Bis(1-n-butyl-3-methylcyclopentadienyl)zirconium dichloride

Guidance on Safe Use

First-aid measures

SKIN EXPOSURE: If spilled on skin, begin decontamination with running water, for at least 15 minutes. Remove exposed or contaminated clothing, taking care not to contaminate eyes.

EYE EXPOSURE: If chemical is in eyes, open victim's eyes while under gentle running water.  Use sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes.

INHALATION: If chemical is inhaled, remove victim to fresh air. If necessary, use artificial respiration to support vital functions. Remove or cover gross contamination to avoid exposure to rescuers.

INGESTION: If chemical is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION.

If professional advice is not available, do not induce vomiting. Victim should drink milk, egg whites, or large quantities of water. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or who cannot swallow.

Victims of chemical exposure must be taken for medical attention. Rescuers should be taken for medical attention, if necessary. Take copy of label and MSDS with victim to health professional.

Fire-fighting measures

FIRE EXTINGUISHING MATERIALS:

Water Spray, Foam, Carbon Dioxide, Dry Chemical,  "B" type, or Halon

SPECIAL FIRE FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural fire fighters must wear Self-Contained Breathing Apparatus and full protective equipment.

UNUSUAL FIRE and EXPLOSION HAZARDS: Slight fire hazard. Dust/air mixtures may ignite or explode.

EXPLOSION SENSITIVITY TO MECHANICAL IMPACT: Not sensitive.

EXPLOSION SENSITIVITY TO STATIC DISCHARGE: Dust/air mixtures may ignite or explode.

HAZARDOUS COMBUSTION PRODUCTS: carbon oxides, halogenated compounds, zirconium/zirconium oxides.

Accidental release measures

SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned procedures. Proper protective equipment should be used. In case of a spill, clear the affected area, protect people, and respond with trained personnel. Minimum Personal Protective Equipment should be minimum be Level B: triple-gloves (rubber gloves and nitrile gloves, over latex gloves), chemically resistant suit and boots, hard-hat, and Self-Contained Breathing Apparatus. Decontaminate the area thoroughly. Place all spill residue in a double plastic bag and seal. Decontaminate area thoroughly by rinsing with soap and water. Dispose of in accordance with government hazardous waste disposal regulations.

Handling and storage

WORK PRACTICES and HYGIENE PRACTICES: Avoid getting chemicals ON YOU or IN YOU. Wash hands after handling chemicals. Do not eat or drink while handling chemicals. Follow SPECIFIC USE INSTRUCTIONS supplied with product.

STORAGE and HANDLING PRACTICES: Store product in properly labeled, closed containers in cool location, away from sources of ignition. Dusts may exist in "empty" containers of this product, which could ignite and explode if in contact with a source of ignition. Store this product under an inert atmosphere, such as nitrogen or argon. Keep away from intense light.

PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated above. Make certain application equipment is locked and tagged-out safely. Always use this product in areas where adequate ventilation is provided. Decontaminate equipment, according to the procedures under the "Accidental Release Measures” section before maintenance begins. Collect all rinsates and dispose of according to applicable government procedures.

Transport information

Shipping

SpecialProvisions

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

Shipping

Remarks

Shipping

Remarks

SpecialProvisions

Exposure controls / personal protection

EXPOSURE LIMITS MEASUREMENT METHOD: Particulate filter; Acid; Inductively coupled plasma; NIOSH III # 7300, Elements

VENTILATION and ENGINEERING CONTROLS: Use with adequate ventilation. Use a mechanical fan or vent area to outside.

RESPIRATORY PROTECTION: Minimum NIOSH/MSHA approved organic cartridge type respirator under routine conditions of use. Maintain airborne contaminant concentrations below guidelines listed in Section 3. If respiratory protection is needed, use only protection authorized by applicable government regulations. Use supplied air respiration protection if oxygen levels are below 19.5%. Use Self-Contained Breathing Apparatus during release response procedures.

EYE PROTECTION: Splash goggles or safety glasses.

HAND PROTECTION: Protective gloves recommended. Wash hands after removing gloves.

BODY PROTECTION: Use body protection appropriate for task. Cover-alls, rubber aprons, or chemical protective clothing made from natural rubber are generally acceptable, depending upon the task.

Stability and reactivity

STABILITY: Stable.

MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Acids, bases, oxidizers. Material may decompose when exposed to air or moisture.

HAZARDOUS POLYMERIZATION: Will not occur.

CONDITIONS TO AVOID: Extreme heat, flame, sparks, contact with air, moisture, or incompatible chemicals.

Disposal considerations

PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate government regulations. This chemical, if unaltered by the handling, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority.