Registration Dossier
Registration Dossier
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EC number: 203-321-6 | CAS number: 105-67-9
Guidance on Safe Use
Administrative data
First-aid measures
First aid measures:
General advice: Immediate medical attention is required.
If inhaled: Move to fresh air. Call a physician or poison control centre immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
In case of skin contact: Call a physician immediately. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Apply PEG/EtOH solution liberally to affected area. Allow to remain 15 to 30 seconds, then wash with water. Continue cycle of water - PEG/EtOH solution for at least 15 minutes. (PEG/EtOH solution consists of 2 parts polyethylene glycol 400 to 1 part ethanol. For external use only). Finish decontamination with thorough washing using soap and water.
In case of eye contact: Call a physician immediately. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses. Keep eye wide open while rinsing.
If swallowed: Call a physician immediately. Do NOT induce vomiting. Rinse mouth. Ingest immediately about 350 ml (5 ml/kg body weight) of activated charcoal slurry. Note: To prepare activated charcoal slurry, mix thoroughly 50 g of activated charcoal in 400 ml (about 2 cups) water. Never give anything by mouth to an unconscious person. Immediately call a POISON CENTER or doctor/ physician.
Most important symptoms and effects, both acute and delayed
Symptoms: Asphyxia from glottal edema may occur. Marked decrease in blood pressure may occur with moist rales, frothy sputum, and high pulse pressure.
Risks: Corrosive Material
Indication of any immediate medical attention and special treatment needed
Treatment: Use of gastric lavage or emesis is
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: Dry chemical, Foam, Water spray, Carbon dioxide (CO2)
Unsuitable extinguishing media: High volume water jet
Special hazards arising from the substance or mixture
Specific hazards during firefighting: Dangerous gases or fumes may occur in case of fire.
Advice for firefighters
Special protective equipment for firefighters: Wear an approved positive pressure self-contained breathing apparatus in addition to standard fire fighting gear.
Further information: Standard procedure for chemical fires.
Accidental release measures
Personal precautions: Evacuate personnel to safe areas. Use personal protective equipment. Avoid contact with skin, eyes and clothing. Keep people away from and upwind of spill/leak. Refer to protective measures listed in sections Handling and Storage and Exposure controls/personal protection
Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Should not be released into the environment. Prevent product from entering drains. Site should have a spill plan to ensure that adequate safeguards are in place to minimize the impact of episodic releases.
Methods for cleaning up: Soak up with inert absorbent material. Pick up and transfer to properly labelled containers. Keep in suitable, closed containers for disposal.
Handling and storage
Precautions for safe handling
Advice on safe handling: Wear personal protective equipment. Avoid contact with skin and eyes. Ensure adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment.
Advice on protection against fire and explosion: Keep away from open flames, hot surfaces and sources of ignition.
Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers: Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in properly labelled containers.
Storage class (TRGS 510): 6.1A: Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 2261
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Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 2261
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Marine transport (UN RTDG/IMDG)
- UN number:
- 2261
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 2261
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Exposure controls / personal protection
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS
National occupational exposure limits: No data available
EUROPEAN OCCUPATIONAL EXPOSURE LIMITS: No data available
ENGINEERING MEASURES
Handle only in a place equipped with local exhaust (or other appropriate exhaust).
Drain down and flush system prior to equipment opening or maintenance.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory protection:
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Respirator with a full face mask ABEK-filter
Hand protection: The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other., Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time., Be aware that in daily use the durability of a chemical resistant protective glove can be notably shorter than the break through time measured according to EN 374, due to the numerous outside influences (e.g. temperature).
gloves suitable for permanent contact:
Material: Fluorinated rubber Break through time: >= 60 min Layer thickness: 0.4 mm
Material: Polychloroprene Break through time: >= 60 min Layer thickness: 0.4 mm
Material: Polyvinylchloride Break through time: >= 60 min. min Layer thickness: 0.4 mm
Eye protection: Ensure that eyewash stations and safety showers are close to the workstation location., Tightly fitting safety goggles, Face-shield
Skin and body protection: Wear as appropriate:, Impervious clothing, Impervious gloves, Boots, Chemical resistant apron
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. When using, do not eat, drink or smoke. Wash hands and face before breaks and immediately after handling the product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Contaminated work clothing should not be allowed out of the workplace. Keep away from food, drink and animal feedingstuffs.
Protective measures
Avoid contact with the skin and the eyes.
ENVIRONMENTAL EXPOSURE CONTROLS
General advice
Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Should not be released into the environment. Prevent product from entering drains. Site should have a spill plan to ensure that adequate safeguards are in place to minimize the impact of episodic releases.
Stability and reactivity
Reactivity
Note: No decomposition if stored and applied as directed.
Chemical stability
Note: Stable under normal conditions.
Possibility of hazardous reactions
Hazardous reactions: Burning produces noxious and toxic fumes. The product causes burns of eyes, skin and mucous membranes.
Conditions to avoid: Heat, flames and sparks. Exposure to air or moisture over prolonged periods.
Incompatible materials to avoid
Materials to avoid: Incompatible with strong acids and bases.; Incompatible with oxidizing agents.; Copper alloys; Aluminium
Hazardous decomposition products
Carbon monoxide Carbon dioxide (CO2)
Thermal decomposition
Thermal decomposition can lead to release of irritating gases and vapours.
Disposal considerations
Waste treatment methods
Product: Dispose of in accordance with local regulations., Can be incinerated, when in compliance with local regulations., Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities., Where possible recycling is preferred to disposal or incineration.
Contaminated packaging
Do not re-use empty containers., Empty containers should be taken to an approved waste handling site for recycling or disposal.
waste code of the European Union: EWC
A waste code in accordance with the European Waste Catalogue (EWC) may not be assigned to this product since it admits of a classification only when the consumer uses it for some purpose. The waste code must be determined in agreement with the regional waste disposal authority or company
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
