection: respirator with P3 filter

Eye protection: safety glasses with side-shields

Hand protection: During the handling of the substance according to the intended use protection gloves from nitrile rubber have been proved. During the handling of pure solid substances or powder mixtures a permeation of the rubber material is not to be expected. In case of doubt, especially

during handling of the substance together with organic solvents, the stability of the protection gloves has to be clarified with the manufacturer.

Skin and body protection: Choose body protection according to the amount and concentration of the dangerous substance at the work place.

Stability and reactivity

Condition to avoid: No data available

Materials to avoid: Oxidizing agents, Strong acids

Hazardous reactions: None known

Disposal considerations

Product: Dispose of as special waste in compliance with local and national regulations